Chemistry · p-Block Elements (Group 15-18)

JEE Main 2026 — 5 April, Morning Shift — Question 57

Correct statements from the following are : A. Nitrogen in oxidation states from +1 to +4 disproportionates in acid medium. B. Nitrogen has the ability of form dπ−pπ\mathrm{d} \pi-\mathrm{p} \pi multiple bonds with itself and other elements with small size and high electronegativity. C. N-N single bond is stronger than P-P single bond. D. Nitrogen has highest density in its group due to small size. E. The maximum covalency of nitrogen is four since it has only four valence orbitals for bonding. Choose the correct answer from the options given below :

  1. Option A:

    B, C, and D only

  2. Option B:

    C, D, and E only

  3. Option C:

    A, C and E only

  4. Option D:

    A and E only

    Correct

Answer: D

Step-by-step solution

(A) In the case of nitrogen, all oxidation states from +1 to +4 tend to disproportionate in acid solution. For example. 3HNO2→HNO3+H2O+2NO3 \mathrm{HNO}_{2} \rightarrow \mathrm{HNO}_{3}+\mathrm{H}_{2} \mathrm{O}+2 \mathrm{NO} (B) Nitrogen form pπ−pπp_{\pi}-p_{\pi} bonds with itself and other elements with small size and high electronegativity, dπ−pπd_{\pi}-p_{\pi} is not possible with itself as it has no d-orbital. (C) The single N−N\mathrm{N}-\mathrm{N} bond is weaker than the single P−P\mathrm{P}-\mathrm{P} bond because of high intereelecronic repulsion of the non-bonding electrons (lone pair), owing to the small bond length. (D) Nitrogen has lowest density in its group. (E) The maximum covalency of nitrogen is four.

Correct answer are (A) and (E)

Answer key and solution verified before publishing.

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Exam
JEE Main 2026
Subject
Chemistry
Chapter
p-Block Elements (Group 15-18)
Topic
Introduction & Properties of Group 15: Nitrogen Family
Correct statements from the following are : A. Nitrogen in oxidation… | JEE Main 2026 PYQ with Solution · DhiX AI