Chemistry · Solutions and Colligative Properties

JEE Main 2025 — 3 April, Morning Shift — Question 1

22 moles each of ethylene glycol and glucose are dissolved in 500 g500\,\mathrm{g} of water. The boiling point of the resulting solution is:

(Given: Kb=0.52 K kg mol−1K_b = 0.52\,\mathrm{K\,kg\,mol^{-1}})

  1. Option A:

    377.3 K

    Correct
  2. Option B:

    375.3 K

  3. Option C:

    379.2 K

  4. Option D:

    277.3 K

Answer: A

Step-by-step solution

Both ethylene glycol and glucose are non-electrolytes, so i=1i=1 for each.

Total moles of solute = 2+2=4 mol2+2=4\,\mathrm{mol}

Mass of solvent = 500 g=0.5 kg500\,\mathrm{g}=0.5\,\mathrm{kg}

Molality: m=40.5=8 mol kg−1m=\frac{4}{0.5}=8\,\mathrm{mol\,kg^{-1}}

Elevation in boiling point: ΔTb=Kb⋅m=0.52×8=4.16 K\Delta T_b = K_b \cdot m = 0.52 \times 8 = 4.16\,\mathrm{K}

Boiling point of solution: Tb=373 K+4.16 K=377.16 K≈377.3 KT_b = 373\,\mathrm{K} + 4.16\,\mathrm{K} = 377.16\,\mathrm{K} \approx 377.3\,\mathrm{K}

Answer key and solution verified before publishing.

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Exam
JEE Main 2025
Subject
Chemistry
Chapter
Solutions and Colligative Properties
Topic
Abnormal Colligative Properties - van't Hoff Factor
2 moles each of ethylene glycol and glucose are dissolved in 500\, g… | JEE Main 2025 PYQ with Solution · DhiX AI