JEE Main 2025 · previous year paper

JEE Main 2025 — 23 January, Morning Shift

67 questions with the verified answer key. Open any question for its step-by-step solution.

  1. Question 1Mathematics· Definite Integration

    The value of ∫e2e41x(e((log⁡ex)2+1)−1e((log⁡ex)2+1)−1+e((6−log⁡ex)2+1)−1)dx\int_{e^{2}}^{e^{4}} \frac{1}{x}\left(\frac{e^{\left(\left(\log _{e} x\right)^{2}+1\right)^{-1}}}{e^{\left(\left(\log _{e} x\right)^{2}+1\right)^{-1}}+e^{\left(\left(6-\log _{e} x\right)^{2}+1\right)^{-1}}}\right) d x is

    1. Option A:

      log⁡e2\log _{e} 2

    2. Option B:

      2

    3. Option C:

      1

    4. Option D:

      e2\mathrm{e}^{2}

  2. Question 2Mathematics· Indefinite Integration

    Let I(x)=∫dx(x−11)1113(x+15)1513\mathrm{I}(\mathrm{x})=\int \frac{\mathrm{dx}}{(\mathrm{x}-11)^{\frac{11}{13}}(\mathrm{x}+15)^{\frac{15}{13}}}. If I(37)−I(24)=14(1 b113−1c113),b,c∈N\mathrm{I}(37)-\mathrm{I}(24)=\frac{1}{4}\left(\frac{1}{\mathrm{~b}^{\frac{1}{13}}}-\frac{1}{\mathrm{c}^{\frac{1}{13}}}\right), \mathrm{b}, \mathrm{c} \in \mathbb{N}, then 3(b+c)3(b+c) is equal to

    1. Option A:

      40

    2. Option B:

      39

    3. Option C:

      22

    4. Option D:

      26

  3. Question 3Mathematics· Limits, Continuity and Differentiability

    If the function

    f(x)={2x{sin⁡(k1+1)x+sin⁡(k2−1)x},x<04,x=02xlog⁡e(2+k1x2+k2x),x>0f(x) = \begin{cases} \frac{2}{x} \{\sin(k_1+1)x + \sin(k_2-1)x\}, & x < 0 \\ 4, & x = 0 \\ \frac{2}{x} \log_e \left(\frac{2+k_1x}{2+k_2x}\right), & x > 0 \end{cases}

    is continuous at x=0\mathrm{x}=0, then k12+k22\mathrm{k}_{1}{ }^{2}+\mathrm{k}_{2}{ }^{2} is equal to

    1. Option A:

      8

    2. Option B:

      20

    3. Option C:

      5

    4. Option D:

      10

  4. Question 4Mathematics· Parabola

    If the line 3x−2y+12=03 x-2 y+12=0 intersects the parabola 4y=3x24 y=3 x^{2} at the points AA and BB, then at the vertex of the parabola, the line segment AB subtends an angle equal to

    1. Option A:

      tan⁡−1(119)\tan ^{-1}\left(\frac{11}{9}\right)

    2. Option B:

      π2−tan⁡−1(32)\frac{\pi}{2}-\tan ^{-1}\left(\frac{3}{2}\right)

    3. Option C:

      tan⁡−1(45)\tan ^{-1}\left(\frac{4}{5}\right)

    4. Option D:

      tan⁡−1(97)\tan ^{-1}\left(\frac{9}{7}\right)

  5. Question 5Mathematics· Differential Equations

    Let a curve y=f(x)y=f(x) pass through the points (0,5)(0,5) and (log⁡e2,k)\left(\log _{\mathrm{e}} 2, k\right). If the curve satisfies the differential

    equation 2(3+y)e2xdx−(7+e2x)dy=02(3+y) e^{2 x} d x-\left(7+e^{2 x}\right) d y=0, then kk is equal to

    1. Option A:

      16

    2. Option B:

      8

    3. Option C:

      32

    4. Option D:

      4

  6. Question 6Mathematics· Functions

    Let f(x)=log⁡exf(x)=\log _{e} x and g(x)=x4−2x3+3x2−2x+22x2−2x+1g(x)=\frac{x^{4}-2 x^{3}+3 x^{2}-2 x+2}{2 x^{2}-2 x+1} . Then the domain of fog is

    1. Option A:

      R\mathbb{R}

    2. Option B:

      (0,∞)(0, \infty)

    3. Option C:

      [0,∞)[0, \infty)

    4. Option D:

      [1,∞)[1, \infty)

  7. Question 7Mathematics· Circles

    Let the arc AC of a circle subtend a right angle at the centre OO. If the point BB on the arc ACA C, divides the arc AC

    such that  length of arc⁡AB length of arc⁡BC=15\frac{\text { length of } \operatorname{arc} \mathrm{AB}}{\text { length of } \operatorname{arc} \mathrm{BC}}=\frac{1}{5}, and OC→=αOA→+βOB→\overrightarrow{\mathrm{OC}}=\alpha \overrightarrow{\mathrm{OA}}+\beta \overrightarrow{\mathrm{OB}}, then α+2(3−1)β\alpha+\sqrt{2}(\sqrt{3}-1) \beta is equal to

    1. Option A:

      2−32-\sqrt{3}

    2. Option B:

      232 \sqrt{3}

    3. Option C:

      535 \sqrt{3}

    4. Option D:

      2+32+\sqrt{3}

  8. Question 8Mathematics· Sequence and Series

    If the first term of an A.P. is 3 and the sum of its first four terms is equal to one-fifth of the sum of the next four terms, then the sum of the first 20 terms is equal to

    1. Option A:

      −1200-1200

    2. Option B:

      −1080-1080

    3. Option C:

      −1020-1020

    4. Option D:

      −120-120

  9. Question 9Mathematics· Straight lines

    Let P be the foot of the perpendicular from the point Q(10,−3,−1)Q(10,-3,-1) on the line x−37=y−2−1=z+1−2\frac{x-3}{7}=\frac{y-2}{-1}=\frac{z+1}{-2}. Then the area of the right angled triangle PQR , where R is the point (3,−2,1)(3,-2,1), is

    1. Option A:

      9159 \sqrt{15}

    2. Option B:

      30\sqrt{30}

    3. Option C:

      8158 \sqrt{15}

    4. Option D:

      3303 \sqrt{30}

  10. Question 10Mathematics· Complex Numbers

    Let ∣zˉ−i2zˉ+i∣=13,z∈C\left|\frac{\bar{z}-i}{2 \bar{z}+i}\right|=\frac{1}{3}, z \in \mathbb{C}, be the equation of a circle with center at CC. If the area of the triangle, whose vertices are at the points (0,0),C(0,0), \mathrm{C} and (α,0)(\alpha, 0) is 11 square units, then α2\alpha^{2} equals

    1. Option A:

      100

    2. Option B:

      50

    3. Option C:

      12125\frac{121}{25}

    4. Option D:

      8125\frac{81}{25}

  11. Question 11Mathematics· Sets and Relations

    Let R={(1,2),(2,3),(3,3)}\mathrm{R}=\{(1,2),(2,3),(3,3)\} be a relation defined on the set {1,2,3,4}\{1,2,3,4\}. Then the minimum number of

    elements, needed to be added in R so the R becomes an equivalence relation, is :

    1. Option A:

      10

    2. Option B:

      8

    3. Option C:

      9

    4. Option D:

      7

  12. Question 12Mathematics· Permutations and Combinations

    The number of words, which can be formed using all the letters of the word "DAUGHTER", so that all the vowels never come together, is

    1. Option A:

      34000

    2. Option B:

      37000

    3. Option C:

      36000

    4. Option D:

      35000

  13. Question 13Mathematics· Straight lines

    Let the area of a △PQR\triangle P Q R with vertices P(5,4),Q(−2,4)P(5,4), Q(-2,4) and R(a,b)R(a, b) be 35 square units. If its orthocenter and centroid are O(2,145)O\left(2, \frac{14}{5}\right) and C(c,d)C(c, d) respectively, then c+2 d\mathrm{c}+2 \mathrm{~d} is equal to

    1. Option A:

      73\frac{7}{3}

    2. Option B:

      3

    3. Option C:

      2

    4. Option D:

      83\frac{8}{3}

  14. Question 14Mathematics· Inverse Trigonometric Functions

    If π2≤x≤3π4\frac{\pi}{2} \leq x \leq \frac{3 \pi}{4}, then cos⁡−1(1213cos⁡x+513sin⁡x)\cos ^{-1}\left(\frac{12}{13} \cos x+\frac{5}{13} \sin x\right)

    is equal to

    1. Option A:

      x−tan⁡−143x-\tan ^{-1} \frac{4}{3}

    2. Option B:

      x−tan⁡−1512x-\tan ^{-1} \frac{5}{12}

    3. Option C:

      x+tan⁡−145x+\tan ^{-1} \frac{4}{5}

    4. Option D:

      x+tan⁡−1512x+\tan ^{-1} \frac{5}{12}

  15. Question 15Mathematics· Trigonometry Ratios and Identities

    The value of (sin⁡70∘)(cot⁡10∘cot⁡70∘−1)\left(\sin 70^{\circ}\right)\left(\cot 10^{\circ} \cot 70^{\circ}-1\right) is

    1. Option A:

      1

    2. Option B:

      0

    3. Option C:

      3/23 / 2

    4. Option D:

      2/32 / 3

  16. Question 16Mathematics· Statistics

    Marks obtained by all the students of class 12 are presented in a frequency distribution with classes of equal width. Let the median of this grouped data be 14 with median class interval 12-18 and median class frequency 12 . If the number of students whose marks are less than 12 is 18 , then the total number of students is

    1. Option A:

      48

    2. Option B:

      44

    3. Option C:

      40

    4. Option D:

      52

  17. Question 17Mathematics· Vector Algebra

    Let the position vectors of the vertices A,BA, B and CC of a tetrahedron ABCDA B C D be i^+2j^+k^,i^+3j^−2k^\hat{i}+2 \hat{j}+\hat{k}, \hat{i}+3 \hat{j}-2 \hat{k} and 2i^+j^−k^2 \hat{i}+\hat{j}-\hat{k} respectively. The altitude from the vertex D to the opposite face ABC meets the median line segment through AA of the triangle ABCA B C at the point EE. If the length of ADA D is 1103\frac{\sqrt{110}}{3} and the volume of the tetrahedron is 80562\frac{\sqrt{805}}{6 \sqrt{2}}, then the position vector of E is

    1. Option A:

      12(i^+4j^+7k^)\frac{1}{2}(\hat{\mathrm{i}}+4 \hat{\mathrm{j}}+7 \hat{\mathrm{k}})

    2. Option B:

      112(7i^+4j^+3k^)\frac{1}{12}(7 \hat{i}+4 \hat{j}+3 \hat{k})

    3. Option C:

      16(12i^+12j^+k^)\frac{1}{6}(12 \hat{i}+12 \hat{j}+\hat{k})

    4. Option D:

      16(7i^+12j^+k^)\frac{1}{6}(7 \hat{i}+12 \hat{j}+\hat{k})

  18. Question 18Mathematics· Matrices

    If A,B\mathrm{A}, \mathrm{B} and (adj⁡(A−1)+adj⁡(B−1))\left(\operatorname{adj}\left(\mathrm{A}^{-1}\right)+\operatorname{adj}\left(\mathrm{B}^{-1}\right)\right) are non-singular matrices of same order, then the inverse of

    A(adj⁡(A−1)+adj⁡(B−1))−1 B\mathrm{A}\left(\operatorname{adj}\left(\mathrm{A}^{-1}\right)+\operatorname{adj}\left(\mathrm{B}^{-1}\right)\right)^{-1} \mathrm{~B}, is equal to

    1. Option A:

      AB−1+A−1 B\mathrm{AB}^{-1}+\mathrm{A}^{-1} \mathrm{~B}

    2. Option B:

      adj⁡(B−1)+adj⁡(A−1)\operatorname{adj}\left(\mathrm{B}^{-1}\right)+\operatorname{adj}\left(\mathrm{A}^{-1}\right)

    3. Option C:

      1∣AB∣(adj⁡(B)+adj⁡(A))\frac{1}{|\mathrm{AB}|}(\operatorname{adj}(\mathrm{B})+\operatorname{adj}(\mathrm{A}))

    4. Option D:

      AB−1∣A∣+BA−1∣B∣∣B∣\frac{A B^{-1}}{|A|}+\frac{{B A^{-1}}^{|B|}}{|B|}

  19. Question 19Mathematics· Matrices

    If the system of equations

    (λ−1)x+(λ−4)y+λz=5(\lambda-1) x+(\lambda-4) y+\lambda z=5

    λx+(λ−1)y+(λ−4)z=7\lambda x+(\lambda-1) y+(\lambda-4) z=7

    (λ+1)x+(λ+2)y−(λ+2)z=9(\lambda+1) x+(\lambda+2) y-(\lambda+2) z=9

    has infinitely many solutions, then λ2+λ\lambda^{2}+\lambda is equal to

    1. Option A:

      10

    2. Option B:

      12

    3. Option C:

      6

    4. Option D:

      20

  20. Question 20Mathematics· Probability

    One die has two faces marked 1 , two faces marked 2 , one face marked 3 and one face marked 4. Another die has one face marked 1, two faces marked 2, two faces marked 3 and one face marked 4. The probability of getting the sum of numbers to be 4 or 5 , when both the dice are thrown together, is

    1. Option A:

      12\frac{1}{2}

    2. Option B:

      35\frac{3}{5}

    3. Option C:

      23\frac{2}{3}

    4. Option D:

      49\frac{4}{9}

  21. Question 21Mathematics· Area under the Curves

    If the area of the larger portion bounded between the curves x2+y2=25x^{2}+y^{2}=25 and y=∣x−1∣y=|x-1| is 14(bπ+c)\frac{1}{4}(b \pi+c), b,c∈N\mathrm{b}, \mathrm{c} \in \mathbb{N}, then b+c\mathrm{b}+\mathrm{c} is equal to _____\_\_\_\_\_

  22. Question 22Mathematics· Binomial Theorem

    The sum of all rational terms in the expansion of (1+21/3+31/2)6\left(1+2^{1 / 3}+3^{1 / 2}\right)^{6} is equal to _____\_\_\_\_\_

  23. Question 23Mathematics· Circles

    Let the circle C touch the line x−y+1=0\mathrm{x}-\mathrm{y}+1=0, have the centre on the positive x -axis, and cut off a chord of length 413\frac{4}{\sqrt{13}} along the line −3x+2y=1-3 x+2 y=1. Let HH be the hyperbola x2α2−y2β2=1\frac{x^{2}}{\alpha^{2}}-\frac{y^{2}}{\beta^{2}}=1, whose one of the foci is the centre of CC and the length of the transverse axis is the diameter of C . Then 2α2+3β22 \alpha^{2}+3 \beta^{2} is equal to _____\_\_\_\_\_

  24. Question 24Mathematics· Quadratic Equations

    If the set of all values of aa, for which the equation 5x3−15x−a=05 x^{3}-15 x-a=0 has three distinct real roots, is the interval (α,β)(\alpha, \beta), then β−2α\beta-2 \alpha is equal to _____\_\_\_\_\_

  25. Question 25Mathematics· Quadratic Equations

    If the equation a(b−c)x2+b(c−a)x+c(a−b)=0a(b-c) x^{2}+b(c-a) x+c(a-b)=0 has equal roots, where a+c=15\mathrm{a}+\mathrm{c}=15 and

    b=365\mathrm{b}=\frac{36}{5}, then a2+c2\mathrm{a}^{2}+\mathrm{c}^{2} is equal to _____\_\_\_\_\_

  26. Question 26Chemistry· Periodicity of Elements and Periodic Properties

    The element that does not belong to the same period of the remaining elements (modern periodic table) is:

    1. Option A:

      Palladium

    2. Option B:

      Iridium

    3. Option C:

      Osmium

    4. Option D:

      Platinum

  27. Question 27Chemistry· Structure of Atom

    Heat treatment of muscular pain involves radiation of wavelength about 900 nm900\,\mathrm{nm}. Which spectral line of hydrogen atom is suitable?

    (Given: RH=105 cm−1R_H = 10^5\,\mathrm{cm^{-1}})

    1. Option A:

      Paschen series, ∞→3\infty \rightarrow 3

    2. Option B:

      Lyman series, ∞→1\infty \rightarrow 1

    3. Option C:

      Balmer series, ∞→2\infty \rightarrow 2

    4. Option D:

      Paschen series, 5→35 \rightarrow 3

  28. Question 28Chemistry· Periodicity of Elements and Periodic Properties

    The incorrect statements among the following is

    1. Option A:

      PH3\mathrm{PH}_{3} shows lower proton affinity than NH3\mathrm{NH}_{3}.

    2. Option B:

      PF3\mathrm{PF}_{3} exists but NF5\mathrm{NF}_{5} does not.

    3. Option C:

      NO2\mathrm{NO}_{2} can dimerise easily.

    4. Option D:

      SO2\mathrm{SO}_{2} can act as an oxidizing agent, but not as a reducing agent.

  29. Question 29Chemistry· Ionic Equilibrium

    CrCl3⋅xNH3\mathrm{CrCl}_{3} \cdot \mathrm{xNH}_{3} can exist as a complex. 0.1 molal aqueous solution of this complex shows a depression in freezing point of 0.558∘C0.558^{\circ} \mathrm{C}. Assuming 100%100 \% ionisation of this complex and coordination number of Cr is 6 , the complex will be (Given Kf=1.86 K kg mol−1\mathrm{K}_{\mathrm{f}}=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1} )

    1. Option A:

      [Cr(NH3)6]Cl3\left[\mathrm{Cr}\left(\mathrm{NH}_{3}\right)_{6}\right] \mathrm{Cl}_{3}

    2. Option B:

      [Cr(NH3)4Cl2]Cl\left[\mathrm{Cr}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{Cl}_{2}\right] \mathrm{Cl}

    3. Option C:

      [Cr(NH3)5Cl]Cl2\left[\mathrm{Cr}\left(\mathrm{NH}_{3}\right)_{5} \mathrm{Cl}\right] \mathrm{Cl}_{2}

    4. Option D:

      [Cr(NH3)3Cl3]\left[\mathrm{Cr}\left(\mathrm{NH}_{3}\right)_{3} \mathrm{Cl}_{3}\right]

  30. Question 30Chemistry· d and f Block Elements

    FeO42−→+2.0VFe3+→+0.8VFe2+→−0.5VFe0\mathrm{FeO_4^{2-}} \xrightarrow{+2.0V} \mathrm{Fe^{3+}} \xrightarrow{+0.8V} \mathrm{Fe^{2+}} \xrightarrow{-0.5V} \mathrm{Fe^{0}}

    In the above diagram, the standard electrode potentials are given in volts(over the arrow)

    The value of EFeO42−/Fe2+⊖ is \text{The value of } E^\ominus_{\mathrm{FeO_4^{2-}/Fe^{2+}}} \text{ is}

    1. Option A:

      1.7 V

    2. Option B:

      1.2 V

    3. Option C:

      2.1 V

    4. Option D:

      1.4 V

  31. Question 31Chemistry· Alkyl and Aryl Halides

    Match the LIST-I with LIST-II Choose the correct answer from the options given below:

    LIST-I Name reactionLIST-II Product obtainable
    A.Swarts reactionI.Ethyl benzene
    B.Sandmeyer‟s reactionII.Ethyl iodide
    C.Wurtz Fittig reactionIII.Cyanobenzene
    D.Finkelstein reactionIV.Ethyl fluoride
    1. Option A:

      A-II, B-III, C-I, D-IV

    2. Option B:

      A-IV, B-I, C-III, D-II

    3. Option C:

      A-IV, B-III, C-I, D-II

    4. Option D:

      A-II, B-I, C-III, D-IV

  32. Question 32Chemistry· Biomolecules

    Given below are two statements : one is labelled as Statement I and the other is labelled as Statement II :

    Statement I : Fructose does not contain an aldehydic group but still reduces Tollen's reagent

    Statement II : In the presence of base, fructose undergoes rearrangement to give glucose.

    In the light of the above statements, choose the correct answer from the options given below

    1. Option A:

      Statement I is false but Statement II is true

    2. Option B:

      Both Statement I and Statement II are true

    3. Option C:

      Both Statement I and Statement II are false

    4. Option D:

      Statement I is true but Statement II is false

  33. Question 33Chemistry· Some Basic Concepts of Chemistry (Mole Concept) + Stoichiometry

    After removing 102110^{21} molecules from an x mgx\,\mathrm{mg} sample of CO2\mathrm{CO_2}, 2.8×10−3 mol2.8 \times 10^{-3}\,\mathrm{mol} of CO2\mathrm{CO_2} is left. The mass of CO2\mathrm{CO_2} taken initially is:

    (NA=6.02×1023 mol−1)(N_A = 6.02 \times 10^{23}\,\mathrm{mol^{-1}})
    1. Option A:

      196.2 mg196.2\,\mathrm{mg}

    2. Option B:

      98.3 mg98.3\,\mathrm{mg}

    3. Option C:

      150.4 mg150.4\,\mathrm{mg}

    4. Option D:

      48.2 mg48.2\,\mathrm{mg}

  34. Question 34Chemistry· Thermodynamics & Thermochemistry

    Ice at −5∘C-5^{\circ} \mathrm{C} is heated to become vapor with temperature of 110∘C110^{\circ} \mathrm{C} at atmospheric pressure. The entropy change associated with this process can be obtained from :

    1. Option A:

      ∫268 K383 KCpdT+ΔHmelting 273+ΔHboiling 373\int_{268 \mathrm{~K}}^{383 \mathrm{~K}} \mathrm{C}_{\mathrm{p}} \mathrm{dT}+\frac{\Delta \mathrm{H}_{\text {melting }}}{273}+\frac{\Delta \mathrm{H}_{\text {boiling }}}{373}

    2. Option B:

      $\int_{268 \mathrm{~K}}^{273 \mathrm{~K}} \frac{\mathrm{C}{\mathrm{p}, \mathrm{m}}}{\mathrm{T}} \mathrm{dT}+\frac{\Delta \mathrm{H}{\mathrm{m}} \text {, fusion }}{\mathrm{T}{\mathrm{f}}}+\frac{\Delta \mathrm{H}{\mathrm{m}, \text { vaporisation }}}{\mathrm{T}{\mathrm{b}}}$$$+\int{273 \mathrm{~K}}^{373 \mathrm{~K}} \frac{\mathrm{C}{\mathrm{p}, \mathrm{~m}} \mathrm{dT}}{\mathrm{~T}}+\int{373 \mathrm{~K}}^{383 \mathrm{~K}} \frac{\mathrm{C}_{\mathrm{p}, \mathrm{~m}} \mathrm{dT}}{\mathrm{~T}}$$

    3. Option C:

      ∫268 K383 KCpdT+qrevT\int_{268 \mathrm{~K}}^{383 \mathrm{~K}} \mathrm{C}_{\mathrm{p}} \mathrm{dT}+\frac{\mathrm{q}_{\mathrm{rev}}}{\mathrm{T}}

    4. Option D:

      $\int_{268 \mathrm{~K}}^{273 \mathrm{~K}} \mathrm{C}{\mathrm{p}, \mathrm{m}} \mathrm{dT}+\frac{\Delta \mathrm{H}{\mathrm{m}} \text {, fusion }}{\mathrm{T}{\mathrm{f}}}+\frac{\Delta \mathrm{H}{\mathrm{m}, \text { vaporisation }}}{\mathrm{T}{\mathrm{b}}}$$$+\int{273 \mathrm{~K}}^{373 \mathrm{~K}} \mathrm{C}{\mathrm{p}, \mathrm{~m}} \mathrm{dT}+\int{373 \mathrm{~K}}^{383 \mathrm{~K}} \mathrm{C}_{\mathrm{p}, \mathrm{~m}} \mathrm{dT}$$

  35. Question 35Chemistry· Coordination Compounds

    The d-electronic configuration of an octahedral Co (II) complex having magnetic moment of 3.95 BM is :

    1. Option A:

      t2g6eg1t_{2 g}^{6} e_{g}^{1}

    2. Option B:

      t2g3eg0t_{2 g}^{3} e_{g}^{0}

    3. Option C:

      t2g5eg2t_{2 g}^{5} e_{g}^{2}

    4. Option D:

      e4t23e^{4} t_{2}^{3}

  36. Question 36Chemistry· Coordination Compounds

    The complex that shows Facial - Meridional isomerism is

    1. Option A:

      [Co(NH3)3Cl3]\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{3} \mathrm{Cl}_{3}\right]

    2. Option B:

      [Co(NH3)4Cl2]+\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{Cl}_{2}\right]^{+}

    3. Option C:

      [Co(en)3]3+\left[\mathrm{Co}(\mathrm{en})_{3}\right]^{3+}

    4. Option D:

      [Co(en)2Cl2]+\left[\mathrm{Co}(\mathrm{en})_{2} \mathrm{Cl}_{2}\right]^{+}

  37. Question 37Chemistry· General Organic Chemistry

    The correct stability order of the following species/molecules is :

    figure

    1. Option A:

      q>r>pq>r>p

    2. Option B:

      r>q>pr>q>p

    3. Option C:

      q>p>rq>p>r

    4. Option D:

      p>q>rp>q>r

  38. Question 38Chemistry· Isomerism

    Propane molecule on chlorination under photochemical condition gives two di-chloro products, " xx " and " yy ". Amongst " xx " and " yy ", " xx " is an optically active molecule. How many tri-chloro products (consider only structural isomers) will be obtained from " xx " when it is further treated with chlorine under the photochemical condition?

    1. Option A:

      4

    2. Option B:

      2

    3. Option C:

      5

    4. Option D:

      3

  39. Question 39Chemistry· Practical Organic Chemistry

    What amount of bromine will be required to convert 2 g of phenol into 2,4,62,4,6-tribromophenol ? (Given molar mass in gmol−1\mathrm{g} \mathrm{mol}^{-1} of C,H,O,Br\mathrm{C}, \mathrm{H}, \mathrm{O}, \mathrm{Br} are 12,1,16,8012,1,16,80 respectively)

    1. Option A:

      10.22 g

    2. Option B:

      6.0 g

    3. Option C:

      4.0 g

    4. Option D:

      20.44 g

  40. Question 40Chemistry· d and f Block Elements

    The correct set of ions (aqueous solution) with same colour from the following is :

    1. Option A:

      V2+,Cr3+,Mn3+\mathrm{V}^{2+}, \mathrm{Cr}^{3+}, \mathrm{Mn}^{3+}

    2. Option B:

      Zn2+,V3+,Fe3+\mathrm{Zn}^{2+}, \mathrm{V}^{3+}, \mathrm{Fe}^{3+}

    3. Option C:

      Ti4+,V4+,Mn2+\mathrm{Ti}^{4+}, \mathrm{V}^{4+}, \mathrm{Mn}^{2+}

    4. Option D:

      Sc3+,Ti3+,Cr2+\mathrm{Sc}^{3+}, \mathrm{Ti}^{3+}, \mathrm{Cr}^{2+}

  41. Question 41Chemistry· Practical Inorganic chemistry (Qualitative Analysis)

    Given below are two statements : one is labelled as Statement I and the other is labelled as Statement II :

    Statement I : In Lassaigne's test, the covalent organic molecules are transformed into ionic compounds.

    Statement II : The sodium fusion extract of an organic compound having N and S gives prussian blue colour with FeSO4\mathrm{FeSO}_{4} and Na4[Fe(CN)6]\mathrm{Na}_{4}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]

    In the light of the above statements, choose the correct answer from the options given below

    1. Option A:

      Both Statement I and Statement II are true

    2. Option B:

      Both Statement I and Statement II are false

    3. Option C:

      Statement I is false but Statement II is true

    4. Option D:

      Statement I is true but Statement II is false

  42. Question 42Chemistry· Ionic Equilibrium

    Which of the following happens when NH4OH\mathrm{NH}_{4} \mathrm{OH} is added gradually to the solution containing

    1MA2+1 \mathrm{M} \mathrm{A}^{2+} and 1MB3+1 \mathrm{M} \mathrm{B}^{3+} ions ?

    Given : Ksp [A(OH)2]=9×10−10\mathrm{K}_{\text {sp }}\left[\mathrm{A}(\mathrm{OH})_{2}\right]=9 \times 10^{-10} and

    Ksp[ B(OH)3]=27×10−18 at 298 K.\mathrm{K}_{\mathrm{sp}}\left[\mathrm{~B}(\mathrm{OH})_{3}\right]=27 \times 10^{-18} \text { at } 298 \mathrm{~K} .
    1. Option A:

      B(OH)3\mathrm{B}(\mathrm{OH})_{3} will precipitate before A(OH)2\mathrm{A}(\mathrm{OH})_{2}

    2. Option B:

      A(OH)2\mathrm{A}(\mathrm{OH})_{2} and B(OH)3\mathrm{B}(\mathrm{OH})_{3} will precipitate together

    3. Option C:

      A(OH)2\mathrm{A}(\mathrm{OH})_{2} will precipitate before B(OH)3\mathrm{B}(\mathrm{OH})_{3}

    4. Option D:

      Both A(OH)2\mathrm{A}(\mathrm{OH})_{2} and B(OH)3\mathrm{B}(\mathrm{OH})_{3} do not show precipitation with NH4OH\mathrm{NH}_{4} \mathrm{OH}

  43. Question 43Chemistry· Chemical Bonding

    Match the LIST-I with LIST-II

    LIST-I (Classification of molecules based on octet rule)LIST-II (Example)
    A.Molecules obeying octet ruleI.NO,NO2\text{NO},\text{N}{{\text{O}}_{2}}
    B.Molecules with incomplete octetII.BCl3,AlCl3\text{BC}{{\text{l}}_{3}},\text{AlC}{{\text{l}}_{3}}
    C.Molecules with incomplete octet with odd electronIII.H2SO4,PCl5{{\text{H}}_{2}}\text{S}{{\text{O}}_{4}},\text{PC}{{\text{l}}_{5}}
    D.Molecules with expanded octetIV.CCl4,CO2\text{CC}{{\text{l}}_{4}},\text{C}{{\text{O}}_{2}}

    Choose the correct answer from the options given below :

    1. Option A:

      A-IV, B-II, C-I, D-III

    2. Option B:

      A-III, B-II, C-I, D-IV

    3. Option C:

      A-IV, B-I, C-III, D-II

    4. Option D:

      A-II, B-IV, C-III, D-I

  44. Question 44Chemistry· Nitrogen Containing Organic Compounds

    Which among the following react with Hinsberg's reagent?

    figure

    Choose the correct answer from the options given below :

    1. Option A:

      B and D only

    2. Option B:

      C and D only

    3. Option C:

      A, B and E only

    4. Option D:

      A, C and E only

  45. Question 45Chemistry· Ionic Equilibrium

    If 1 mM solution of ethylamine produces pH=9\mathrm{pH}=9, then the ionization constant (Kb)\left(\mathrm{K}_{\mathrm{b}}\right) of ethylamine is 10−x10^{-x}. The value of x is___ (nearest integer).[0pt] [The degree of ionization of ethylamine can be neglected with respect to unity.]

  46. Question 46Chemistry· Practical Organic Chemistry

    During "S" estimation, 160 mg of an organic compound gives 466 mg of barium sulphate. The percentage of Sulphur in the given compound is___%\%.

    (Given molar mass in gmol−1\mathrm{g} \mathrm{mol}^{-1} of Ba:137, S:32\mathrm{Ba}: 137, \mathrm{~S}: 32, O:16)

  47. Question 47Chemistry· Nitrogen Containing Organic Compounds

    Consider the following sequence of reactions to produce major product (A)

    figure

    Molar mass of product (A) is \qquad gmol−1\mathrm{g} \mathrm{mol}^{-1}.

    (Given molar mass in gmol−1\mathrm{g} \mathrm{mol}^{-1} of C:12,H:1\mathrm{C}: 12, \mathrm{H}: 1, O:16,Br:80, N:14,P:31\mathrm{O}: 16, \mathrm{Br}: 80, \mathrm{~N}: 14, \mathrm{P}: 31 )

  48. Question 48Chemistry· Thermodynamics & Thermochemistry

    The standard enthalpy and standard entropy of decomposition of N2O4\mathrm{N}_{2} \mathrm{O}_{4} to NO2\mathrm{NO}_{2} are 55.0 kJ mol−155.0 \mathrm{~kJ} \mathrm{~mol}^{-1} and 175.0 J/K/mol175.0 \mathrm{~J} / \mathrm{K} / \mathrm{mol} respectively. The standard free energy change for this reaction at 25∘C25^{\circ} \mathrm{C} in Jmol−1\mathrm{J} \mathrm{mol}^{-1} is____ (Nearest integer)

  49. Question 49Physics· Electromagnetic Induction

    Regarding self-inductance : A : The self-inductance of the coil depends on its geometry. B : Self-inductance does not depend on the permeability of the medium. C : Self-induced e.m.f. opposes any change in the current in a circuit. D : Self-inductance is electromagnetic analogue of mass in mechanics. E : Work needs to be done against self-induced e.m.f. in establishing the current. Choose the correct answer from the options given below:

    1. Option A:

      A, B, C, D only

    2. Option B:

      A, C, D, E only

    3. Option C:

      A, B, C, E only

    4. Option D:

      B, C, D, E only

  50. Question 50Physics· Simple Harmonic Motion

    A light hollow cube of side length 10 cm and mass 10 g , is floating in water. It is pushed down and released to execute simple harmonic oscillations. The time period of oscillations is yπ×10−2 s\mathrm{y} \pi \times 10^{-2} \mathrm{~s}, where the value of y is\ (Acceleration due to gravity, g=10 m/s2\mathrm{g}=10 \mathrm{~m} / \mathrm{s}^{2}, density of water =103 kg/m3=10^{3} \mathrm{~kg} / \mathrm{m}^{3} )

    1. Option A:

      2

    2. Option B:

      6

    3. Option C:

      4

    4. Option D:

      1

  51. Question 51Physics· Mechanical Properties of Matter

    Given below are two statements : one is labelled as Statement I and the other is labelled as Statement II :

    Statement-I : The hot water flows faster than cold water.

    Statement-II : Soap water has higher surface tension as compared to fresh water.

    In the light above statements, choose the correct answer from the options given below

    1. Option A:

      Statement-I is false but Statement II is true

    2. Option B:

      Statement-I is true but Statement II is false

    3. Option C:

      Both Statement-I and Statement-II are true

    4. Option D:

      Both Statement-I and Statement-II are false

  52. Question 52Physics· Atomic Physics

    . A sub-atomic particle of mass 10−30 kg10^{-30} \mathrm{~kg} is moving with

    a velocity 2.21×106 m/s2.21 \times 10^{6} \mathrm{~m} / \mathrm{s}. Under the matter

    wave consideration, the particle will behave closely like

    \qquad . (h=6.63×10−34 J.s)\left(\mathrm{h}=6.63 \times 10^{-34} \mathrm{~J} . \mathrm{s}\right)

    1. Option A:

      Infra-red radiation

    2. Option B:

      X-rays

    3. Option C:

      Gamma rays

    4. Option D:

      Visible radiation

  53. Question 53Physics· Geometrical Optics

    A spherical surface of radius of curvature R, separates air from glass (refractive index =1.5 ). The centre of curvature is in the glass medium. A point object ' O ' placed in air on the optic axis of the surface, so that its real image is formed at ' I ' inside glass. The line OI intersects the spherical surface at P and PO=PI. The distance PO equals to-

    1. Option A:

      5R

    2. Option B:

      3R

    3. Option C:

      2R

    4. Option D:

      1.5R

  54. Question 54Physics· Nuclear Physics

    A radioactive nucleus n_2 has 3 times the decay constant as compared

    to the decay constant of another radioactive nucleus n_1. If initial number

    of both nuclei are the same, what is the ratio of number of nuclei .

    of n_2 to the number of nuclei of n_1, after one half-life of n_1 ?

    1. Option A:

      1/4

    2. Option B:

      1/8

    3. Option C:

      4

    4. Option D:

      8

  55. Question 55Physics· Capacitors and R-C Circuits

    Identify the valid statements relevant to the given circuit at the instant when the key is closed. IMAGES A. There will be no current through resistor R . B. There will be maximum current in the connecting wires. C. Potential difference between the capacitor plates A and B is minimum. D. Charge on the capacitor plates is minimum. Choose the correct answer from the options given below :

    Question 55 figure
    1. Option A:

      C, D only

    2. Option B:

      B, C, D only

    3. Option C:

      A, C only

    4. Option D:

      A, B, D only

  56. Question 56Physics· Units, Dimensions & Error Analysis

    . The position of a particle moving on xx-axis is given by

    x(t)=Asin⁡t+Bcos⁡2t+Ct2+Dx(t)=A \sin t+B \cos ^{2} t+\mathrm{Ct}^{2}+D, where tt is time.

    The dimension of ABCD\frac{A B C}{D} is-

    1. Option A:

      L

    2. Option B:

      L3 T−2\mathrm{L}^{3} \mathrm{~T}^{-2}

    3. Option C:

      L2 T−2\mathrm{L}^{2} \mathrm{~T}^{-2}

    4. Option D:

      L2L^{2}

  57. Question 57Physics· Thermodynamics

    Match the List-I with List-II

    List -IList -II
    APressure varies inversely with volume of an ideal gas.IAdiabatic process
    BHeat absorbed goes partly to increase internal energy and partly to do work.IIIsochoric process
    CHeat is neither absorbed nor released by a systemIIIIsothermal process
    DNo work is done on or by a gasIVIsobaric process

    Choose the correct answer from the options given below :

    1. Option A:

      A-I, B-IV, C-II, D-III

    2. Option B:

      A-III, B-I, C-IV, D-II

    3. Option C:

      ) A-I, B-III, C-II, D-IV

    4. Option D:

      A-III, B-IV, C-I, D-II

  58. Question 58Physics· Units, Dimensions & Error Analysis

    Consider a moving coil galvanometer (MCG) :

    A : The torsional constant in moving coil galvanometer has dimensions [ ML2 T−2\mathrm{ML}^{2} \mathrm{~T}^{-2} ]

    B : Increasing the current sensitivity may not necessarily increase the voltage sensitivity.

    C : If we increase number of turns (N)(\mathrm{N}) to its double (2 N)(2 \mathrm{~N}), then the voltage sensitivity doubles.

    D : MCG can be converted into an ammeter by introducing a shunt resistance of large value in parallel with galvanometer.

    E: Current sensitivity of MCG depends inversely on number of turns of coil.

    Choose the correct answer from the options given below :

    1. Option A:

      A, B only

    2. Option B:

      A, D only

    3. Option C:

      B,D,E only

    4. Option D:

      A, B,E only

  59. Question 59Physics· Thermal Properties of Matter

    A gun fires a lead bullet of temperature 300 K into a wooden block. The bullet having melting temperature of 600 K penetrates into the block and melts down. If the total heat required for the process is 625 J , then the mass of the bullet is \qquad grams.

    (Latent heat of fusion of lead =2.5×104JKg−1=2.5 \times 10^{4} \mathrm{JKg}^{-1} and specific heat capacity of lead =125JKg−1 K−1=125 \mathrm{JKg}^{-1} \mathrm{~K}^{-1} )

    1. Option A:

      20

    2. Option B:

      15

    3. Option C:

      10

    4. Option D:

      5

  60. Question 60Physics· Geometrical Optics

    What is the lateral shift of a ray refracted through a parallel-sided glass slab of thickness ' hh ' in terms of the angle of incidence ' ii ' and angle of refraction ' rr ', if the glass slab is placed in air medium ?

    1. Option A:

      (htan⁡(i−r))/(tan⁡r)(h tan⁡(i-r))/(tan⁡r)

    2. Option B:

      htan⁡(i−r)tan⁡r\frac{h \tan (i-r)}{\tan r}

    3. Option C:

      h

    4. Option D:

      hsin⁡(i−r)cos⁡r\frac{h \sin (i-r)}{\cos r}

  61. Question 61Physics· Rotational Dynamics

    A solid sphere of mass ' mm ' and radius ' rr ' is allowed to roll without slipping from the highest point of an inclined plane of length 'L' and makes an angle 30∘30^{\circ} with the horizontal. The speed of the particle at the bottom of the plane is v1\mathrm{v}_{1}. If the angle of inclination is increased to 45∘45^{\circ} while keeping LL constant. Then the new speed of the sphere at the bottom of the plane is v2v_{2}. The ratio of v12:v22v_{1}{ }^{2}: v_{2}{ }^{2} is

    1. Option A:

      1:21: \sqrt{2}

    2. Option B:

      1:31: 3

    3. Option C:

      1:21: 2

    4. Option D:

      1:31: \sqrt{3}

  62. Question 62Physics· Electromagnetic Waves

    The electric field of an electromagnetic wave in free space is E→=57cos[7.5  ⁣ ⁣× ⁣ ⁣ 106t−5  ⁣ ⁣× ⁣ ⁣ 10(−3)(3x+4y)](4i∧−3j∧)N/C.{{E}^{\to }}=57cos[7.5\text{ }\!\!\times\!\!\text{ }{{10}^{6}}t-5\text{ }\!\!\times\!\!\text{ }{{10}^{(-3)}}(3x+4y)](4{{i}^{\wedge }}-3{{j}^{\wedge }})N/C. The associated magnetic field in Tesla is-

    1. Option A:

      B→=573×108cos[7.5×106t−5×10−3(3x+4y)](5k ){{B}^{\to }}=\frac{57}{3\times {{10}^{8}}}\text{cos}\left[ 7.5\times {{10}^{6}}\text{t}-5\times {{10}^{-3}}\left( 3\text{x}+4\text{y} \right) \right]\left( 5\overset{\text{}}{\mathop{\text{k}}}\, \right)

    2. Option B:
      B→=57/(3  ⁣ ⁣× ⁣ ⁣ 108)cos[7.5  ⁣ ⁣× ⁣ ⁣ 106t−5  ⁣ ⁣× ⁣ ⁣ 10(−3)(3x+4y)](k∧ ){{B}^{\to }}=57/(3\text{ }\!\!\times\!\!\text{ }{{10}^{8}})cos[7.5\text{ }\!\!\times\!\!\text{ }{{10}^{6}}t-5\text{ }\!\!\times\!\!\text{ }{{10}^{(-3)}}(3x+4y)]({{k}^{\wedge }}\text{ })
    3. Option C:

      B→=−573×108cos[7.5×106t−5×10−3(3x+4y)](5k ){{B}^{\to }}=-\frac{57}{3\times {{10}^{8}}}\text{cos}\left[ 7.5\times {{10}^{6}}\text{t}-5\times {{10}^{-3}}\left( 3\text{x}+4\text{y} \right) \right]\left( 5\overset{\text{}}{\mathop{\text{k}}}\, \right)

    4. Option D:

      B→=−573×108cos[7.5×106t−5×10−3(3x+4y)]( k ){{B}^{\to }}=-\frac{57}{3\times {{10}^{8}}}\text{cos}\left[ 7.5\times {{10}^{6}}\text{t}-5\times {{10}^{-3}}\left( 3\text{x}+4\text{y} \right) \right]\left( \text{ }k\text{ } \right)

  63. Question 63Physics· System Of Particles

    Consider a circular disc of radius 20 cm with centre located at the origin. A circular hole of a radius 5 cm is cut from this disc in such a way that the edge of the hole touches the edge of the disc. The distance of centre of mass of residual or remaining disc from the origin will be-

    1. Option A:

      2.0cm

    2. Option B:

      0.5cm

    3. Option C:

      1.5cm

    4. Option D:

      1.0cm

  64. Question 64Physics· Vectors and Scalars

    Two particles are located at equal distance from origin. The position vectors of those are represented by A→=2i^+3nj^+2k^\overrightarrow{\mathrm{A}}=2 \hat{\mathrm{i}}+3 \mathrm{n} \hat{\mathrm{j}}+2 \hat{\mathrm{k}} \quad and B⃗=2i^−2j^+4p^\vec{B}=2 \hat{i}-2 \hat{j}+4 \hat{p}, respectively. If both the vectors are at right angle to each other, the value of n−1\mathrm{n}^{-1} is \qquad .

  65. Question 65Physics· Thermodynamics

    item An ideal gas initially at 0∘C0^{\circ} \mathrm{C} temperature, is compressed suddenly to one fourth of its volume. If the ratio of specific heat at constant pressure to that at constant volume is 3/23 / 2, the change in temperature due to the thermodynamics process is \qquad K.

  66. Question 66Physics· Work, Power & Energy

    A force f=x2yi^+y2j^f=x^{2} y \hat{i}+y^{2} \hat{j} acts on a particle in a plane x+y=10x+y=10. The work done by this force during a displacement from (0,0)(0,0) to (4 m,2 m)(4 \mathrm{~m}, 2 \mathrm{~m}) is \qquad Joule (round off to the nearest integer)

  67. Question 67Physics· Electromagnetic Induction

    In the given circuit the sliding contact is pulled outwards such that electric current in the circuit changes at the rate of 8 A/s8 \mathrm{~A} / \mathrm{s}. At an instant when R is 12Ω12 \Omega, the value of the current in the circuit will be \qquad A.

    Question 67 figure

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