JEE Main 2025 — 3 April, Evening Shift

Given below are two statements : one is labelled as Statement I and the other is labelled as Statement II:

Statement I: Hyperconjugation is not a permanent effect.

Statement II: In general, greater the number of alkyl groups attached to a positively charged C -atom, greater is the hyperconjugation interaction and stabilization of the cation.

In the light of the above statements, choose the correct answer from the options given below :

Identify the diamagnetic octahedral complex ions from below :

A. $\left[\mathrm{Mn}(\mathrm{CN})_{6}\right]^{3-}$

B. $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}$

C. $\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{4-}$

D. $\left[\mathrm{Co}\left(\mathrm{H}_{2} \mathrm{O}\right)_{3} \mathrm{~F}_{3}\right]$

Choose the correct answer from the options given below.

Given below are two statements : one is labelled as Statement I and the other is labelled as Statement II:

Statement I: When a system containing ice in equilibrium with water (liquid) is heated, heat is absorbed by the system and there is no change in the temperature of the system until whole ice gets melted.

Statement II: At melting point of ice, there is absorption of heat in order to overcome intermolecular forces of attraction within the molecules of water in ice and kinetic energy of molecules is not increased at melting point.

In the light of the above statements, choose the correct answer from the options given below :

Given below are two statements : one is labelled as Statement I and the other is labelled as Statement II:

Statement I: Wet cotton clothes made of cellulose based carbohydrate takes comparatively longer time to get dried than wet nylon polymer based clothes.

Statement II: Intermolecular hydrogen bonding with water molecule is more in nylon-based clothes than in the case of cotton clothes.

In the light of the above statements, choose the correct answer from the options given below :

Given below are two statements : one is labelled as Statement I and the other is labelled as Statement II:

Statement I: $\mathrm{CrO}_{3}$ is a stronger oxidizing agent than $\mathrm{MoO}_{3}$

Statement II: $\mathrm{Cr}(\mathrm{VI})$ is more stable than $\mathrm{Mo}(\mathrm{VI})$

In the light of the above statements, choose the correct answer from the options given below :

Mass of magnesium required to produce 220 mL of hydrogen gas at STP on reaction with excess of dil. HCl is Given: Molar mass of $\mathrm{Mg}^{\text {is }} 24 \mathrm{~g} \mathrm{~mol}^{-1}$.

Compounds that should not be used as primary standards in titrimetric analysis are :

A. $\mathrm{Na}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}$

B. Oxalic acid

C. NaOH

D. $\mathrm{FeSO}_{4} .6 \mathrm{H}_{2} \mathrm{O}$

E. Sodium tetraborate

Choose the most appropriate answer from the options given below:

Consider the following statements related to temperature dependence of rate constants. Identify the correct statements.

A. The Arrhenius equation holds true only for an elementary homogenous reaction.

B. The unit of $A$ is same as that of $k$ in Arrhenius equation.

C. At a given temperature, a low activation energy means a fast reaction.

D. A and Ea as used in Arrhenius equation depend on temperature.

E. When Ea >> RT, A and Ea become interdependent.

Choose the correct answer from the options given below.

In Dumas' method for estimation of nitrogen 0.4 g of an organic compound gave 60 mL of nitrogen collected at 300 K temperature and 715 mm Hg pressure. The percentage composition of nitrogen in the compound is (Given : Aqueous tension at $300 \mathrm{~K}=15 \mathrm{~mm} \mathrm{Hg}$ )

The standard cell potential ($E^\circ_{\text{cell}}$) of a fuel cell based on the oxidation of methanol in air is measured as 1.21 V. The standard half-cell reduction potential for $\text{O}_2$ ($E^\circ_{\text{O}_2/\text{H}_2\text{O}}$) is 1.229 V. Choose the correct statement:

The correct orders among the following are

Atomic radius: $\mathrm{B}<\mathrm{Al}<\mathrm{Ga}<\mathrm{In}<\mathrm{Tl}$

Electronegativity : $\mathrm{Al}<\mathrm{Ga}<\mathrm{In}<\mathrm{Tl}<\mathrm{B}$

Density : $\mathrm{Tl}<\mathrm{In}<\mathrm{Ga}<\mathrm{Al}<\mathrm{B}$

$1^{\text {st }}$ Ionisation energy : $\mathrm{In}<\mathrm{Al}<\mathrm{Ga}<\mathrm{Tl}<\mathrm{B}$

Choose the correct answer from the options given below :

Fat soluble vitamins are:

(A) Vitamin $\mathrm{B}_{1}$

(B) Vitamin $\mathrm{C}$

(C) Vitamin $\mathrm{E}$

(D) Vitamin $\mathrm{B}_{12}$

(E) Vitamin $\mathrm{K}$

Choose the correct answer from the options given below:

Match the List-I with List-II.

Choose the correct answer from the options given below.

10 mL of 2 M NaOH solution is added to 20 mL of 1 M HCl solution kept in a beaker. Now, 10 mL of this mixture is poured into a volumetric flask of 100 mL containing 2 moles of HCl and made the volume upto the mark with distilled water. The solution in this flask.

For electrons in ' $2s$ ' and ' $2p$ ' orbitals, the orbital angular momentum values, respectively, are

X g of nitrobenzene on nitration gave 4.2 g of m -dinitrobenzene. $\mathrm{X}=$ $\_\_\_\_\_$ g. (nearest integer) [Given: molar mass (in $\mathrm{g} \mathrm{mol}^{-1}$ ) C: 12, H: 1, O: 16, N: 14]

A sample of n-octane ( 1.14 g ) was completely burnt in excess of oxygen in a bomb calorimeter, whose heat capacity is $5 \mathrm{~kJ} \mathrm{~K}^{-1}$. As a result of combustion reaction, the temperature of the calorimeter is increased by 5 K . The magnitude of the heat of combustion of octane at constant volume is $\_\_\_\_\_$ $\mathrm{kJ} \mathrm{mol}^{-1}$ (nearest integer).

A perfect gas ( 0.1 mol ) having $\overline{\mathrm{C}}_{\mathrm{v}}=1.50 \mathrm{R}$ (independent of temperature) undergoes the above transformation

from point 1 to point 4. If each step is reversible, the total work done (w) while going from point 1 to point 4 is (-)

$\_\_\_\_\_$ J (nearest integer) [Given: $\mathrm{R}=0.082 \mathrm{~L} \mathrm{~atm} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}$ ]

Among, $\mathrm{Sc}, \mathrm{Mn}, \mathrm{Co}$ and Cu , identify the element with highest enthalpy of atomisation. The spin only magnetic moment value of that element in its +2 oxidation state is $\_\_\_\_\_$ $B M$ (in nearest integer).

The total number of structural isomers possible for the substituted benzene derivatives with the molecular formula $\mathrm{C}_{9} \mathrm{H}_{12}$ is $\_\_\_\_\_$ .

Line $L_{1}$ of slope 2 and line $L_{2}$ of slope $\frac{1}{2}$ intersect at the origin $O$. In the first quadrant, $P_{1}, P_{2} \ldots P_{12}$ are

12 points on line $L_{1}$ and $Q_{1}, Q_{2} \ldots, Q_{9}$ are 9 points on line $L_{2}$. Then the total number of triangles, that can

be formed having vertices at three of the 22 points $O, P_{1}, P_{2} \ldots, P_{12}, Q_{1} Q_{2}, \ldots . Q_{9}$, is:

Let the Mean and Variance of five observations $x_{1}=$ $1, x_{2}=3, x_{3}=a, x_{4}=7$ and $x_{5}=b, a>b$, be

5 and 10 respectively. Then the Variance of the observations $n+x_{n}, n=1.2, \ldots, 5$ is

Let the equation $x(x+2)(12-k)=2$ have equal roots. Then the distance of the point $\left(k, \frac{k}{2}\right)$ from the line $3 x+4 y+5=0$ is

The integral $\int_{0}^{\pi} \frac{8 x d x}{4 \cos ^{2} x+\sin ^{2} x}$ is equal to

If the domain of the function $f(x)=\log _{7}\left(1-\log _{4}\left(x^{2}-\right.\right.$ $9 x+18)$ ) is $(\alpha, \beta) \cup(\gamma, \delta)$, then $\alpha+\beta+\gamma+\delta$ is equal to

Let $f: R \rightarrow R$ be a function defined by $f(x)=\| x+2 \mid$ $-2 \mid x \|$. If $m$ is the number of points of local minima and n is the number of points of local maxima of $f$, then $m+n$ is :

If the probability that the random variable $X$ takes the value $x$ is given by

$P(X=x)=k(x+1) 3^{-x}, x=0,1,2,3 \ldots$, where $k$ is a constant, then $P(X \geq 3)$ is equal to

Each of the angles $\beta$ and $\gamma$ that a given line makes with the positive $y$ - and $z$-axes, respectively, is half of the angle that this line makes with the positive $x$-axes. Then the sum of all possible values of the angle $\beta$ is

If the four distinct points $(4,6),(-1,5),(0,0)$ and $(k, 3 k)$ lie on a circle of radius $r$, then $10 k+r^{2}$ is equal to

The sum $1+\frac{1+3}{2!}+\frac{1+3+5}{3!}+\frac{1+3+5+7}{4!}+\ldots$ upto $\infty$ terms, is equal to

Let $f$ be a function such that $f(x)+3 f\left(\frac{24}{x}\right)=4 x$, $x \neq 0$. Then $f(3)+f(8)$ is equal to

The number of solutions of the equation $(4-\sqrt{3}) \sin x-2 \sqrt{3} \cos ^{2} x=-\frac{4}{1+\sqrt{3}}, x \in\left[-2 \pi, \frac{5 \pi}{2}\right]$

is

The shortest distance between the curves $y^{2}=8 x$ and $x^{2}+y^{2}+12 y+35=0$ is:

Let $A=\{-2,-1,0,1,2,3\}$. Let $R$ be a relation on $A$ defined by $x R y$ if and only if $y=\max \{x, 1\}$. Let $/$ be the number of elements in $R$. Let $m$ and $n$ be the minimum number of elements required to be added in $R$ to make it reflexive and symmetric relations, respectively. Then $I+m+n$ is equal to

The distance of the point $(7,10,11)$ from the line $\frac{x-4}{1}=\frac{y-4}{0}=\frac{z-2}{3} \quad$ along the line

$\frac{x-9}{2}=\frac{y-13}{3}=\frac{z-17}{6}$ is

Consider the lines $x(3 \lambda+1)+y(7 \lambda+2)=17 \lambda+5$, $\lambda$ being a parameter, all passing through a point $P$.

One of these lines (say $L$ ) is farthest from the origin. If the distance of $L$ from the point $(3,6)$ is $d$, then the

value of $d^{2}$ is

If $z_{1}, z_{2}, z_{3} \in \mathbb{C}$ are the vertices of an equilateral triangle, whose centroid is $z_{0}$, then $\sum_{k=1}^{3}\left(z_{k}-z_{0}\right)^{2}$

is equal to

The area of the region $\{(x, y):|x-y| \leq y \leq 4 \sqrt{x}\}$ is

Let $y=y(x)$ be the solution of the differential equation $\frac{d y}{d x}+3\left(\tan ^{2} x\right) y+3 y=\sec ^{2} x,$

$y(0)=\frac{1}{3}+e^{3}$. Then $y\left(\frac{\pi}{4}\right)$ is equal to

Let $C$ be the circle of minimum area enclosing the ellipse $E: \frac{x^{2}}{a^{2}}+\frac{y^{2}}{b^{2}}=1$ with eccentricity $\frac{1}{2}$ and foci $( \pm 2,0)$. Let $P Q R$ be a variable triangle, whose vertex $P$ is on the circle $C$ and the side $Q R$ of length 2 a is parallel to the major axis of $E$ and contains the point of intersection of $E$ with the negative $y$-axis. Then the maximum area of the triangle $P Q R$ is:

If the equation of the hyperbola with foci $(4,2)$ and $(8,2)$ is $3 x^{2}-y^{2}-\alpha x+\beta y+\gamma=0$, then

$\alpha+\beta+\gamma$ is equal to $\qquad$ -.

Let $I$ be the identity matrix of order $3 \times 3$ and for the matrix $A=\left[\begin{array}{ccc}\lambda & 2 & 3\\ 4 & 5 & 6\\ 7 & -1 & 2\end{array}\right],|A|=-1$. Let $B$ be the

inverse of the matrix $\operatorname{adj}\left(A \operatorname{adj}\left(A^{2}\right)\right)$. Then $|\lambda(B+1)|$ is equal to $\qquad$ .

If $\lim _{x \rightarrow 0}\left(\frac{\tan x}{x}\right)^{\frac{1}{x^{2}}}=p$, then $96 \log _{e} p$ is equal to

Let $\vec{a}=\hat{i}+2 \hat{j}+\hat{k}, \vec{b}=3 \hat{i}-3 \hat{j}+3 \hat{k}, \vec{c}=2 \hat{i}-\hat{j}+2 \hat{k}$ and $\vec{d}$ be a vector such that $\vec{b} \times \vec{d}=\vec{c} \times \vec{d}$

and $\vec{a} \cdot \vec{d}=4$. Then $|(\vec{a} \times \vec{d})|^{2}$ is equal to $\_\_\_\_$ -.

Let $\left(1+x+x^{2}\right)^{10}=a_{0}+a_{1} x+a_{2} x^{2}+\ldots+a_{20} x^{20}$. If

$\left(a_{1}+a_{3}+a_{5}+\ldots+a_{19}\right)-11 a_{2}=121 k$, then $k$ is equal to $\_\_\_\_$ .

A magnetic dipole experiences a torque of $80 \sqrt{3} \mathrm{~N} \mathrm{~m}$ when placed in uniform magnetic field in such a way that dipole moment makes angle of $60^{\circ}$ with magnetic field. The potential energy of the dipole is :

Consider two blocks $A$ and $B$ of masses $m_{1}=10 \mathrm{~kg}$ and $m_{2}=5 \mathrm{~kg}$ that are placed on a frictionless table. The block $A$ moves with a constant speed $v=3 \mathrm{~m} / \mathrm{s}$ towards the block $B$ kept at rest. A spring with spring constant $k=3000 \mathrm{~N} / \mathrm{m}$ is attached with the block $B$ as shown in the figure. After the collision, suppose that the blocks $A$ and $B$, along with the spring in constant compression state, move together, then the compression in the spring is, (Neglect the mass of the spring)

An ideal gas exists in a state with pressure $P_{0}$, volume $V_{0}$. It is isothermally expanded to 4 times of its initial volume $\left(V_{0}\right)$, then isobarically compressed to its original volume. Finally the system is heated isochorically to bring it to its initial state. The amount of heat exchanged in this process is

A particle is projected with velocity $u$ so that its horizontal range is three times the maximum height attained by it. The horizontal range of the projectile is given as $\frac{n u^{2}}{25 g}$, where value of $n$ is : (Given, ' $g$ ' is the acceleration due to gravity.)

A monochromatic light of frequency $5 \times 10^{14} \mathrm{~Hz}$ travelling through air, is incident on a medium of refractive index '2'. Wavelength of the refracted light will be :

A block of mass 1 kg , moving along $x$ with speed $v_{i}=10 \mathrm{~m} / \mathrm{s}$ enters a rough region ranging from $x=0.1 \mathrm{~m}$ to $x=1.9 \mathrm{~m}$. The retarding force acting on the block in this range is $F_{r}=-k x \mathrm{~N}$, with $k=10$ $\mathrm{N} / \mathrm{m}$. Then the final speed of the block as it crosses rough region is.

The truth table corresponding to the circuit given below is :

Two monochromatic light beams have intensities in the ratio $1: 9$. An interference pattern is obtained by these beams. The ratio of the intensities of maximum to minimum is

In the resonance experiment, two air columns (closed at one end) of 100 cm and 120 cm long, give 15 beats per second when each one is sounding in the respective fundamental modes. The velocity of sound in the air column is

Width of one of the two slits in a Young's double slit interference experiment is half of the other slit. The ratio of the maximum to the minimum intensity in the interference pattern is

Given below are two statements: one is labelled as Assertion $\mathbf{A}$ and the other is labelled as Reason $\mathbf{R}$

Assertion A : If Oxygen ion $\left(\mathrm{O}^{-2}\right)$ and Hydrogen ion $\left(\mathrm{H}^{+}\right)$enter normal to the magnetic field with equal momentum, then the path of $\mathrm{O}^{-2}$ ion has a smaller curvature than that of $\mathrm{H}^{+}$.

Reason R:A proton with same linear momentum as an electron will form a path of smaller radius of curvature on entering a uniform magnetic field perpendicularly.

In the light of the above statements, choose the correct answer from the options given below

An electric bulb rated as $100 \mathrm{~W}-220 \mathrm{~V}$ is connected to an ac source of rms

voltage 220 V . The peak value of current through the bulb is

Match the LIST-I with LIST-II. Choose the correct answer from the options given below.

Using a battery, a 100 pF capacitor is charged to 60 V and then the battery is removed. After that, a second uncharged capacitor is connected to the first capacitor in parallel. If the final voltage across the second capacitor is 20 V , its capacitance is: (in pF )

A particle moves along the $x$-axis and has its displacement $x$ varying with time $t$ according

to the equation: $x=c_{0}\left(t^{2}-2\right)+c(t-2)^{2}$ Where co and cone constants

of appropriate dimensions.

Then, which of the following statements is correct?

A motor operating on 100 V draws a current of 1 A . If the efficiency of the motor is $91.6 \%$, then the loss of power in units of cal/s is

Two cylindrical vessels of equal cross sectional area of $2 \mathrm{~m}^{2}$ contain water upto heights 10 m and 6 m , respectively If the vessels are connected at their bottom then the work done by the force of gravity is (Density of water is $10^{3} \mathrm{~kg} / \mathrm{m}^{3}$ and $g=10 \mathrm{~m} / \mathrm{s}^{2}$ )

A solid steel ball of diameter 3.6 mm acquired terminal velocity $2.45 \times 10^{-2} \mathrm{~m} / \mathrm{s}$ while falling under gravity through an oil of density $925 \mathrm{~kg} \mathrm{~m}^{-3}$. Take density of steel as $7825 \mathrm{~kg} \mathrm{~m}^{-3}$ and $g$ as $9.8 \mathrm{~m} / \mathrm{s}^{2}$. The viscosity of the oil in SI unit is

Pressure of an ideal gas, contained in a closed vessel, is increased by $0.4 \%$ when heated by $1^{\circ} \mathrm{C}$. Its initial temperature must be:

Two cells of emfs 1 V and 2 V and internal resistances $2 \Omega$ and $1 \Omega$, respectively, are connected in series with an external resistance of $6 \Omega$. The total current in the circuit is $\Lambda_{1}$. Now the same two cells in parallel configuration are connected to same external resistance. In this case, the total current drawn is $I_{2}$. The value of $\left(\frac{l_{1}}{l_{2}}\right)$ is $\frac{x}{3}$. The value of $x$ is

An electron in the hydrogen atom initially in the fourth excited state makes a transition to $\mathrm{n}^{\text {th }}$ energy state by emitting a photon of energy 2.86 eV . The integer value of $n$ will be $\qquad$ .

A physical quantity $C$ is related to four other quantities $p, q, r$ and $s$ as follows $C=\frac{p q^{2}}{r^{3} \sqrt{s}}$.

The percentage errors in the measurement of $p, q, r$ and $s$ are $1 \%, 2 \%, 3 \%$ and $2 \%$,

respectively. The percentage error in the measurement of $C$ will be $\qquad$ $\%$.

Light from a point source in air falls on a spherical glass surface (refractive index, $\mu=1.5$ and radius of curvature $=50 \mathrm{~cm}$ ). The image is formed at a distance of 200 cm from the glass surface inside the glass. The magnitude of distance of the light source from the glass surface is $\qquad$ m.

The excess pressure inside a soap bubble $A$ in air is half the excess pressure inside another soap bubble

$B$ in air. If the volume of the bubble $A$ is $n$ times the volume of the bubble $B$, then, the value of $n$ is