JEE Main 2025 — 3 April, Morning Shift

$2$ moles each of ethylene glycol and glucose are dissolved in $500\,\mathrm{g}$ of water. The boiling point of the resulting solution is:

(Given: $K_b = 0.52\,\mathrm{K\,kg\,mol^{-1}}$)

Which compound would give 3-methyl-6oxoheptanal upon ozonolysis?

Among $10^{-9} \mathrm{~g}$ (each) of the following elements, which one will have the highest number of atoms?

Elements: Pb, Po, Pr and Pt

Correct order of limiting molar conductivity for cations in water at 298 K is :

Which of the following postulate of Bohr's model of hydrogen atom is not in agreement with quantum mechanical model of an atom?

Number of molecules from below which cannot give iodoform reaction is : Ethanol, Isopropyl alcohol, Bromoacetone, 2Butanol, 2-Butanone, Butanal, 2-Pentanone, 3Pentanone, Pentanal and 3-Pentanol.

Given below are two statements :

Statement (I) : A catalyst cannot alter the equilibrium constant $\left(\mathrm{K}_{\mathrm{c}}\right)$ of the reaction, temperature remaining constant.

Statement (II) : A homogenous catalyst can change the equilibrium composition of a system, temperature remaining constant.

In the light of the above statements, choose the correct answer from the options given below.

Match the LIST-I with LIST-II

Choose the correct answer from the options given below:

In a reaction $A+B \rightarrow C$, initial concentrations of $A$ and $B$ are related as $[A]_{0}=8[B]_{0}$. The half lives of $A$ and $B$ are 10 min and 40 min , respectively, If they start to disappear at the same time, both following first order kinetics, after how much time will the concentration of both the reactants be same?

The least acidic compound, among the following is

The metal ions that have the calculated spin only magnetic moment value of 4.9 B.M. are

A. $\mathrm{Cr}^{2+}$

B. $\mathrm{Fe}^{2+}$

C. $\mathrm{Fe}^{3+}$

D. $\mathrm{Co}^{2+}$

E. $\mathrm{Mn}^{3+}$

Choose the correct answer from the options given below:

Given below are two statements, one is labelled as Statement I and the other is labelled as Statement II.

Statement I: The $N - N$ single bond is weaker and longer than that of $P-P$ single bond.

Statement II: Compounds of group 15 elements in +3 oxidation states readily undergo disproportionation reactions.

In the light of the above statements, choose the correct answer from the options given below :

Which of the following statements are correct?

A. The process of adding an electron to a neutral gaseous atom is always exothermic.

B. The process of removing an electron from an isolated gaseous atom is always endothermic.

C. The 1st ionization energy of boron is less than that of beryllium.

D. The electronegativity of C is 2.5 in $\mathrm{CH}_{4}$ and $\mathrm{CCl}_{4}$

E. Li is the most electropositive among elements of group 1 .

Choose the correct answer from the options given below:

The correct order of the complexes

$\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{5}\left(\mathrm{H}_{2} \mathrm{O}\right)\right]^{3+}(\mathrm{A}),\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}(\mathrm{B}),\left[\mathrm{Co}(\mathrm{CN})_{6}\right]^{3-}$ (C) and

$\left[\mathrm{CoCl}\left(\mathrm{NH}_{3}\right)_{5}\right]^{2+}(\mathrm{D})$ in terms of wavelength of light absorbed is

The number of optical isomers exhibited by the iron complex (A) obtained from the following reaction is $\_\_\_\_\_$ .

$\mathrm{FeCl}_{3}+\mathrm{KOH}+\mathrm{H}_{2} \mathrm{C}_{2} \mathrm{O}_{4} \rightarrow \mathrm{~A}$

During estimation of nitrogen by Dumas' method of compound X (0.42 g)

$\_\_\_\_\_$ mL of $\mathrm{N}_{2}$ gas will be liberated at STP. (nearest integer)

(Given molar mass in $\mathrm{g} \mathrm{mol}^{-1}: \mathrm{C}: 12, \mathrm{H}: 1, \mathrm{~N}: 14$ )

Given : $\Delta \mathrm{H}_{\text {sub }}^{\Theta}[\mathrm{C}($ graphite $)]=710 \mathrm{~kJ} \mathrm{~mol}^{-1}$

$\Delta_{\mathrm{C}-\mathrm{H}} \mathrm{H}^{\Theta}=414 \mathrm{~kJ} \mathrm{~mol}^{-1}$

$\Delta_{\mathrm{H}-\mathrm{H}} \mathrm{H}^{\Theta}=436 \mathrm{~kJ} \mathrm{~mol}^{-1}$

$\Delta_{\mathrm{C}=\mathrm{C}} \mathrm{H}^{\Theta}=611 \mathrm{~kJ} \mathrm{~mol}^{-1}$

The $\Delta \mathrm{H}_{\mathrm{f}}^{\Theta}$ for $\mathrm{CH}_{2}=\mathrm{CH}_{2}$ is $\_\_\_\_\_$ $\mathrm{kJ} \mathrm{mol}^{-1}$ (nearest integer value)

0.5 g of an organic compound on combustion gave 1.46 g of $\mathrm{CO}_{2}$ and 0.9 g of $\mathrm{H}_{2} \mathrm{O}$. The percentage of carbon in the compound is $\_\_\_\_\_$ . (Nearest integer) [Given : Molar mass (in $\mathrm{g} \mathrm{mol}^{-1}$ ) $\mathrm{C}: 12, \mathrm{H}: 1, \mathrm{O}$ : 16]

Consider the following reactions

$\text{A} + \text{NaCl} + \text{H}_2\text{SO}_4 \xrightarrow{\text{Little amount}} \text{CrO}_2\text{Cl}_2 + \text{Side Products}$ $\text{CrO}_2\text{Cl}_{2(\text{vapour})} + \text{NaOH} \rightarrow \text{B} + \text{NaCl} + \text{H}_2\text{O}$ $\text{B} + \text{H}^+ \rightarrow \text{C} + \text{H}_2\text{O}$

The number of terminal ' $O$ ' present in the compound ' $C$ ' is $\_\_\_\_\_$

Let A be a matrix of order $3 \times 3$ and $|\mathrm{A}|=5$. If $|2 \operatorname{adj}(3 \mathrm{~A} \operatorname{adj}(2 \mathrm{~A}))|=2^{\alpha} .3^{\beta} .5^{\gamma} \alpha, \beta, \gamma \in \mathrm{N}$ then

$\alpha+\beta+\gamma$ is equal to

Let a line passing through the point $(4,1,0)$ intersect the line $L_{1} ; \frac{x-1}{2}=\frac{y-2}{3}=\frac{z-3}{4}$ at the point A

$(\alpha, \beta, \gamma)$ and the line $L_{2}: x-6=y=-z+4$ at the point $B(a, b, c)$. Then $\left|\begin{array}{lll}1 & 0 & 1\\ \alpha & \beta & \gamma\\ \mathrm{a} & \mathrm{b} & \mathrm{c}\end{array}\right|$ is equal to

Let $\alpha$ and $\beta$ be the roots of $x^{2}+\sqrt{3 x}-16=0$, and $\gamma$ and $\delta$ be the roots of $x^{2}+3 x-1=0$. If

$\mathrm{P}_{\mathrm{n}}=\alpha^{\mathrm{n}}+\beta^{\mathrm{n}}$ and $\mathrm{Q}_{\mathrm{n}}=\gamma^{\mathrm{n}}+\delta^{\mathrm{n}}$, then $\frac{P_{25}+\sqrt{3 P_{24}}}{2 P_{23}}+\frac{Q_{25}-Q_{23}}{Q_{24}}$ is equal to

The sum of all rational terms in the expansion of $(2+\sqrt{3})^{8}$ is

Let $\mathrm{A}=\{-3,-2,-1,0,1,2,3$,$\}$. Let $R$ be a relation on A defined by xRy if and only if $0 \leq x^{2}+2 y \leq 4$ . Let $l$ be the number of elements in R and $m$ be the minimum number of elements required

to be added in R to make it a reflexive relation. then $l+m$ is equal to

A line passing through the point $\mathrm{P}(\sqrt{5}, \sqrt{5})$ intersects the ellipse $\frac{\mathrm{x}^{2}}{36}+\frac{\mathrm{y}^{2}}{25}=1$ at $A$ and $B$ such that

$(P A) .(P B)$ is maximum. Then $5\left(P A^{2}+P B^{2}\right)$ is equal to :

The sum $1+3+11+25+45+71+$.. upto 20 terms, is equal to

If the domain of the function $f(x)=\log _{e}\left(\frac{2 x-3}{5+4 x}\right)+\sin ^{-1}\left(\frac{4+3 x}{2-x}\right)$ is $[\alpha, \beta)$, then $\alpha^{2}+4 \beta$ is

equal to

If $\sum_{\mathrm{r}=1}^{9}\left(\frac{\mathrm{r}+3}{2^{\mathrm{r}}}\right) \cdot{ }^{9} \mathrm{C}_{\mathrm{r}}=\alpha\left(\frac{3}{2}\right)^{9}-\beta, \quad \alpha, \beta \in \mathrm{N}$, then $(\alpha+\beta)^{2}$ is equal to

The number of solutions of the equation $2 \mathrm{x}+3 \tan \mathrm{x}=\pi, \mathrm{x} \in[-2 \pi, 2 \pi]-\left\{ \pm \frac{\pi}{2}, \pm \frac{3 \pi}{2}\right\}$ is :

If $\mathrm{y}(\mathrm{x})=\left|\begin{array}{ccc}\sin \mathrm{x} & \cos \mathrm{x} & \sin \mathrm{x}+\cos \mathrm{x}+1\\ 27 & 28 & 27\\ 1 & 1 & 1\end{array}\right|, \mathrm{x} \in \mathbb{R}$, then $\frac{\mathrm{d}^{2} \mathrm{y}}{\mathrm{dx}^{2}}+\mathrm{y}$ is equal to:

Let $g$ be a differentiable function such that $\int_{0}^{\mathrm{x}} \mathrm{g}(\mathrm{t}) \mathrm{dt}=\mathrm{x}-\int_{0}^{\mathrm{x}} \mathrm{tg}(\mathrm{t}) \mathrm{dt}, \mathrm{x} \geq 0$ and let $\mathrm{y}=\mathrm{y}(\mathrm{x})$

satisfy the differential equation $\frac{d y}{d x}-y \tan x=$ $2(x+1) \sec x g(x), x \in\left[0, \frac{\pi}{2}\right)$. If $y(0)=0$, then

$y\left(\frac{\pi}{3}\right)$ is equal to

A line passes through the origin and makes equal angles with the positive coordinate axes. It intersects the lines

$L_{1}: 2 x+y+6=0$ and $L_{2}: 4 x+2 y-p=0, p>0$, at the points A and B , respectively. If

$\mathrm{AB}=\frac{9}{\sqrt{2}}$ and the foot of the perpendicular from the point A on the line $L_{2}$ is $M$, then $\frac{A M}{B M}$ is equal to

Let $z \in C$ be such that $\frac{z^{2}+3 i}{z-2+i}=2+3 i$. Then the sum of all possible values of $z^{2}$ is

Let $f(x)=\int \mathrm{x}^{3} \sqrt{3-\mathrm{x}^{2}} \mathrm{dx}$. If $5 f(\sqrt{2})=-4$, then $f(1)$ is equal to

Let $a_{1}, a_{2}, a_{3}, \ldots$ be a G. P. of increasing positive numbers. If $\mathrm{a}_{3} \mathrm{a}_{5}=729$ and $\mathrm{a}_{2}+\mathrm{a}_{4}=\frac{111}{4}$, then

$24\left(a_{1}+a_{2}+a_{3}\right)$ is equal to

Let the domain of the function $f(x)=\log _{2} \log _{4} \log _{6}\left(3+4 x-x^{2}\right)$ be $(a, b)$. If

$\int_{0}^{b-a}\left[x^{2}\right] d x=p-\sqrt{q}-\sqrt{r}, p, q, r \in \mathbb{N}, \operatorname{gcd}(p, q, r)=1$, where $[\cdot]$ is the greatest integer

function, then $\mathrm{p}+\mathrm{q}+\mathrm{r}$ is equal to

The radius of the smallest circle which touches the parabolas $\mathrm{y}=\mathrm{x}^{2}+2$ and $\mathrm{x}=\mathrm{y}^{2}+2$ is

Let $f(\mathrm{x})=\left\{\begin{array}{lll}(1+\mathrm{ax})^{1 / \mathrm{x}} & , & \mathrm{x}<0\\ 1+\mathrm{b} & , & \mathrm{x}=0\\ \frac{(\mathrm{x}+4)^{1 / 2}-2}{(\mathrm{x}+\mathrm{c})^{1 / 3}-2} & , & \mathrm{x}>0\end{array}\right.$ be continuous at $\mathrm{x}=0$. Then $\mathrm{e}^{\mathrm{a}} \mathrm{bc}$ is equal to

Line $L_{1}$ passes through the point $(1,2,3)$ and is parallel to z-axis. Line $\mathrm{L}_{2}$ passes through the point $(\lambda, 5,6)$

and is parallel to $y$-axis. Let for $\lambda=\lambda_{1}, \lambda_{2}, \lambda_{2}<\lambda_{1}$, the shortest distance between the two lines be 3 . Then the square of the distance of the point $\left(\lambda_{1}, \lambda_{2}, 7\right)$ from the line $L_{1}$ is

All five letter words are made using all the letters A, B, C, D, E and arranged as in an English dictionary with serial

numbers. Let the word at serial number $n$ be denoted by $W_{n}$. Let the probability $\mathrm{P}\left(\mathrm{W}_{\mathrm{n}}\right)$ of choosing the word

$\mathrm{W}_{\mathrm{n}}$ satisfy $\mathrm{P}\left(\mathrm{W}_{\mathrm{n}}\right)=2 \mathrm{P}\left(\mathrm{W}_{\mathrm{n}-1}\right), \mathrm{n}>1$. If $\mathrm{P}(\mathrm{CDBEA})=\frac{2^{\alpha}}{2^{\beta}-1}, \alpha, \beta \in \mathbb{N}$, then $\alpha+\beta$ is

equal to: $\_\_\_\_\_$

Let the product of the focal distances of the point $\mathrm{P}(4,2 \sqrt{3})$ on the hyperbola $\mathrm{H}: \frac{\mathrm{x}^{2}}{\mathrm{a}^{2}}-\frac{\mathrm{y}^{2}}{\mathrm{~b}^{2}}=1$ be 32.

Let the length of the conjugate axis of H be p and the length of its latus rectum be q . Then $\mathrm{p}^{2}+\mathrm{q}^{2}$ is equal to ......

Let $\vec{a}=\hat{i}+\hat{j}+\hat{k}, \vec{b}=3 \hat{i}+2 \hat{j}-\hat{k}, \vec{c}=\lambda \hat{j}+\mu \hat{k}$ and $\hat{d}$ be a unit vector such that $\vec{a} \times \hat{d}=\vec{b} \times \hat{d}$ and

$\vec{c} . \hat{d}=1$, If $\vec{c}$ is perpendicular to $\vec{a}$, then $|3 \lambda \hat{d}+\mu \vec{c}|^{2}$ is equal to $\_\_\_\_\_$ .

If the number of seven-digit numbers, such that the sum of their digits is even, is $m \cdot n \cdot 10^{\mathrm{n}}$;

$m, n \in\{1,2,3, \ldots, 9\}$, then $m+n$ is equal to

The area of the region bounded by the curve $y=\max \{|x|, x|x-2|\}$, then $x$-axis and the lines $\mathrm{x}=-2$ and $\mathrm{x}=4$ is equal to $\_\_\_\_\_$ .

Match the List-I with List-II Choose the correct answer from the options given below:

A particle is released from height $S$ above the surface of the earth. At certain height its kinetic energy is three times its potential energy. The height from the surface of the earth and the speed of the particle at that instant are respectively.

Consider following statements for refraction of light through prism, when angle of deviation is minimum.

A. The refracted ray inside prism becomes parallel to the base.

B. Larger angle prisms provide smaller angle of minimum deviation.

C. Angle of incidence and angle of emergence becomes equal.

D. There are always two sets of angle of incidence for which deviation will be same except at minimum deviation setting.

E. Angle of refraction becomes double of prism angle.

Choose the correct answer from the options given below:

The radiation pressure exerted by a 450 W light source on a perfectly reflecting surface placed at 2 m away from it, is

A parallel plate capacitor is filled equally (half) with two dielectrics of dielectric constants $\varepsilon_{1}$ and $\varepsilon_{2}$, as shown in figures. The distance between the plates is $d$ and area of each plate is $A$. If capacitance in first configuration and second configuration are $C_{1}$ and $C_{2}$ respectively, then $\frac{C_{1}}{C_{2}}$ is

A person measures mass of 3 different particles as $435.42 \mathrm{~g}, 226.3 \mathrm{~g}$ and 0.125 g . According to the rules for arithmetic operations with significant figures, the addition of the masses of 3 particles will be

During the melting of a slab of ice at 273 K at atmospheric pressure:

The work function of a metal is 3 eV . The color of the visible light that is required to cause emission of photoelectrons is

Match the List-I with List-II Choose the correct answer from the options given below:

A force of 49 N acts tangentially at the highest point of a sphere (solid) of mass 20 kg , kept on a rough horizontal plane. If the sphere rolls without slipping, then the acceleration of the center of the sphere is

Choose the correct logic circuit for the given truth table having inputs $A$ and $B$.

The electrostatic potential on the surface of uniformly charged spherical shell of radius $R=10 \mathrm{~cm}$ is 120 V . The potential at the centre of shell, at a distance $r=5$ cm from centre, and at a distance $r=15 \mathrm{~cm}$ from the centre of the shell respectively, are:

Consider a completely full cylindrical water tank of height 1.6 m and of cross-sectional area $0.5 \mathrm{~m}^{2}$. It has a small hole in its side at a height 90 cm from the bottom. Assume, the cross-sectional area of the hole to be negligibly small as compared to that of the water tank. If a load 50 kg is applied at the top surface of the water in the tank then the velocity of the water coming out at the instant when the hole is opened is: ( $g=10 \mathrm{~m} / \mathrm{s}^{2}$ )

A gas is kept in a container having walls which are thermally non-conducting. Initially the gas has a volume of $800 \mathrm{~cm}^{3}$ and temperature $27^{\circ} \mathrm{C}$. The change in temperature when the gas is adiabatically compressed to $200 \mathrm{~cm}^{3}$ is : (Take $\gamma=1.5$; $\gamma$ is the ratio of specific heats at constant pressure and at constant volume)

Two blocks of masses $m$ and $M,(M>m)$ are placed on a frictionless table as shown in figure. A massless spring with spring constant $k$ is attached with the lower block. If the system is slightly displaced and released, then ( $\mu=$ coefficient of friction between the two blocks)

A. The time period of small oscillation of the two blocks is $T=2 \pi \sqrt{\frac{(m+M)}{k}}$

B. The acceleration of the blocks is $a=-\frac{k x}{M+m}$ ( $x=$ displacement of the blocks from the mean position)

C. The magnitude of the frictional force on the upper block is $\frac{m \mu|x|}{M+m}$

D. The maximum amplitude of the upper block, if it does not slip, is $\frac{\mu(M+m) g}{k}$ E. Maximum frictional force can be $\mu(M+m) g$ Choose the correct answer from the options given below :

The radii of curvature for a thin convex lens are 10 cm and 15 cm respectively. The focal length of the lens is 12 cm . The refractive index of the lens material is

Which of the following curves possibly represent onedimensional motion of a particle? Choose the correct answer from the options given below :

A.

B.

A wire of length 25 m and cross-sectional area $5 \mathrm{~mm}^{2}$ having resistivity $2 \times 10^{-6} \Omega \mathrm{~m}$ is bent into a complete circle. The resistance between diametrically opposite points will be

A loop $A B C D A$, carrying current $I=12 \mathrm{~A}$, is placed in a plane,

consists of two semi-circular segments of radius

$R_{1}=6 \pi \mathrm{~m}$ and $R_{2}=4 \pi \mathrm{~m}$.

The magnitude of the resultant magnetic field at center $O$ is $k \times 10^{-7} \mathrm{~T}$.

The value of $k$ is $\qquad$ .

(Given $\mu_{0}=4 \pi \times 10^{-7} \mathrm{Tm} \mathrm{A}^{-1}$ )

In the figure shown below, a resistance of $150.4 \Omega$ is connected in series to an ammeter A of resistance $240 \Omega$. A shunt resistance of $10 \Omega$ is connected in parallel with the ammeter. The reading of the ammeter is $\qquad$ mA .

Three identical spheres of mass $m$, are placed at the vertices of an equilateral triangle of length $a$.

When released, they interact only through gravitational force and collide after a time $T=4$ seconds.

If the sides of the triangle are increased to length $2 a$ and also the masses of the spheres are

made $2 m$, then they will collide after $\qquad$ seconds.

Two coherent monochromatic light beams of intensities $4 /$ and $9 /$ are superimposed. The difference between the maximum and minimum intensities in the resulting interference pattern is $x$ I. The value of $x$ is

A 4.0 cm long straight wire carrying a current of 8 A is placed perpendicular to a uniform magnetic field of strength 0.15 T . The magnetic force on the wire is $\qquad$ mN .