JEE Main 2026 · previous year paper

JEE Main 2026 — 5 April, Morning Shift

68 questions with the verified answer key. Open any question for its step-by-step solution.

  1. Question 1Physics· Units, Dimensions & Error Analysis

    In a Vernier calipers, when both jaws touch each other, zero of the Vernier scale is shifted to the right of zero of the main scale and 7th Vernier division coincides with a main scale reading. If the value of 1 main scale division is 1 mm and there are 10 Vernier scale divisions, then the Vernier caliper has

    1. Option A:

      0.07 cm negative zero error

    2. Option B:

      0.7 cm negative zero error

    3. Option C:

      0.07 cm positive zero error

    4. Option D:

      0.7 cm positive zero error

  2. Question 2Physics· Units, Dimensions & Error Analysis

    L, C and R represents physical quantities inductance, capacitance and resistance respectively. The dimensional formula ML2T−4A−2M L^2 T^{-4} A^{-2} corresponds to ________.

    1. Option A:

      RLC\frac{R}{LC}

    2. Option B:

      RLCR LC

    3. Option C:

      CLR\frac{C}{LR}

    4. Option D:

      1LRC\frac{1}{L R C}

  3. Question 3Physics· Gravitation

    When one moves from a point 16 km below the earth's surface to a point 16 km above the earth's surface. The change in g is approximately α\alpha %. The value of α\alpha is _______. (Take radius of the earth = 6400 km.)

    1. Option A:

      0.12

    2. Option B:

      0.25

    3. Option C:

      0.5

    4. Option D:

      0.75

  4. Question 4Physics· Newton's Laws of Motion

    Three masses m1=4kgm_1 = 4\mathrm{kg}, m2=4kgm_2 = 4\mathrm{kg} and m3=6kgm_3 = 6\mathrm{kg} are suspended from a fixed smooth frictionless pulley as shown in the figure below. The value of T1/T2T_1/T_2 is (take g=10m/s2g = 10\mathrm{m/s}^2).

    Question 4 figure
    1. Option A:

      53\frac{5}{3}

    2. Option B:

      23\frac{2}{3}

    3. Option C:

      35\frac{3}{5}

    4. Option D:

      25\frac{2}{5}

  5. Question 5Physics· Newton's Laws of Motion

    A wedge Y with mass of 10kg10\mathrm{kg} and all frictionless surfaces and the inclined surface making 37∘37^{\circ} with horizontal. A block X with mass 2kg2\mathrm{kg} is placed at the highest point of the wedge as shown in figure is at rest. At t=0t = 0 wedge (Y) is pulled toward right with constant force (f)(f) of 24N24\mathrm{N}. Taking the block X at rest at t=0t = 0, the time taken by it to slide down 8.8m8.8\mathrm{m} on the slope, while Y is on the move, is _s. (take tan⁡37∘=3/4\tan 37^{\circ} = 3/4 and g=10m/s2g = 10\mathrm{m/s}^2)

    Question 5 figure
  6. Question 6Physics· Mechanical Properties of Matter

    The Young's modulus of steel wire of radius r and length L is Y. If the radius r and length L of the wire are doubled then the value of Y.

    1. Option A:

      increases by two times

    2. Option B:

      reduces by half

    3. Option C:

      remains unchanged

    4. Option D:

      becomes one fourth

  7. Question 7Physics· Kinetic Theory of Gases

    Statement I : Change in internal energy of a system containing n mole of ideal gas can be written as ΔU=nCv(Tf−Ti)=nRγ−1(Tf−Ti)\Delta U = nC_v(T_f - T_i) = \frac{nR}{\gamma-1}(T_f - T_i), where γ=Cp/Cv\gamma = C_p/C_v. Statement II : Relation between degree of freedom ff and γ\gamma is γ=1+2f\gamma = 1 + \frac{2}{f}.

    1. Option A:

      Both A and R are true and R is the correct explanation of A

    2. Option B:

      Both A and R are true but R is NOT the correct explanation of A

    3. Option C:

      A is true but R is false

    4. Option D:

      A is false but R is true

  8. Question 8Physics· Thermodynamics

    Consider the following statements: A. Zeroth law of thermodynamics gives concept of temperature. B. First law of thermodynamics gives concept of internal energy. C. In isothermal expansion of ideal gas, ΔQ≠ΔW\Delta Q \neq \Delta W. D. Product of intensive and extensive variables is extensive. E. The ratio of any extensive variable to mass will be an extensive variable.

    1. Option A:

      C, D and E Only

    2. Option B:

      A, B and C Only

    3. Option C:

      A, B and D Only

    4. Option D:

      B, C and D Only

  9. Question 9Physics· Atomic Physics

    An electron of mass mm is moving in an electric field E⃗=−2E0i^\vec{E} = -2E_0\hat{i} (E0=constant>0E_0 = \text{constant} > 0), with an initial velocity V⃗=voi^\vec{V} = v_o\hat{i} (v0=constant>0v_0 = \text{constant} > 0). If λ0=h4mv0\lambda_0 = \frac{h}{4mv_0}, its de Broglie wavelength at time tt is __________. (e=charge   of   electrone = \text{charge\; of\; electron})

    1. Option A:

      4λ0[1−E0e2mtv0]\frac{4\lambda_0}{\left[1 - \frac{E_0e}{2m}\frac{t}{v_0}\right]}

    2. Option B:

      4λ0[1+E0e2mtv0]\frac{4\lambda_0}{\left[1 + \frac{E_0e}{2m}\frac{t}{v_0}\right]}

    3. Option C:

      4λ0[1+2E0emtv0]\frac{4\lambda_0}{\left[1 + \frac{2E_0e}{m}\frac{t}{v_0}\right]}

    4. Option D:

      4λ0[1−2E0emtv0]\frac{4\lambda_0}{\left[1 - \frac{2E_0e}{m}\frac{t}{v_0}\right]}

  10. Question 10Physics· Atomic Physics

    In the hydrogen atom, the electron makes a transition from the higher orbit (i) to a lower orbit (f) such that the ratio of radii ri:rf=16:4r_i : r_f = 16:4. The wavelength of photon emitted due to this transition is ___ nm. (Given Rydberg constant = 1.0973 × 10^7 /m)

    1. Option A:

      121

    2. Option B:

      242

    3. Option C:

      486

    4. Option D:

      974

  11. Question 11Physics· Electromagnetic Waves

    A displacement current of 4.0 A can be set up in the space between two parallel plates of 6 μF capacitor. The rate of change of potential difference across the plates of the capacitor is nearly α×106\alpha \times 10^6 V/s. The value of α\alpha is ______.

    1. Option A:

      0.58

    2. Option B:

      0.67

    3. Option C:

      0.82

    4. Option D:

      0.75

  12. Question 12Physics· Wave Optics

    In Young's double slit experiment using monochromatic light, the fringe width of the interference pattern produced on the screen is 2.4 μm. If the experiment is carried out in another medium having refractive index 1.2, the fringe width will be ______ μm.

    1. Option A:

      1.2

    2. Option B:

      2

    3. Option C:

      2.4

    4. Option D:

      2.88

  13. Question 13Physics· Geometrical Optics

    A ray of light passing through an equilateral prism is having velocity 2.12×1082.12 \times 10^8 m/s in the prism material, then the minimum angle of deviation is ______ degrees.

    1. Option A:

      45

    2. Option B:

      30

    3. Option C:

      28

    4. Option D:

      58

  14. Question 14Physics· Atomic Physics

    Light source having wavelength 331331 nm is used to generate photo-electrons whose stopping potential is 0.20.2 V. The work function of the used metal in the experiment is α×10−19\alpha \times 10^{-19} J. The value of α\alpha is (h = 6.62×10^{-34} J s, e = 1.6×10^{-19} C, c = 3×10^8 m/s)

    1. Option A:

      3.68

    2. Option B:

      4.68

    3. Option C:

      5.68

    4. Option D:

      2.68

  15. Question 15Physics· Geometrical Optics

    A compound microscope is designed with two symmetric biconvex lenses. The objective lens is cut vertically, creating two identical plano-convex lenses. One of them is used in place of original objective lens. To retain same magnification keeping the object distance unchanged, the tube length has to be :

    1. Option A:

      increased two times

    2. Option B:

      increased 32\frac{3}{2} times

    3. Option C:

      decreased two times

    4. Option D:

      decreased 32\frac{3}{2} times

  16. Question 16Physics· Mechanical Properties of Matter

    Two wires as shown in the figure below, made of steel and have breaking stress of 12×10512 \times 10^5 N/m². Area of cross-section of upper wire is 0.0080.008 cm² and of lower wire is 0.0040.004 cm². The maximum mass that can be added to pan without breaking any wire is ______ kg (take g = 10 m/s²).

    Question 16 figure
    1. Option A:

      56

    2. Option B:

      38

    3. Option C:

      96

    4. Option D:

      5.6

  17. Question 17Physics· Alternating Current

    An a.c. source of angular frequency ω is connected across a resistor R and a capacitor C in series. The current is observed as I. Now the frequency of the source is changed to ω/4, (keeping the voltage unchanged) the current is found to be I/3. The ratio of resistance to reactance at frequency ω is

    1. Option A:

      67\frac{6}{7}

    2. Option B:

      35\frac{3}{5}

    3. Option C:

      78\frac{7}{8}

    4. Option D:

      34\frac{3}{4}

  18. Question 18Physics· Semiconductor and Electronic Devices

    For the given logic circuit, which of the following inputs combination will make both LED-1 and LED-2 to glow?

    Question 18 figure
    1. Option A:

      A = 0, B = 1, C = 1

    2. Option B:

      A = 1, B = 0, C = 0

    3. Option C:

      A = 1, B = 0, C = 1

    4. Option D:

      A = 1, B = 1, C = 0

  19. Question 19Physics· Mechanical Properties of Matter

    A cube has side length 55 cm and modulus of rigidity 10510^5 N/m². The displacement produced by a force of 1010 N in the upper face of cube is ______ mm.

    Question 19 figure
  20. Question 20Physics· Motion in one Dimension

    From 1818 m height above the ground a ball is dropped from rest. The height above the ground at which the magnitude of velocity equals the magnitude of acceleration (in the same set of units) due to gravity is ______ m. (Take g=10g = 10 m/s² and neglect air resistance)

    Question 20 figure
  21. Question 21Physics· Transverse waves

    A transverse wave on a string is described by y=3sin⁡(36t+0.018x+π/4)y = 3\sin(36t + 0.018x + \pi/4), where x, y are in cm and t in seconds. The least distance between the two successive crests in the wave is ______ cm. (Nearest integer) (π=3.14\pi = 3.14)

    Question 21 figure
  22. Question 22Physics· Moving Charges and Magnetic Field

    The charged particle moving in a uniform magnetic field of (3i^+2j^)(3\hat{i} + 2\hat{j}) T has an acceleration (4i^−x2j^)(4\hat{i} - \frac{x}{2}\hat{j}) m/s². The value of xx is ______.

  23. Question 23Physics· Electromagnetic Induction

    In the given circuit below inductance values of L1,L2L_1, L_2 and L3L_3 are same. The magnetic energy stored in the entire circuit is U1U_1 and that stored in the L2L_2 inductor is U2U_2. The ratio U1/U2U_1/U_2 is (Ignore the mutual inductance if any)

    Question 23 figure
  24. Question 24Mathematics· Quadratic Equations

    Let a,b∈C.a, b ∈ C. Let α,βα, β be the roots of the equation x2+ax+b=0x² + ax + b = 0. If β−α=11β - α = \sqrt11 and β2−α2=3i11β² - α² = 3i\sqrt{11}, then (β3−α3)2(β³ - α³)² is equal to :

    1. Option A:

      160

    2. Option B:

      176

    3. Option C:

      194

    4. Option D:

      187

  25. Question 25Mathematics· Sequence and Series

    Let the sum of the first n terms of an A.P. be 3n2+5n.3n² + 5n. Then the sum of squares of the first 1010 terms of the A.P. is:

    1. Option A:

      1022010220

    2. Option B:

      1286012860

    3. Option C:

      1522015220

    4. Option D:

      1978019780

  26. Question 26Mathematics· Matrices

    Let AA be a 3×33×3 matrix such that A[[1],[0],[−1]]=[[2],[1],[1]],A[[0],[1],[1]]=[[1],[2],[3]],A[[1],[1],[0]]=[[1],[3],[1]].A[[1],[0],[-1]] = [[2],[1],[1]], A[[0],[1],[1]] = [[1],[2],[3]], A[[1],[1],[0]] = [[1],[3],[1]]. If det(A)=1,det(A)=1, then det(adj(A2+A))det(adj(A²+A)) is equal to:

    1. Option A:

      1616

    2. Option B:

      2525

    3. Option C:

      4949

    4. Option D:

      6464

  27. Question 27Mathematics· Determinants

    Consider the system of linear equations in x,y,z:x+2y+tz=0,6x+y+5tz=0,3x+t2y+f(t)z=0,x, y, z: x+2y+tz=0, 6x+y+5tz=0, 3x+t²y+f(t)z=0, where f:R→Rf: R→R is differentiable. If this system has infinitely many solutions for all t∈R,t∈R, then f:f:

    1. Option A:

      is a constant function

    2. Option B:

      is strictly increasing on R

    3. Option C:

      is strictly decreasing on R

    4. Option D:

      has two critical points

  28. Question 28Mathematics· Sequence and Series

    ∑n=110528n(n+1)(n+2)∑_{n=1}^{10} \frac{528}{n(n+1)(n+2)} is equal to:

    1. Option A:

      65

    2. Option B:

      130

    3. Option C:

      220

    4. Option D:

      440

  29. Question 29Mathematics· Quadratic Equations

    Let tan A, tan B, where A,B∈(-π/2,π/2) be the roots of the quadratic equation x² - 2x - 5 = 0. Then 20 sin²((A+B)/2) is equal to:

    1. Option A:

      10+1010+\sqrt{10}

    2. Option B:

      10−21010-2\sqrt{10}

    3. Option C:

      10−31010-3\sqrt{10}

    4. Option D:

      10−1010-\sqrt{10}

  30. Question 30Mathematics· Probability

    A letter is known to have arrived by post either from KANPUR or from ANANTPUR. On the envelope just two consecutive letters AN are visible. The probability that the letter came from ANANTPUR is:

    1. Option A:

      46302

    2. Option B:

      10/17

    3. Option C:

      12/19

    4. Option D:

      7/19

  31. Question 31Mathematics· Statistics

    The mean deviation about the mean for the data

    xix_i579101215
    fif_i862226

    is equal to:

    1. Option A:

      40/13

    2. Option B:

      42/13

    3. Option C:

      44/13

    4. Option D:

      46/13

  32. Question 32Mathematics· Ellipse

    Let a focus of the ellipse E: x2/a2+y2/b2=1x²/a² + y²/b² = 1 be S(4,0)S(4,0) and its eccentricity be 45\frac{4}{5}. If the point P(3,α)P(3,α) lies on E and O is the origin, then the area of ΔPOSΔPOS is equal to:

    1. Option A:

      12/5

    2. Option B:

      14/5

    3. Option C:

      24/5

    4. Option D:

      48/5

  33. Question 33Mathematics· Circles

    Let P be a moving point on the circle x2+y2−6x−8y+21=0.x²+y²-6x-8y+21=0. Then the maximum distance of P from the vertex of the parabola x2+6x+y+13=0x²+6x+y+13=0 is equal to:

    1. Option A:

      88

    2. Option B:

      1010

    3. Option C:

      1212

    4. Option D:

      99

  34. Question 34Mathematics· Straight lines

    In an equilateral triangle PQR, let the vertex P be at (3,5)(3,5) and the side QR be along the line x+y=4.x+y=4. If the orthocentre of triangle PQRPQR is (α,β),(α,β), then 9(α+β)9(α+β) is equal to :

    1. Option A:

      1616

    2. Option B:

      2727

    3. Option C:

      3636

    4. Option D:

      4848

  35. Question 35Mathematics· Trigonometry Ratios and Identities

    The sum of all the integral values of pp such that the equation 3sin2x+12cosx−3=p,x∈R,3 sin² x + 12 cos x - 3 = p, x∈R, has at least one solution, is :

    1. Option A:

      −54-54

    2. Option B:

      −60-60

    3. Option C:

      −75-75

    4. Option D:

      −84-84

  36. Question 36Mathematics· 3D Geometry

    The square of the distance of the point P(5,6,7) from the line (x-2)/2 = (y-5)/3 = (z-2)/4 is equal to:

    1. Option A:

      3

    2. Option B:

      5

    3. Option C:

      6

    4. Option D:

      8

  37. Question 37Mathematics· Vector Algebra

    Let a=7i+j−kandb=j+2ka = \sqrt7 i + j - k and b = j + 2k. If rr is a vector such that r×a+a×b=0r×a + a×b = 0 and r⋅a=0r·a = 0, then ∣3r∣2|3r|² is equal to :

    1. Option A:

      4444

    2. Option B:

      5454

    3. Option C:

      8686

    4. Option D:

      132132

  38. Question 38Mathematics· 3D Geometry

    The square of the distance of the point of intersection of the lines r = (i+j-k) + λ(ai - j), a≠0 and r = (4i - k) + μ(2i + ak) from the origin is:

    1. Option A:

      5

    2. Option B:

      10

    3. Option C:

      17

    4. Option D:

      26

  39. Question 39Mathematics· Area under the Curves

    The area of the region R = {(x,y): xy ≤ 27, 1 ≤ y ≤ x²} is equal to:

    1. Option A:

      78log⁡e3−52378 \log _{e} 3-\frac{52}{3}

    2. Option B:

      54log⁡e3−52354 \log _{\mathrm{e}} 3-\frac{52}{3}

    3. Option C:

      54log⁡e3−26354 \log _{e} 3-\frac{26}{3}

    4. Option D:

      54log⁡e3+26354 \log _{e} 3+\frac{26}{3}

  40. Question 40Mathematics· Limits, Continuity and Differentiability

    The product of all possible values of α, for which limx→01−cos(αx)cos((α+1)x)cos((α+2)x)sin2((α+1)x)=2,lim_{x→0} \frac{1 - cos(αx) cos((α+1)x) cos((α+2)x)} { sin²((α+1)x)} = 2, is :

    1. Option A:

      −2-2

    2. Option B:

      11

    3. Option C:

      −1-1

    4. Option D:

      54\frac{5}{4}

  41. Question 41Mathematics· Definite Integration

    The value of the integral ∫0∞log⁡e(x)x2+4dx\int_{0}^{\infty} \frac{\log _{e}(x)}{x^{2}+4} d x is:

    1. Option A:

      πlog⁡e(2)2\frac{\pi \log _{\mathrm{e}}(2)}{2}

    2. Option B:

      πlog⁡e(2)4\frac{\pi \log _{e}(2)}{4}

    3. Option C:

      1+πlog⁡e(2)1+\pi \log _{\mathrm{e}}(2)

    4. Option D:

      2+πlog⁡e(2)2+\pi \log _{\mathrm{e}}(2)

  42. Question 42Mathematics· Functions

    Let f:R→R\mathrm{f}: \mathrm{R} \rightarrow \mathrm{R} be a differentiable function such that f(x+y3)=f(x)+f(y)3f\left(\frac{x+y}{3}\right)=\frac{f(x)+f(y)}{3} for all x,y∈Rx, y \in R and f′(0)=3f^{\prime}(0)=3. Then the minimum value of the function g(x)=3+exf(x)g(x)=3+e^{x} f(x), is

    1. Option A:

      3(e+1e)3\left(\frac{\mathrm{e}+1}{\mathrm{e}}\right)

    2. Option B:

      3(e−1e)3\left(\frac{\mathrm{e}-1}{\mathrm{e}}\right)

    3. Option C:

      3−ee\frac{3-e}{e}

    4. Option D:

      3 e

  43. Question 43Mathematics· Definite Integration

    The value of the integral ∫π6π3(4−cosec⁡2xcos⁡4x)dx\int_{\frac{\pi}{6}}^{\frac{\pi}{3}}\left(\frac{4-\operatorname{cosec}^{2} x}{\cos ^{4} x}\right) d x is:

    1. Option A:

      113\frac{11}{\sqrt{3}}

    2. Option B:

      163\frac{16}{\sqrt{3}}

    3. Option C:

      3233\frac{32}{3 \sqrt{3}}

    4. Option D:

      6433\frac{64}{3 \sqrt{3}}

  44. Question 44Mathematics· Permutations and Combinations

    Let A={1,2,3,4,5,6}\mathrm{A}=\{1,2,3,4,5,6\}. The number of one-one functions f:A→A\mathrm{f}: \mathrm{A} \rightarrow \mathrm{A} such that f(1)≥3,f(3)≤4\mathrm{f}(1) \geq 3, \mathrm{f}(3) \leq 4 and f(2)+f(3)=5f(2)+f(3)=5, is ____\_\_\_\_

  45. Question 45Mathematics· Probability

    Two players A and B play a series of games of badminton. The player who wins 5 games first wins the series. Assuming that no game ends in a draw, the number of ways in which player A wins the series is

  46. Question 46Mathematics· Binomial Theorem

    If the sum of the coefficients of x7x^{7} and x14x^{14} in the expansion of (1x3−x4)n,x≠0\left(\frac{1}{x^{3}}-x^{4}\right)^{n}, x \neq 0, is zero, then the value of nn is ____\_\_\_\_。

  47. Question 47Mathematics· Trigonometry Ratios and Identities

    If π4+∑p=111tan⁡−1(2p−11+22p−1)=α\frac{\pi}{4}+\sum_{p=1}^{11} \tan ^{-1}\left(\frac{2^{p-1}}{1+2^{2 p-1}}\right)=\alpha, then tan⁡α\tan \alpha is equal to ____\_\_\_\_ .

  48. Question 48Mathematics· Differential Equations

    Let y=y(x)\mathrm{y}=\mathrm{y}(\mathrm{x}) be the solution of the differential equation xsin⁡(yx)dy=(ysin⁡(yx)−x)dx,y(1)=π2x \sin \left(\frac{y}{x}\right) d y=\left(y \sin \left(\frac{y}{x}\right)-x\right) d x, y(1)=\frac{\pi}{2} and let α=cos⁡(y(e12)e12)\alpha=\cos \left(\frac{\mathrm{y}\left(\mathrm{e}^{12}\right)}{\mathrm{e}^{12}}\right). Then the number of integral value of pp, for which the equation x2+y2−2px+2py+α+2=0x^{2}+y^{2}-2 p x+2 p y+\alpha+2=0 represents a circle of radius r≤6r \leq 6, is ____\_\_\_\_

  49. Question 49Chemistry· Some Basic Concepts of Chemistry (Mole Concept) + Stoichiometry

    How many grams of residue is obtained by heating 2.76 g of silver carbonate? (Given : Molar mass of C,O\mathrm{C}, \mathrm{O} and Ag are 12, 16 and 108 g mol−1108 \mathrm{~g} \mathrm{~mol}^{-1} respectively)

    1. Option A:

      1.08 g

    2. Option B:

      2.16 g

    3. Option C:

      3.24 g

    4. Option D:

      4.32 g

  50. Question 50Chemistry· Structure of Atom

    Arrange the following atomic orbitals of multi electron atoms in order of increasing energy. (A) n=3,ℓ=2, m=+1\mathrm{n}=3, \ell=2, \mathrm{~m}=+1 (B) n=4,ℓ=0,m=0n=4, \ell=0, m=0 (C) n=6,ℓ=1, m=0\mathrm{n}=6, \ell=1, \mathrm{~m}=0 (D) n=5,ℓ=1, m=+1\mathrm{n}=5, \ell=1, \mathrm{~m}=+1 (E) n=2,ℓ=1, m=+1\mathrm{n}=2, \ell=1, \mathrm{~m}=+1

    Choose the correct answer from the options given below :

    1. Option A:

      C << D << B << A << E

    2. Option B:

      B << A << E << C << D

    3. Option C:

      E << C << D << B << A

    4. Option D:

      E << B << A << D << C

  51. Question 51Chemistry· Structure of Atom

    Identify the correct statements from the following : A. Heisenberg uncertainty principle is applicable to electron. B. The size of 2px2 p_{x} orbital is less than the size of 3px3 p_{x} orbital. C. The energy of 2s orbital of H atom is equal to the energy of 2s orbital of Li. D. The electronic configuration of Cr is [Ar]3 d54 s1[\mathrm{Ar}] 3 \mathrm{~d}^{5} 4 \mathrm{~s}^{1}

    Choose the correct answer from the options given below:

    1. Option A:

      A, B and C only

    2. Option B:

      A, B and D only

    3. Option C:

      B, C, and D only

    4. Option D:

      A, C and D only

  52. Question 52Chemistry· Some Basic Concepts of Chemistry (Mole Concept) + Stoichiometry

    What is the mole fraction of water in 10%10 \% by weight (w/w)(\mathrm{w} / \mathrm{w}) of aqueous urea solution ?[0pt][Given : Molar mass of H,O,C\mathrm{H}, \mathrm{O}, \mathrm{C} and N are 1, 16, 12 and 14 g mol−114 \mathrm{~g} \mathrm{~mol}^{-1} respectively]

    1. Option A:

      0.825

    2. Option B:

      0.032

    3. Option C:

      0.867

    4. Option D:

      0.967

  53. Question 53Chemistry· Solutions and Colligative Properties

    M3 A2\mathrm{M}_{3} \mathrm{~A}_{2} is a sparingly soluble salt of molar mass y gmol−1\mathrm{g} \mathrm{mol}^{-1} and solubility ×gL−1\times \mathrm{g} \mathrm{L}^{-1}. The ratio of the molar concentration of the anion ( A3−\mathrm{A}^{3-} ) to the solubility product of the salt is

    1. Option A:

      154⋅y4x4\frac{1}{54} \cdot \frac{y^{4}}{x^{4}}

    2. Option B:

      y5108x4\frac{y^{5}}{108 x^{4}}

    3. Option C:

      108⋅x5y5108 \cdot \frac{x^{5}}{y^{5}}

    4. Option D:

      1108y4x4\frac{1}{108} \frac{y^{4}}{x^{4}}

  54. Question 54Chemistry· Ionic Equilibrium

    Arrange the following resultant mixtures in increasing order of their pH values A. 10 mL0.2MCa(OH)2+25 mL0.1MHCl10 \mathrm{~mL} 0.2 \mathrm{M} \mathrm{Ca}(\mathrm{OH})_{2}+25 \mathrm{~mL} 0.1 \mathrm{M} \mathrm{HCl} B. 10 mL0.01MH2SO4+10 mL0.01MCa(OH)210 \mathrm{~mL} 0.01 \mathrm{M} \mathrm{H}_{2} \mathrm{SO}_{4}+10 \mathrm{~mL} 0.01 \mathrm{M} \mathrm{Ca}(\mathrm{OH})_{2} C. 10 mL0.1MH2SO4+10 mL0.1MKOH10 \mathrm{~mL} 0.1 \mathrm{M} \mathrm{H}_{2} \mathrm{SO}_{4}+10 \mathrm{~mL} 0.1 \mathrm{M} \mathrm{KOH}

    Choose the correct answer from the options given below :

    1. Option A:

      B<C<A\mathrm{B}<\mathrm{C}<\mathrm{A}

    2. Option B:

      C << A << B

    3. Option C:

      C << B << A

    4. Option D:

      A << C << B

  55. Question 55Chemistry· Chemical Kinetics

    First order gas phase reaction A→B+C\mathrm{A} \rightarrow \mathrm{B}+\mathrm{C} pi=p_{i}= initial pressure of gas A, pt=p_{t}= total pressure of the reaction mixture at time t

    Expression of rate constant ( k ) is

    1. Option A:

      1tln⁡pi2pi−pt\frac{1}{t} \ln \frac{p_{i}}{2 p_{i}-p_{t}}

    2. Option B:

      1tln⁡2pipi−pt\frac{1}{t} \ln \frac{2 p_{i}}{p_{i}-p_{t}}

    3. Option C:

      1tln⁡pi3pi−2pt\frac{1}{t} \ln \frac{p_{i}}{3 p_{i}-2 p_{t}}

    4. Option D:

      1tln⁡3pi4pi−pt\frac{1}{t} \ln \frac{3 p_{i}}{4 p_{i}-p_{t}}

  56. Question 56Chemistry· Periodicity of Elements and Periodic Properties

    Statement I : The correct order of electronegativity of fluorine, oxygen nitrogen is F>O>N\mathrm{F}>\mathrm{O}>\mathrm{N}.

    Statement II : The oxidation state of oxygen in OF2\mathrm{OF}_{2} is +2 and in Na2O\mathrm{Na}_{2} \mathrm{O} is -2 .

    In the light of the above statements, choose the correct answer from the options given below

    1. Option A:

      Both Statement I and Statement II are true

    2. Option B:

      Both Statement I and Statement II are false

    3. Option C:

      Statement I is true but Statement II is false

    4. Option D:

      Statement I is false but Statement II is true

  57. Question 57Chemistry· p-Block Elements (Group 15-18)

    Correct statements from the following are : A. Nitrogen in oxidation states from +1 to +4 disproportionates in acid medium. B. Nitrogen has the ability of form dπ−pπ\mathrm{d} \pi-\mathrm{p} \pi multiple bonds with itself and other elements with small size and high electronegativity. C. N-N single bond is stronger than P-P single bond. D. Nitrogen has highest density in its group due to small size. E. The maximum covalency of nitrogen is four since it has only four valence orbitals for bonding. Choose the correct answer from the options given below :

    1. Option A:

      B, C, and D only

    2. Option B:

      C, D, and E only

    3. Option C:

      A, C and E only

    4. Option D:

      A and E only

  58. Question 58Chemistry· d and f Block Elements

    Which of the following is NOT a physical or chemical characteristics of interstitial compounds?

    1. Option A:

      They have high melting points, higher than those of pure metals

    2. Option B:

      They are very soft ionic in nature

    3. Option C:

      They retain metallic conductivity

    4. Option D:

      They are chemically inert and usually nonstoichiometric

  59. Question 59Chemistry· Coordination Compounds

    The correct statements about metal carbonyls are A. The metal-carbon bonds in metals carbonyls possess both σ\sigma and π\pi-character. B. Due to synergic bonding interactions between metals and CO ligand the metal-carbon bond becomes weak. C. The metal-carbon σ\sigma bond is formed by the donation of lone pair of electrons on the carbonyl carbon into a vacant orbital of metal. D. The metal-carbon π\pi bond is formed by the donation of electrons from filled d-orbital of metal into vacant π∗\pi^{*} orbital of CO. Choose the correct answer from the options given below:

    1. Option A:

      A and B only

    2. Option B:

      A, C and D only

    3. Option C:

      B and C only

    4. Option D:

      A and D only

  60. Question 60Chemistry· Coordination Compounds

    Given below are two statements :

    Statement I : Each electron in eg\mathrm{e}_{\mathrm{g}} orbitals destabilizes the orbitals by +0.6Δ0+0.6 \Delta_{0} and each electron in the t2gt_{2 g} orbitals stabilizes the orbitals by −0.4Δ0-0.4 \Delta_{0} in an octahedral field on the basis of crystal field theory.

    Statement II : All the d-orbitals of the transition metals have the same energy in their free atomic state but when a complex is formed the ligands destroy the degeneracy of these orbitals on the basis of crystal field theory.

    In the light of the above statements, choose the correct answer from the options given below.

    1. Option A:

      Both Statement I and Statement II are correct

    2. Option B:

      Both Statement I and Statement II are incorrect

    3. Option C:

      Statement I is correct but Statement II is incorrect

    4. Option D:

      Statement I is incorrect but Statement II is correct

  61. Question 61Chemistry· General Organic Chemistry

    Given below are two statements :

    Statement I: On the basis of inductive effect, the order of stability of alkyl carbanions is CH3−>CH3−CH2−>(CH3)2CH−>(CH3)3C−\mathrm{CH}_{3}^{-}>\mathrm{CH}_{3} -\mathrm{CH}_{2}^{-}>\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CH}^{-}>\left(\mathrm{CH}_{3}\right)_{3} \mathrm{C}^{-}.

    Statement II : Allyl and benzyl carbanions are more stabilised by inductive effect and not by resonance effect.

    In the light of the above statements choose the correct answer from the options given below:

    1. Option A:

      Both Statement I and Statement II are correct

    2. Option B:

      Both Statement I and Statement II are incorrect

    3. Option C:

      Statement I is correct and Statement II is incorrect

    4. Option D:

      Statement I is incorrect and Statement II is correct

  62. Question 62Chemistry· Alcohols, Ethers and Phenols

    Consider compounds A,B\mathrm{A}, \mathrm{B} and C with following structural formulae A=CH3−CH2−CH2−CH2−CH2−OH\mathrm{A}=\mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{CH}_{2}-\mathrm{CH}_{2}-\mathrm{CH}_{2}-\mathrm{OH} B=CH2=CH−CH2−CH2−CH3\mathrm{B}=\mathrm{CH}_{2}=\mathrm{CH}-\mathrm{CH}_{2}-\mathrm{CH}_{2}-\mathrm{CH}_{3} C=HO−CH2−CH2−CH(OH)−CH3\mathrm{C}=\mathrm{HO}-\mathrm{CH}_{2}-\mathrm{CH}_{2}-\mathrm{CH}(\mathrm{OH})-\mathrm{CH}_{3} For the conversion of B from A , reagent (D) required is ____\_\_\_\_ and structural formula of product (E) obtained when C undergoes same reaction using excess reagent (D) is ____\_\_\_\_

    1. Option A:
      Option A figure
    2. Option B:
      Option B figure
    3. Option C:
      Option C figure
    4. Option D:
      Option D figure
  63. Question 63Chemistry· Biomolecules

    Identify the correct statements A. Glucose exist in two anomeric forms. B. Anomers of glucose differ in configuration at C -1 in cyclic hemiacetal structure. C. Melting point of α\alpha-anomer of glucose is greater than β\beta-anomer. D. Specific rotation of α\alpha-anomer is +19∘+19^{\circ} while for β\beta-anomer is +112∘+112^{\circ} E. α\alpha and β\beta-anomers of glucose are prepared by crystallization of saturated glucose solution at 303 K and 371 K respectively. Choose the correct answer from the options given below:

    1. Option A:

      A and B only

    2. Option B:

      B and C only

    3. Option C:

      A, B and D only

    4. Option D:

      A, B and E only

  64. Question 64Chemistry· d and f Block Elements

    Statement I : Sodium dichromate and potassium dichromate are classified as primary standard in titrimetric analysis .

    Statement II : Phenolphthalein is a weak base, therefore it dissociates in acidic medium.

    In the light of the above statements, choose the correct answer from the options given below

    1. Option A:

      Both Statement I and Statement II are true

    2. Option B:

      Both Statement I and Statement II are false

    3. Option C:

      Statement I is true but Statement II is false

    4. Option D:

      Statement I is false but Statement II is true

  65. Question 65Chemistry· p-Block Elements (Group 15-18)

    Consider the following species BrF5,XeF5−,BF4−,ICl4−,XeF4,SF4,NH4+,ClF3,XeF2,ICl2−\mathrm{BrF}_{5}, \mathrm{XeF}_{5}^{-}, \mathrm{BF}_{4}^{-}, \mathrm{ICl}_{4}^{-}, \mathrm{XeF}_{4}, \mathrm{SF}_{4}, \mathrm{NH}_{4}^{+}, \mathrm{ClF}_{3}, \mathrm{XeF}_{2}, \mathrm{ICl}_{2}^{-} Number of species having sp 3 d{ }^{3} \mathrm{~d} hybridized central atom is ____\_\_\_\_.

  66. Question 66Chemistry· Alcohols, Ethers and Phenols

    One mole of phenol is treated with dilute HNO3\mathrm{HNO}_{3} at 298 K to give a mixture of products. The mixture is separated by steam distillation. The seam volatile compound ( X ) is separated. The increase in percentage of oxygen in (X) with respect to phenol is ____\_\_\_\_ 10−1%10^{-1} \% (Given molar mass in gmol−1H:1,C:12, N:14\mathrm{g} \mathrm{mol}^{-1} \mathrm{H}: 1, \mathrm{C}: 12, \mathrm{~N}: 14, O:16).

  67. Question 67Chemistry· Thermodynamics & Thermochemistry

    The values of pressure equilibrium constant recorded at different temperatures for the following equilibrium reaction have been given below: A(g)⇌B(g)+C(g)\mathrm{A}(\mathrm{g}) \rightleftharpoons \mathrm{B}(\mathrm{g})+\mathrm{C}(\mathrm{g})

    1T (K−1)log⁡10Kp0.053.50.062.50.071.5\begin{array}{c c} \frac{1}{T}\,(\mathrm{K}^{-1}) & \log_{10} K_p \\ 0.05 & 3.5 \\ 0.06 & 2.5 \\ 0.07 & 1.5 \end{array}

    The magnitude of ΔH∘R\frac{\Delta \mathrm{H}^{\circ}}{\mathrm{R}} calculated from the above data is ____\_\_\_\_ .(Nearest integer).

  68. Question 68Chemistry· Chemical Kinetics

    If the half life of a first order reaction is 6.93 minutes then the time required for completion of 99%99 \% of the reaction will be ____\_\_\_\_ minutes. (Given : log⁡2=0.3010\log 2=0.3010 ).

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