JEE Main 2026 — 24 January, Morning Shift

If the function $\mathrm{f}(\mathrm{x}) =\frac{\mathrm{e}^{\mathrm{x}}\left(\mathrm{e}^{\tan \mathrm{x}-\mathrm{x}}-1\right)+\log _{\mathrm{e}}(\sec \mathrm{x}+\tan \mathrm{x})-\mathrm{x}}{\tan \mathrm{x}-\mathrm{x}}$ is Continuous at $\mathrm{x}=0$, then the value of $\mathrm{f}(0)$ is equal to

Let a circle of radius 4 pass through the origin O , the points $\mathrm{A}(-\sqrt{3} \mathrm{a}, 0)$ and $\mathrm{B}(0,-\sqrt{2} \mathrm{~b})$, where a and b are real parameters and $\mathrm{ab} \neq 0$. Then the locus of the centroid of $\triangle \mathrm{OAB}$ is a circle of radius :

Let the lines $L_{1}: \vec{r}=\hat{i}+2 \hat{j}+3 \hat{k}+\lambda(2 \hat{i}+3 \hat{j}+4 \hat{k})$, $\lambda \in \mathbb{R}$ and $L_{2}: \vec{r}=(4 \hat{i}+\hat{j})+\mu(5 \hat{i}+2 \hat{j}+\hat{k}), \mu \in \mathbb{R}$, intersect at the point R . Let P and Q be the points lying on lines $\mathrm{L}_{1}$ and $\mathrm{L}_{2}$, respectively, such that $|\overrightarrow{\mathrm{PR}}|=\sqrt{29}$ and $|\overrightarrow{\mathrm{PQ}}|=\sqrt{\frac{47}{3}}$. If the point P lies in the first octant, then $27(\mathrm{QR})^{2}$ is equal to

Let $729,81,9,1, \ldots$ be a sequence and $\mathrm{P}_{\mathrm{n}}$ denote the product of the first $n$ terms of this sequence If $2 \sum_{n=1}^{40}\left(P_{n}\right)^{\frac{1}{n}}=\frac{3^{\alpha}-1}{3^{\beta}}$ and $\operatorname{gcd}(\alpha, \beta)=1$, then $\alpha+\beta$ is equal to

Let $\vec{a}=2 \hat{i}+\hat{j}-2 \hat{k}, \vec{b}=\hat{i}+\hat{j}$ and $\vec{c}=\vec{a} \times \vec{b}$. Let $\overrightarrow{\mathrm{d}}$ be a vector such that $|\overrightarrow{\mathrm{d}}-\overrightarrow{\mathrm{a}}|=\sqrt{11},|\overrightarrow{\mathrm{c}} \times \overrightarrow{\mathrm{d}}|=3$ and the angle between $\vec{c}$ and $\vec{d}$ is $\frac{\pi}{4}$. Then $\vec{a} \cdot \vec{d}$ is equal to

If the domain of the function $f(x)=\log _{\left(10 x^{2}-17 x+7\right)}\left(18 x^{2}-11 x+1\right)$ is $(-\infty, a) \cup(b, c) \cup(d, \infty)-\{e\}$, then $90(\mathrm{a}+\mathrm{b}+\mathrm{c}+\mathrm{d}+\mathrm{e})$ equals:

7. Let each of the two ellipses $\mathrm{E}_{1}: \frac{\mathrm{x}^{2}}{\mathrm{a}^{2}}+\frac{\mathrm{y}^{2}}{\mathrm{~b}^{2}}=1,(\mathrm{a}>\mathrm{b})$ and $\mathrm{E}_{2}: \frac{\mathrm{x}^{2}}{\mathrm{~A}^{2}}+\frac{\mathrm{y}^{2}}{\mathrm{~B}^{2}}=1,(\mathrm{~A}<\mathrm{B})$ have eccentricity $\frac{4}{5}$. Let the lengths of the latus recta of $\mathrm{E}_{1}$ and $\mathrm{E}_{2}$ be $\ell_{1}$ and $\ell_{2}$, respectively, such that $2 \ell_{1}^{2}=9 \ell_{2}$. If the distance between the foci of $\mathrm{E}_{1}$ is 8 , then the distance between the foci of $\mathrm{E}_{2}$ is

The value of $\frac{\sqrt{3} \operatorname{cosec} 20^{\circ}-\sec 20^{\circ}}{\cos 20^{\circ} \cos 40^{\circ} \cos 60^{\circ} \cos 80^{\circ}}$ is equal to

Let $\mathrm{S}=\left\{\mathrm{z} \in \mathbb{C}:\left|\frac{\mathrm{z}-6 \mathrm{i}}{\mathrm{z}-2 \mathrm{i}}\right|=1\right.$ and $\left.\left|\frac{\mathrm{z}-8+2 \mathrm{i}}{\mathrm{z}+2 \mathrm{i}}\right|=\frac{3}{5}\right\}$. Then $\sum_{\mathrm{z} \in \mathrm{s}}|\mathrm{z}|^{2}$ is equal to

If $\cot x=\frac{5}{12}$ for some $x \in\left(\pi, \frac{3 \pi}{2}\right)$, then $\sin 7 x\left(\cos \frac{13 x}{2}+\sin \frac{13 x}{2}\right)+ \cos 7 x\left(\cos \frac{13 x}{2}-\sin \frac{13 x}{2}\right)$ is equal to

Let $\mathrm{f}(\mathrm{t})=\int\left(\frac{1-\sin \left(\log _{\mathrm{e}} \mathrm{t}\right)}{1-\cos \left(\log _{\mathrm{e}} \mathrm{t}\right)}\right) \mathrm{dt}, \mathrm{t}>1$.

If $\mathrm{f}\left(\mathrm{e}^{\pi / 2}\right)=-\mathrm{e}^{\pi / 2}$ and $\mathrm{f}\left(\mathrm{e}^{\pi / 4}\right)=\alpha \mathrm{e}^{\pi / 4}$, then $\alpha$ equals

Let R be a relation defined on the set $\{1,2,3,4\} \times\{1,2,3,4\}$ by $R=\{((a, b),(c, d)): 2 a+3 b=3 c+4 d\}$. Then the number of elements in R is

Let $\mathrm{A}(1,0), \mathrm{B}(2,-1)$ and $\mathrm{C}\left(\frac{7}{3}, \frac{4}{3}\right)$ be three points. If the equation of the bisector of the angle ABC is $\alpha x+\beta y=5$, then the value of $\alpha^{2}+\beta^{2}$ is

Let $\mathrm{S}=\frac{1}{25!}+\frac{1}{3!23!}+\frac{1}{5!21!}+\ldots$ up to 13 terms. If $13 \mathrm{~S}=\frac{2^{\mathrm{k}}}{\mathrm{n}!}, \mathrm{k} \in \mathrm{N}$, then $\mathrm{n}+\mathrm{k}$ is equal to

Consider an A.P.: $\mathrm{a}_{1}, \mathrm{a}_{2}, \ldots, \mathrm{a}_{\mathrm{n}} ; \mathrm{a}_{1}>0$. If $\mathrm{a}_{2}-\mathrm{a}_{1}$ $=\frac{-3}{4}, \mathrm{a}_{\mathrm{n}}=\frac{1}{4} \mathrm{a}_{1}$, and $\sum_{\mathrm{i}=1}^{\mathrm{n}} \mathrm{a}_{\mathrm{i}}=\frac{525}{2}$, then $\sum_{\mathrm{i}=1}^{17} \mathrm{a}_{\mathrm{i}}$ is equal to :

Let $\alpha, \beta \in \mathbb{R}$ be such that the function $f(\mathrm{x})= \begin{cases}2 \alpha\left(\mathrm{x}^{2}-2\right)+2 \beta \mathrm{x} & , \mathrm{x}<1 \\(\alpha+3) \mathrm{x}+(\alpha-\beta) & , \mathrm{x} \geq 1\end{cases}$ be differentiable at all $\mathrm{x} \in \mathbb{R}$. Then $34(\alpha+\beta)$ is equal to :

From a lot containing 10 defective and 90 nondefective bulbs, 8 bulbs are selected one by one with replacement. Then the probability of getting at least 7 defective bulbs is :-

The mean and variance of a data of 10 observations are 10 and 2 , respectively. If an observations $\alpha$ in this data is replaced by $\beta$, then the mean and variance become 10.1 and 1.99, respectively. Then $\alpha+\beta$ equals.

Let $\mathrm{A}_{1}$ be the bounded area enclosed by the curves $y=x^{2}+2, x+y=8$ and $y$-axis that lies in the first quadrant. Let $\mathrm{A}_{2}$ be the bounded area enclosed by the curves $\mathrm{y}=\mathrm{x}^{2}+2, \mathrm{y}^{2}=\mathrm{x}, \mathrm{x}=2$, and y -axis that lies in the first quadrant. Then $\mathrm{A}_{1}-\mathrm{A}_{2}$ is equal to

Let a differentiable function $f$ satisfy the equation $\int_{0}^{36} f\left(\frac{\mathrm{tx}}{36}\right) \mathrm{dt}=4 \alpha f(\mathrm{x}) .$ If $\mathrm{y}=f(\mathrm{x})$ is a standard parabola passing through the points $(2,1)$ and $(-4, \beta)$, Then $\beta^{\alpha}$ is equal to $\_\_\_\_$ .

Let a line L passing through the point $\mathrm{P}(1,1,1)$ be perpendicular to the lines $\frac{x-4}{4}=\frac{y-1}{1}=\frac{z-1}{1}$ and $\frac{\mathrm{x}-17}{1}=\frac{\mathrm{y}-71}{1}=\frac{\mathrm{z}}{0}$. Let the line L intersect the yz-plane at the point Q . Another line parallel to L and passing through the point $\mathrm{S}(1,0,-1)$ intersects the yz -plane at the point R . Then the square of the area of the parallelogram PQRS is equal to $\_\_\_\_$ .

The number of numbers greater than 5000 , less than 9000 and divisible by 3 , that can be formed using the digits $0,1,2,5,9$, if the repetition of the digits is allowed, is $\_\_\_\_$

The number of $3 \times 2$ matrices $A$, which can be formed using the elements of the set $\{-2,-1,0,1,2\}$ such that the sum of all the diagonal elements of $\mathrm{A}^{\mathrm{T}} \mathrm{A}$ is 5 , is $\_\_\_\_$

Match the List-I with List-II

Choose the correct answer from the options given below:

Three charges $+2 \mathrm{q} .+3 \mathrm{q}$ and -4 q are situated at $(0,-3 \mathrm{a}),(2 \mathrm{a}, 0)$ and $(-2 \mathrm{a}, 0)$ respectively in the xy plane. The resultant dipole moment about origin is $\_\_\_\_$

A cylindrical block of mass M and area of cross section A is floating in a liquid of density $\rho$ and with its axis vertical. When depressed a little and released the block starts oscillating. The period of oscillation is $\_\_\_\_$ .

Density of water at $4^{\circ} \mathrm{C}$ and $20^{\circ} \mathrm{C}$ are $1000 \mathrm{~kg} / \mathrm{m}^{3}$ and respectively. The increase in internal energy of 4 kg water when it is heated from $4{ }^{\circ} \mathrm{C}$ to $20^{\circ} \mathrm{C}$ is $\_\_\_\_$ J. (Specific heat capacity of water $=4.2 \mathrm{~J} / \mathrm{kg}$. and 1 atmospheric pressure $=10^{5} \mathrm{~Pa}$ )

Two resistors of $100 \Omega$ each are connected in series with a 9 V battery. A voltmeter of $400 \Omega$ resistance is connected to measure the voltage drop across one of the resistors. The voltmeter reading is $\_\_\_\_$ V.

The exit surface of a prism with refractive index $n$ is coated with a material having refractive index $\frac{\mathrm{n}}{2}$. When this prism is set for minimum angle of deviation it exactly meets the condition of critical angle. The prism angle is $\_\_\_\_$

Two electrons are moving in orbits of two hydrogen like atoms with speeds $3 \times 10^{5} \mathrm{~m} / \mathrm{s}$ and $2.5 \times 10^{5} \mathrm{~m} / \mathrm{s}$ respectively. If the radii of these orbits are nearly same then the possible order of energy states are $\_\_\_\_$ respectively.

In a microscope of tube length 10 cm two convex lenses are arranged with focal length of 2 cm and 5 cm . Total magnification obtained with this system for normal adjustment is $(5)^{\mathrm{k}}$. The value of k is $\_\_\_\_$

For the series LCR circuit connected with 220 V , 50 Hz a.c source as shown in the figure, the power factor is $\frac{\alpha}{10}$. The value of $\alpha$ is $\_\_\_\_$

Match the List-I with List-II

Choose the correct answer from the options given below:

A spring of force constant $15 \mathrm{~N} / \mathrm{m}$ is cut into two pieces. If the ratio of their length is $1: 3$, then the force constant of smaller piece is $\_\_\_\_$ $\mathrm{N} / \mathrm{m}$

Two resistors $2 \Omega$ and $3 \Omega$ are connected in the gaps of bridge as shown in figure. The null point is obtained with the contact of jockey at some point on wire XY . When an unknown resistor is connected in parallel with $3 \Omega$ resistor, the null point is shifted by 22.5 cm toward Y . The resistance of unknown resistor is $\Omega$.

Given below are two statements : one is labelled as Statement I and the other is labelled as Statement II :

Statement I : For all elements, greater the mass of the nucleus, greater is the binding energy per nucleon.

Statement II : For all elements, nuclei with less binding energy per nucleon transforms to nuclei with greater binding energy per nucleon.

In the light of the above statements, choose the correct answer from the options given below:

A brass wire of length 2 m and radius 1 mm at $27^{\circ} \mathrm{C}$ is held taut between two rigid supports. Initially it was cooled to a temperature of $-43^{\circ} \mathrm{C}$ creating a tension T in the wire. The temperature to which the wire has to be cooled in order to increase the tension in it to 1.4 T , is $\_\_\_\_$ ${ }^{\circ} \mathrm{C}$

The electrostatic potential in a charged spherical region of radius $r$ varies as $V=a r^{3}+b$, where $a$ and $b$ are constants. The total charge in the sphere of unit radius is $\alpha \times \pi \mathrm{a} \in_{0}$. The value of $\alpha$ is $\_\_\_\_$ . (permittivity of vacuum is $\in_{0}$ )

Two masses 400 g and 350 g are suspended from the ends of a light string passing over a heavy pulley of radius 2 cm . When released from rest the heavier mass is observed to fall 81 cm in 9 s . The rotational inertia of the pulley is $\_\_\_\_$ $\mathrm{kg} . \mathrm{m}^{2}$. ( $\mathrm{g}=9.8 \mathrm{~m} / \mathrm{s}^{2}$ )

An unpolarised light is incident at an interface of two dielectric media having refractive indices of 2 (incident medium) and $2 \sqrt{3}$ (medium) respectively. To satisfy the condition that reflected and refracted rays are perpendicular to each other, the angle of incidence is $\_\_\_\_$ .

A boy thrown a ball into air at $45^{\circ}$ from the horizontal to land it on a roof of a building of height H . If the ball attains maximum height in 2 s and lands on the building in 3 s after launch, then value of H is $\_\_\_\_$ m. $\left(\mathrm{g}=10 \mathrm{~m} / \mathrm{s}^{2}\right)$

There are three co-centric conducting spherical shells $\mathrm{A}, \mathrm{B}$ and C of radii $\mathrm{a}, \mathrm{b}$ and c respectively. The potential of the spheres $\mathrm{A}, \mathrm{B}$ and C respectively, are :

Three masses $200 \mathrm{~kg}, 300 \mathrm{~kg}$ and 400 kg are placed at the vertices of an equilateral triangle with sides 20 m . They are rearranged on the vertices of a bigger triangle of side 25 m and with the same centre. The work done in this process $\_\_\_\_$ J. (Gravitational constant $\mathrm{G}=6.7 \times 10^{-11} \mathrm{~N} \mathrm{~m}^{2} / \mathrm{kg}^{2}$ )

A short bar magnet placed with its axis at $30^{\circ}$ with an external field of 800 Gauss, experiences a torque of 0.016 N.m. The work done in moving it from most stable to most unstable position is $\alpha \times 10^{-3} \mathrm{~J}$. The value of $\alpha$ is $\_\_\_\_$ .

A voltage regulating circuit consisting of Zener diode, having break-down voltage of 10 V and maximum power dissipation of 0.4 W , is operated at 15 V . The approximate value of protective resistance in this circuit is $\_\_\_\_$ $\Omega$.

In the given figure the blocks $\mathrm{A}, \mathrm{B}$ and C weigh $4 \mathrm{~kg}, 6 \mathrm{~kg}$ and 8 kg respectively. The co-efficient of sliding friction between any two surfaces is 0.5 . The force $\overrightarrow{\mathrm{F}}$ required to slide the block C with constant speed is $\_\_\_\_$ N . (Used $\mathrm{g}=10 \mathrm{~m} / \mathrm{s}^{2}$ )

Sixty four rain drops of radius 1 mm each falling down with a terminal velocity of $10 \mathrm{~cm} / \mathrm{s}$ coalesce to form a bigger drop. The terminal velocity of bigger drop is $\_\_\_\_$ $\mathrm{cm} / \mathrm{s}$.

Given below are two statements : one is labelled as Statement I and the other is labelled as Statement II :

Statement-I: Hybridisation, shape and spin only magnetic moment of $\mathrm{K}_{3}\left[\mathrm{Co}\left(\mathrm{CO}_{3}\right)_{3}\right]$ is $\mathrm{sp}^{3} \mathrm{~d}^{2}$, octahedral and 4.9 BM respectively.

Statement-II: Geometry, hybridisation and spin only magnetic moment values (BM) of the ions $\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]^{2-},\left[\mathrm{MnBr}_{4}\right]^{2-}$ and $\left[\mathrm{CoF}_{6}\right]^{3-}$ respectively are square planar, tetrahedral, octahedral : $\mathrm{dsp}^{2}, \mathrm{sp}^{3}$, $\mathrm{sp}^{3} \mathrm{~d}^{2}$ and 0, 5.9, 4.9.

In the light of the above statements, choose the correct answer from the options given below

$\mathrm{A} \rightarrow \mathrm{D}$ is an endothermic reaction occurring in three steps (elementary).

(i) $\mathrm{A} \rightarrow \mathrm{B} \Delta \mathrm{H}_{\mathrm{i}}=+\mathrm{ve}$

(ii) $\mathrm{B} \rightarrow \mathrm{C} \Delta \mathrm{H}_{\mathrm{ii}}=-\mathrm{ve}$

(iii) $\mathrm{C} \rightarrow \mathrm{D} \Delta \mathrm{H}_{\text {iii }}=-\mathrm{ve}$

Which of the following graphs between potential energy ( y -axis) vs reaction coordinate ( x -axis) correctly represents the reaction profile of $\mathrm{A} \rightarrow \mathrm{D}$ ?

Given below are statements about some molecules/ions. Identify the CORRECT statements.

A. The dipole moment value of $\mathrm{NF}_{3}$ is higher than that of $\mathrm{NH}_{3}$. B. The dipole moment value of $\mathrm{BeH}_{2}$ is zero.

C. The bond order of $\mathrm{O}_{2}^{2-}$ and $\mathrm{F}_{2}$ is same.

D. The formal charge on the central oxygen atom of ozone is -1 .

E. In $\mathrm{NO}_{2}$, all the three atoms satisfy the octet rule, hence it is very stable.

Choose the correct answer from the options given below :

A solution is prepared by dissolving 0.3 g of a nonvolatile non-electrolyte solute ' A ' of molar mass $60 \mathrm{~g} \mathrm{~mol}^{-1}$ and 0.9 g of a non-volatile nonelectrolyte solute ' B ' of molar mass $180 \mathrm{~g} \mathrm{~mol}^{-1}$ in $100 \mathrm{~mL} \mathrm{H}_{2} \mathrm{O}$ at $27^{\circ} \mathrm{C}$. Osmotic pressure of the solution will be[0pt] [Given : $\mathrm{R}=0.082 \mathrm{~L} \mathrm{~atm} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}$ ]

The correct stability order of the following diazonium salts is

Consider a mixture ' X ' which is made by dissolving 0.4 mol of $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{5} \mathrm{SO}_{4}\right] \mathrm{Br}$ and 0.4 mol of $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{5} \mathrm{Br}\right] \mathrm{SO}_{4}$ in water to make 4 L of solution. When 2 L of mixture ' X ' is allowed to react with excess of $\mathrm{AgNO}_{3}$, it forms precipitate ' Y '. The rest 2 L of mixture ' X ' reacts with excess $\mathrm{BaCl}_{2}$ to form precipitate ' $Z$ '. Which of the following statements is CORRECT.

Given below are two statements : one is labelled as Statement I and the other is labelled as Statement II :

Statements-I : The number of paramagnetic species among $\left[\mathrm{CoF}_{6}\right]^{3-}, \quad\left[\mathrm{TiF}_{6}\right]^{3-}, \quad \mathrm{V}_{2} \mathrm{O}_{5}$ and $\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{3-}$ is 3 .

Statement-II : $\mathrm{K}_{4}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]<\mathrm{K}_{3}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]< \left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{SO}_{4} \cdot \mathrm{H}_{2} \mathrm{O}<\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{Cl}_{3}$ is the correct order in terms of number of unpaired electron(s) in the complexes.

In the light of the above statements, choose the correct answer from the options given below.

Consider three metal chlorides $\mathrm{x}, \mathrm{y}$ and z , where x is water soluble at room temperature, $y$ is sparingly soluble in water at room temperature and z is soluble in hot water. $\mathrm{x}, \mathrm{y}$ and z are respectively

W ' g of a non-volatile electrolyte solid solute of molar mass ' M ' $\mathrm{g} \mathrm{mol}^{-1}$ when dissolved in 100 mL water, decreases vapour pressure of water from 640 mm Hg to 600 mm Hg . If aqueous solution of the electrolyte boils at 375 K and $\mathrm{K}_{\mathrm{b}}$ for water is $0.52 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$, then the mole fraction of the electrolyte solute ( $\mathrm{x}_{2}$ ) in the solution can be expressed as (Given : density of water $=1 \mathrm{~g} / \mathrm{mL}$ and boiling point of water $=373 \mathrm{~K}$ )

Match the List-I with List-II

Choose the correct answer from the options given below :

A hydroxy compound ( X ) with molar mass 122 g $\mathrm{mol}^{-1}$ is acetylated with acetic anhydride, using a large excess of the reagent ensuring complete acetylation of all hydroxyl groups. The product obtained has a molar mass of $290 \mathrm{~g} \mathrm{~mol}^{-1}$. The number of hydroxyl groups present in compound $(\mathrm{X})$ is :

At $27^{\circ} \mathrm{C}$ in presence of a catalyst, activation energy of a reaction is lowered by $10 \mathrm{~kJ} \mathrm{~mol}^{-1}$. The logarithm ratio of $\frac{\mathrm{k} \text { (catalysed) }}{\mathrm{k} \text { (uncatalysed) }}$ is .... (Consider that the frequency factor for both the reactions is same)

Given below are two statements : one is labelled as Statement I and the other is labelled as Statement II :

Statement I: ' $\mathrm{C}-\mathrm{Cl}$ ' bond is stronger in $\mathrm{CH}_{2}=\mathrm{CH}-\mathrm{Cl}$ than $\mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{Cl}$

Statement II : The given optically active molecule, on hydrolysis gives a solution that can rotate the plane polarized light.

In the light of the above statements, choose the correct answer from the options given below

Arrange the following carbanions in the decreasing order of stability

I. $p-\mathrm{Br}-\mathrm{C}_{6} \mathrm{H}_{4}-\underset{\ddot{\mathrm{C}} \mathrm{H}_{2}}{\ominus}$

II. $\mathrm{C}_{6} \mathrm{H}_{5}-\stackrel{\ominus}{\stackrel{\ominus}{\mathrm{C}}} \mathrm{H}_{2}$

III. $p-\mathrm{CH}_{3} \mathrm{O}-\mathrm{C}_{6} \mathrm{H}_{4}-\stackrel{\ominus}{\stackrel{\ominus}{\mathrm{C}}} \mathrm{H}_{2}$

IV. $p-\mathrm{CHO}-\mathrm{C}_{6} \mathrm{H}_{4}-\stackrel{\ominus}{\stackrel{\ominus}{\mathrm{C}}} \mathrm{H}_{2}$

V. $p-\mathrm{CH}_{3}-\mathrm{C}_{6} \mathrm{H}_{4}-\stackrel{\ominus}{\stackrel{\ominus}{\mathrm{C}}} \mathrm{H}_{2}$

Choose the correct answer from the options given below :

Given below are two statements : one is labelled as Statement I and the other is labelled as Statement II :

Statement I: $\mathrm{K}>\mathrm{Mg}>\mathrm{Al}>\mathrm{B}$ is the correct order in terms of metallic character.

Statement II: Atomic radius is always greater than the ionic radius for any element.

In the light of the above statements, choose the correct answer from the options given below:

Electricity is passed through an acidic solution of $\mathrm{Cu}^{2+}$ till all the $\mathrm{cu}^{2+}$ was exhausted, leading to the deposition of 300 mg of Cu metal. However, a current of 600 mA was continued to pass through the same solution for another 28 minutes by keeping the total volume of the solution fixed at 200 mL . The total volume of oxygen evolved at STP during the entire process is $\_\_\_\_$ mL. (Nearest integer) [Given : $\mathrm{Cu}^{2+}(\mathrm{aq})+2 \mathrm{e}^{-} \rightarrow \mathrm{Cu}(\mathrm{s}) \mathrm{E}_{\text {red }}^{0}=+0.34 \mathrm{~V}$ $\mathrm{O}_{2}(\mathrm{~g})+4 \mathrm{H}^{+}+4 \mathrm{e}^{-} \rightarrow 2 \mathrm{H}_{2} \mathrm{O} \mathrm{E}_{\text {red }}^{0}=+1.23 \mathrm{~V}$ Molar mass of $\mathrm{Cu}=63.54 \mathrm{~g} \mathrm{~mol}^{-1}$ Molar mass of $\mathrm{O}_{2}=32 \mathrm{~g} \mathrm{~mol}^{-1}$ Faraday Constant $=96500 \mathrm{C} \mathrm{mol}^{-1}$ Molar volume at $\mathrm{STP}=22.4 \mathrm{~L}$ ]