JEE Advanced 2019 · previous year paper

JEE Advanced 2019 — Paper 1

46 questions with the verified answer key. Open any question for its step-by-step solution.

  1. Question 1Physics· Gravitation

    Consider a spherical gaseous cloud of mass density ρ(r)\rho(r) in free space where rr is the radial distance from its center. The gaseous cloud is made of particles of equal mass moving in circular orbits about the common center with the same kinetic energy K. The force acting on the particles is their mutual gravitational force. If ρ(r)\rho(\mathrm{r}) is constant in time, the particle number density n(r)=ρ(r)/m\mathrm{n}(\mathrm{r})=\rho(\mathrm{r}) / \mathrm{m} is[0pt] [ GG is universal gravitational constant]

    1. Option A:

      3 Kπr2 m2G\frac{3 \mathrm{~K}}{\pi \mathrm{r}^{2} \mathrm{~m}^{2} \mathrm{G}}

    2. Option B:

      K2πr2 m2G\frac{\mathrm{K}}{2 \pi \mathrm{r}^{2} \mathrm{~m}^{2} \mathrm{G}}

    3. Option C:

      K6πr2 m2G\frac{\mathrm{K}}{6 \pi \mathrm{r}^{2} \mathrm{~m}^{2} \mathrm{G}}

    4. Option D:

      Kπr2m2G\frac{K}{\pi r^{2} m^{2} G}

  2. Question 2Physics· Electrostatics

    A thin spherical insulating shell of radius R carries a uniformly distributed charge such that the potential at its surface is V0V_{0}. A hole with a small area α4πR2(α≪1)\alpha 4 \pi R^{2}(\alpha \ll 1) is made on the shell without affecting the rest of the shell. Which one of the following statements is correct?

    1. Option A:

      The magnitude of electric field at a point, located on a line passing through the hole and shell's center, on a distance 2R2 R from the center of the spherical shell will be reduced by αV02R\frac{\alpha V_{0}}{2 R}

    2. Option B:

      The magnitude of electric field at the center of the shell is reduced by αV02R\frac{\alpha V_{0}}{2 R}

    3. Option C:

      The ratio of the potential at the center of the shell to that of the point at 12R\frac{1}{2} \mathrm{R} from center towards the hole will be 1−α1−2α\frac{1-\alpha}{1-2 \alpha}

    4. Option D:

      The potential at the center of the shell is reduced by 2α V02 \alpha \mathrm{~V}_{0}

  3. Question 3Physics· Thermodynamics

    A current carrying wire heats a metal rod. The wire provides a constant power ( P ) to the rod. The metal rod is enclosed in an insulated container. It is observed that the temperature (T)(\mathrm{T}) in the metal rod changes with time ( t ) as T(t)=T0(1+βt1/4)\mathrm{T}(\mathrm{t})=\mathrm{T}_{0}\left(1+\beta \mathrm{t}^{1 / 4}\right) where β\beta is a constant with appropriate dimension while T0\mathrm{T}_{0} is a constant with dimension of temperature. The heat capacity of the metal is

    1. Option A:

      4P(T(t)−T0)4β4 T05\frac{4 \mathrm{P}\left(\mathrm{T}(\mathrm{t})-\mathrm{T}_{0}\right)^{4}}{\beta^{4} \mathrm{~T}_{0}^{5}}

    2. Option B:

      4P(T(t)−T0)β4 T02\frac{4 \mathrm{P}\left(\mathrm{T}(\mathrm{t})-\mathrm{T}_{0}\right)}{\beta^{4} \mathrm{~T}_{0}^{2}}

    3. Option C:

      4P(T(t)−T0)2β4 T02\frac{4 \mathrm{P}\left(\mathrm{T}(\mathrm{t})-\mathrm{T}_{0}\right)^{2}}{\beta^{4} \mathrm{~T}_{0}^{2}}

    4. Option D:

      4P(T(t)−T0)3β4 T04\frac{4 \mathrm{P}\left(\mathrm{T}(\mathrm{t})-\mathrm{T}_{0}\right)^{3}}{\beta^{4} \mathrm{~T}_{0}^{4}}

  4. Question 4Physics· Nuclear Physics

    In a radioactive sample 1940 K{ }_{19}^{40} \mathrm{~K} nuclei either decay into stable 2040Ca{ }_{20}^{40} \mathrm{Ca} nuclei with decay constant 4.5×10−104.5 \times 10^{-10} per year or into stable 1840Ar{ }_{18}^{40} \mathrm{Ar} nuclei with decay constant 0.5×10−100.5 \times 10^{-10} per year. Given that in this sample all the stable 2040Ca{ }_{20}^{40} \mathrm{Ca} and 1840Ar{ }_{18}^{40} \mathrm{Ar} nuclei are produced by the 1940 K{ }_{19}^{40} \mathrm{~K} nuclei only. In time t×109\mathrm{t} \times 10^{9} years, if the ratio of the sum of stable 2040Ca{ }_{20}^{40} \mathrm{Ca} and 1840Ar{ }_{18}^{40} \mathrm{Ar} nuclei to the radioactive 1940 K{ }_{19}^{40} \mathrm{~K} nuclei is 99 , the value of t will be [Given :ln⁡10=2.3: \ln 10=2.3 ]

    1. Option A:

      1.15

    2. Option B:

      4.6

    3. Option C:

      9.2

    4. Option D:

      2.3

  5. Question 5Physics· Electromagnetic Induction

    A conducting wire of parabolic shape, initially y=x2y=x^{2}, is moving with velocity V⃗=V0i^\vec{V}=V_{0} \hat{i} in a non uniform magnetic field B→=B0(1+(yL)β)k^\overrightarrow{\mathrm{B}}=\mathrm{B}_{0}\left(1+\left(\frac{\mathrm{y}}{\mathrm{L}}\right)^{\beta}\right) \hat{\mathrm{k}}, as shown in figure. If V0\mathrm{V}_{0} , B0, L\mathrm{B}_{0}, \mathrm{~L} and β\beta are positive constants and Δϕ\Delta \phi is the potential difference developed between the ends of the wire, then the correct statement(s) is/are:

    Question 5 figure
    1. Option A:

      ∣Δϕ∣|\Delta \phi| is proportional to the length of the wire projected on the yy-axis.

    2. Option B:

      ∣Δϕ∣|\Delta \phi| remains the same if the parabolic wire is replaced by a straight wire, y=x\mathrm{y}=\mathrm{x} initially, of length 2 L\sqrt{2} \mathrm{~L}

    3. Option C:

      ∣Δϕ∣=12 B0 V0 L|\Delta \phi|=\frac{1}{2} \mathrm{~B}_{0} \mathrm{~V}_{0} \mathrm{~L} for β=0\beta=0

    4. Option D:

      ∣Δϕ∣=43 B0 V0 L|\Delta \phi|=\frac{4}{3} \mathrm{~B}_{0} \mathrm{~V}_{0} \mathrm{~L} for β=2\beta=2

  6. Question 6Physics· Geometrical Optics

    A thin convex lens is made of two materials with refractive indices n1n_{1} and n2n_{2}, as shown in figure. The radius of curvature of the left and right spherical surfaces are equal. ff is the focal length of the lens when n1=n2=n\mathrm{n}_{1}=\mathrm{n}_{2}=\mathrm{n}. The focal length is f+f+ Δf\Delta f when n1=n\mathrm{n}_{1}=\mathrm{n} and n2=n+Δn\mathrm{n}_{2}=\mathrm{n}+\Delta \mathrm{n}. Assuming Δn≪(n−1)\Delta \mathrm{n} \ll(\mathrm{n}-1) and 1<n<21<\mathrm{n}<2. The correct statement(s) is/are.

    Question 6 figure
    1. Option A:

      ∣Δff∣<∣Δnn∣\left|\frac{\Delta f}{f}\right|<\left|\frac{\Delta \mathrm{n}}{\mathrm{n}}\right|

    2. Option B:

      If Δnn<0\frac{\Delta \mathrm{n}}{\mathrm{n}}<0 then Δff>0\frac{\Delta \mathrm{f}}{\mathrm{f}}>0

    3. Option C:

      For n=1.5,Δn=10−3\mathrm{n}=1.5, \Delta \mathrm{n}=10^{-3} and f=20 cm\mathrm{f}=20 \mathrm{~cm}, the value of ∣Δf∣|\Delta \mathrm{f}| will be 0.02 cm (round off to 2nd 2^{\text {nd }} decimal place).

    4. Option D:

      The relation between Δff\frac{\Delta \mathrm{f}}{\mathrm{f}} and Δnn\frac{\Delta \mathrm{n}}{\mathrm{n}} remains unchanged if both the convex surfaces are replaced by concave surfaces of the same radius of curvature.

  7. Question 7Physics· Mechanical Properties of Matter

    A cylindrical capillary tube of 0.2 mm radius is made by joining two capillaries T1\mathrm{T}_{1} and T2\mathrm{T}_{2} of different materials having water contact angles of 0∘0^{\circ} and 60∘60^{\circ}, respectively. The capillary tube is dipped vertically in water in two different configurations, case I and II as shown in figure. Which of the following option(s) is (are) correct?[0pt] [Surface tension of a water =0.075 N/m=0.075 \mathrm{~N} / \mathrm{m}, density of water =1000 kg/m3=1000 \mathrm{~kg} / \mathrm{m}^{3}, take g=10 m/s2\mathrm{g}=10 \mathrm{~m} / \mathrm{s}^{2} ]

    Question 7 figure
    1. Option A:

      For case II, if the joint is kept at 8 cm above the water surface, the height of water column in the tube will be 7.5 cm . (Neglect the weight of the water in the meniscus)

    2. Option B:

      For case I, if the capillary joint is 5 cm above the water surface, the height of water column raised in the tube will be more than 8.75 cm . (Neglect the weight of the water in the meniscus)

    3. Option C:

      For case II, if the capillary joint is 5 cm above the water surface, the height of water column raised in the tube will be 3.75 cm . (Neglect the weight of the water in the meniscus)

    4. Option D:

      The correction in the height of water column raised in the tube, due to weight of water contained in the meniscus, will be different for both cases.

  8. Question 8Physics· Units, Dimensions & Error Analysis

    Let us consider a system of units in which mass and angular momentum are dimensionless. If length has dimension of L , which of the following statement(s) is/are correct?

    1. Option A:

      The dimension of energy is L−2\mathrm{L}^{-2}

    2. Option B:

      The dimension of force is L−3\mathrm{L}^{-3}

    3. Option C:

      The dimension of power is L−5\mathrm{L}^{-5}

    4. Option D:

      The dimension of linear momentum is L−1\mathrm{L}^{-1}

  9. Question 9Physics· Capacitors and R-C Circuits

    In the circuit shown, initially there is no charge on capacitors and keys S1S_{1} and S2S_{2} are open. The values of the

    capacitors are C1=10μ F,C2=30μ F\mathrm{C}_{1}=10 \mu \mathrm{~F}, \mathrm{C}_{2}=30 \mu \mathrm{~F} and C3\mathrm{C}_{3} =C4=80μ F=\mathrm{C}_{4}=80 \mu \mathrm{~F}. Which of the statement(s) is/are

    correct?

    Question 9 figure
    1. Option A:

      The key S1S_{1} is kept closed for long time such that capacitors are fully charged. Now key S2S_{2} is closed, at this time, the instantaneous current across 30Ω30 \Omega resistor (between points P and Q ) will be 0.2 A (round off to 1st 1^{\text {st }} decimal place).

    2. Option B:

      If key S1\mathrm{S}_{1} is kept closed for long time such that capacitors are fully charged, the voltage across the capacitor C1\mathrm{C}_{1} will be 4 V .

    3. Option C:

      At time t=0t=0, the key S1S_{1} is closed, the instantaneous current in the closed circuit will be 25 mA

    4. Option D:

      If key S1S_{1} is kept closed for long time such that capacitors are fully charged, the voltage difference between points P and Q will be 10 V .

  10. Question 10Physics· Thermodynamics

    One mole of a monatomic ideal gas goes through a thermodynamic cycle, as shown in the volume versus temperature (V−T)(\mathrm{V}-\mathrm{T}) diagram. The correct statement(s) is/are:

    [ R is the gas constant]

    Question 10 figure
    1. Option A:

      Work done in this thermodynamic cycle (1→2→3→4→1)(1 \rightarrow 2 \rightarrow 3 \rightarrow 4 \rightarrow 1) is ∣W∣=12RT0|\mathrm{W}|=\frac{1}{2} R T_{0}

    2. Option B:

      The ratio of heat transfer during processes 1→21 \rightarrow 2 and 2→32 \rightarrow 3 is ∣Q1→2Q2→3∣=53\left|\frac{Q_{1 \rightarrow 2}}{Q_{2 \rightarrow 3}}\right|=\frac{5}{3}

    3. Option C:

      The above thermodynamic cycle exhibits only isochoric and adiabatic processes.

    4. Option D:

      The ratio of heat transfer during processes 1→21 \rightarrow 2 and 3→43 \rightarrow 4 is ∣Q1→2Q3→4∣=12\left|\frac{Q_{1 \rightarrow 2}}{Q_{3 \rightarrow 4}}\right|=\frac{1}{2}

  11. Question 11Physics· Current Electricity

    Two identical moving coil galvanometers have 10Ω10 \Omega resistance and full scale deflection at 2μ A2 \mu \mathrm{~A} current. One of them is converted into a voltmeter of 100 mV full scale reading and the other into an Ammeter of 1 mA full scale current using appropriate resistors. These are then used to measure the voltage and current in the Ohm's law experiment with R=1000Ω\mathrm{R}=1000 \Omega resistor by using an ideal cell. Which of the following statement(s) is/are correct?

    1. Option A:

      The measured value of R will be 978Ω<R<982Ω978 \Omega<\mathrm{R}<982 \Omega

    2. Option B:

      The resistance of the Voltmeter will be 100kΩ100 \mathrm{k} \Omega

    3. Option C:

      If the ideal cell is replaced by a cell having internal resistance of 5Ω5 \Omega then the measured value of R will be more than 1000Ω1000 \Omega

    4. Option D:

      The resistance of the Ammeter will be 0.02Ω0.02 \Omega (round off to 2nd 2^{\text {nd }} decimal place)

  12. Question 12Physics· Mechanical Properties of Matter

    A block of weight 100 N is suspended by copper and steel wires of same cross sectional area 0.5 cm20.5 \mathrm{~cm}^{2} and, length 3 m\sqrt{3} \mathrm{~m} and 1 m , respectively. Their other ends are fixed on a ceiling as shown in figure. The angles subtended by copper and steel wires with ceiling are 30∘30^{\circ} and 60∘60^{\circ}, respectively. If elongation in copper wire is (ΔℓC)\left(\Delta \ell_{C}\right) and elongation in steel wire is (ΔℓS)\left(\Delta \ell_{\mathrm{S}}\right), then the ratio ΔℓCΔℓS\frac{\Delta \ell_{\mathrm{C}}}{\Delta \ell_{\mathrm{S}}} is ____\_\_\_\_

    [Young's modulus for copper and steel are 1×1011 N/m21 \times 10^{11} \mathrm{~N} / \mathrm{m}^{2} and 2×1011 N/m22 \times 10^{11} \mathrm{~N} / \mathrm{m}^{2}, respectively.]

    Question 12 figure
  13. Question 13Physics· Work, Power & Energy

    A particle is moved along a path AB-BC-CD-DE-EF-FA, as shown in figure, in presence of a force F⃗=(αyi^+2αxj^)N\vec{F}=(\alpha y \hat{i}+2 \alpha x \hat{j}) N, where x and y are in meter and α=−1Nm−1\alpha=-1 \mathrm{Nm}^{-1}. The work done on the particle by this force F⃗\vec{F} will be ____\_\_\_\_ Joule.

    Question 13 figure
  14. Question 14Physics· Sound Waves

    A train S1, moving with a uniform velocity of 108 km/h\mathrm{km} / \mathrm{h}, approaches another train S2 standing on a platform. An observer O moves with a uniform velocity of 36 km/h36 \mathrm{~km} / \mathrm{h} towards S 2 , as shown in figure. Both the trains are blowing whistles of same frequency 120 Hz . When O is 600 m away from S2 and distance between S 1 and S 2 is 800 m , the number of beats heard by O is ____\_\_\_\_ . [Speed of the sound =330 m/s=330 \mathrm{~m} / \mathrm{s} ]

    Question 14 figure
  15. Question 15Physics· Thermal Properties of Matter

    A liquid at 30∘C30^{\circ} \mathrm{C} is poured very slowly into a Calorimeter that is at temperature of 110∘C110^{\circ} \mathrm{C}. The boiling temperature of the liquid is 80∘C80^{\circ} \mathrm{C}. It is found that the first 5 gm of the liquid completely evaporates. After pouring another 80 gm of the liquid the equilibrium temperature is found to be 50∘C50^{\circ} \mathrm{C}. The ratio of the Latent heat of the liquid to its specific heat will be ____\_\_\_\_ ∘C{ }^{\circ} \mathrm{C}. [Neglect the heat exchange with surrounding]

  16. Question 16Physics· Geometrical Optics

    A planar structure of length L and width W is made of two different optical media of refractive indices n1=1.5\mathrm{n}_{1}=1.5 and n2=1.44\mathrm{n}_{2}=1.44 as shown in figure. If L≫W\mathrm{L} \gg \mathrm{W}, a ray entering from end AB will emerge from end CD only if the total internal reflection condition is met inside the structure. For L=9.6 m\mathrm{L}=9.6 \mathrm{~m}, if the incident angle θ\theta is varied, the maximum time taken by a ray to exit the plane CD is t×10−9 s\mathrm{t} \times 10^{-9} \mathrm{~s}, where t is ____\_\_\_\_ . [Speed of light c=3×108 m/s\mathrm{c}=3 \times 10^{8} \mathrm{~m} / \mathrm{s} ]

    Question 16 figure
  17. Question 17Physics· Capacitors and R-C Circuits

    A parallel plate capacitor of capacitance CC has spacing dd between two plates having area A. The region between the plates is filled with N dielectric layers, parallel to its plates, each with thickness δ=dN\delta=\frac{\mathrm{d}}{\mathrm{N}}. The dielectric constant of the mth m^{\text {th }} layer is Km=K(1+mN)K_{m}=K\left(1+\frac{m}{N}\right). For a very large N(>103)N\left(>10^{3}\right), the capacitance CC is α(Kε0Adln⁡2)\alpha\left(\frac{K \varepsilon_{0} A}{d \ln 2}\right). The value of α\alpha will be ____\_\_\_\_ . [ ϵ0\epsilon_{0} is the permittivity of free space]

  18. Question 18Chemistry· Practical Inorganic chemistry (Qualitative Analysis)

    The green colour produced in the borax bead test of a chromium(III) salt is due to

    1. Option A:

      CrB

    2. Option B:

      Cr2O3\mathrm{Cr}_{2} \mathrm{O}_{3}

    3. Option C:

      Cr2( B4O7)3\mathrm{Cr}_{2}\left(\mathrm{~B}_{4} \mathrm{O}_{7}\right)_{3}

    4. Option D:

      Cr(BO2)3\mathrm{Cr}\left(\mathrm{BO}_{2}\right)_{3}

  19. Question 19Chemistry· Metallurgy

    Calamine, malachite, magnetite and cryolite, respectively, are

    1. Option A:

      ZnSO4,Cu(OH)2,Fe3O4,Na3AlF6\mathrm{ZnSO}_{4}, \mathrm{Cu}(\mathrm{OH})_{2}, \mathrm{Fe}_{3} \mathrm{O}_{4}, \mathrm{Na}_{3} \mathrm{AlF}_{6}

    2. Option B:

      ZnCO3,CuCO3⋅Cu(OH)2,Fe3O4,Na3AlF6\mathrm{ZnCO}_{3}, \mathrm{CuCO}_{3} \cdot \mathrm{Cu}(\mathrm{OH})_{2}, \mathrm{Fe}_{3} \mathrm{O}_{4}, \mathrm{Na}_{3} \mathrm{AlF}_{6}

    3. Option C:

      ZnSO4,CuCO3,Fe2O3,AlF3\mathrm{ZnSO}_{4}, \mathrm{CuCO}_{3}, \mathrm{Fe}_{2} \mathrm{O}_{3}, \mathrm{AlF}_{3}

    4. Option D:

      ZnCO3,CuCO3,Fe2O3,Na3AlF6\mathrm{ZnCO}_{3}, \mathrm{CuCO}_{3}, \mathrm{Fe}_{2} \mathrm{O}_{3}, \mathrm{Na}_{3} \mathrm{AlF}_{6}

  20. Question 20Chemistry· Biomolecules

    Which of the following statements(s) is (are) true ?

    1. Option A:

      Oxidation of glucose with bromine water gives glutamic acid

    2. Option B:

      The two six-membered cyclic hemiacetal forms of D-(+)-glucose are called anomers

    3. Option C:

      Monosaccharides cannot be hydrolysed to give polyhydroxy aldehydes and ketones

    4. Option D:

      Hydrolysis of sucrose gives dextrorotatory glucose and laevorotatory fructose

  21. Question 21Chemistry· Thermodynamics & Thermochemistry

    Choose the reaction(s) from the following options, for which the standard enthalpy of reaction is equal to the standard enthalpy of formation.

    1. Option A:

      2C(g)+3H2( g)⟶C2H6( g)2 \mathrm{C}(\mathrm{g})+3 \mathrm{H}_{2}(\mathrm{~g}) \longrightarrow \mathrm{C}_{2} \mathrm{H}_{6}(\mathrm{~g})

    2. Option B:

      32O2( g)⟶O3( g)\frac{3}{2} \mathrm{O}_{2}(\mathrm{~g}) \longrightarrow \mathrm{O}_{3}(\mathrm{~g})

    3. Option C:

      2H2( g)+O2( g)⟶2H2O(ℓ)2 \mathrm{H}_{2}(\mathrm{~g})+\mathrm{O}_{2}(\mathrm{~g}) \longrightarrow 2 \mathrm{H}_{2} \mathrm{O}(\ell)

    4. Option D:

      18 S8( s)+O2( g)⟶SO2( g)\frac{1}{8} \mathrm{~S}_{8}(\mathrm{~s})+\mathrm{O}_{2}(\mathrm{~g}) \longrightarrow \mathrm{SO}_{2}(\mathrm{~g})

  22. Question 22Chemistry· Chemical Bonding

    Fusion of MnO2\mathrm{MnO}_{2} with KOH in presence of O2\mathrm{O}_{2} produces a salt W . Alkaline solution of W upon electrolytic oxidation yields another salt X . The manganese containing ions present in W and X , respectively, are Y and Z. Correct statement(s) is(are)

    1. Option A:

      In aqueous acidic solution, Y undergoes disproportionation reaction to give Z and MnO2\mathrm{MnO}_{2}

    2. Option B:

      In both Y and Z,π\mathrm{Z}, \pi-bonding occurs between p-orbitals of oxygen and d-orbitals of manganese

    3. Option C:

      Y is diamagnetic in nature while Z is paramagnetic

    4. Option D:

      Both Y and Z are coloured and have tetrahedral shape

  23. Question 23Chemistry· States of Matter - Gaseous State

    Which of the following statement(s) is(are) correct regarding the root mean square speed ( Urms\mathrm{U}_{\mathrm{rms}} ) and average translational kinetic energy ( εav\varepsilon_{\mathrm{av}} ) of a molecule in a gas at equilibrium?

    1. Option A:

      εav\varepsilon_{\mathrm{av}} at a given temperature does not depend on its molecular mass

    2. Option B:

      Urms\mathrm{U}_{\mathrm{rms}} is doubled when its temperature is increased four times

    3. Option C:

      εav\varepsilon_{\mathrm{av}} is doubled when its temperature is increased four times

    4. Option D:

      Urms\mathrm{U}_{\mathrm{rms}} is inversely proportional to the square root of its molecular mass

  24. Question 24Chemistry· Structure of Atom

    In the decay sequence,

    92238U→−x190234Th→−x291234 Pa→−x3234Z→−x490230Th{ }_{92}^{238} \mathrm{U} \xrightarrow{-x_{1}}{ }_{90}^{234} \mathrm{Th} \xrightarrow{-x_{2}}{ }_{91}^{234} \mathrm{~Pa} \xrightarrow{-x_{3}}{ }^{234} \mathrm{Z} \xrightarrow{-\mathrm{x}_{4}}{ }_{90}^{230} \mathrm{Th}

    x1,x2,x3\mathrm{x}_{1}, \mathrm{x}_{2}, \mathrm{x}_{3} and x4\mathrm{x}_{4} are particles /radiation emitted by the respective isotopes. The correct option(s) is(are)

    1. Option A:

      x3x_{3} is γ\gamma-ray

    2. Option B:

      Z is an isotope of uranium

    3. Option C:

      x2\mathrm{x}_{2} is β−\beta^{-}

    4. Option D:

      x1x_{1} will deflect towards negatively charged plate

  25. Question 25Chemistry· Solutions and Colligative Properties

    On dissolving 0.5 g of a non-volatile non-ionic solute to 39 g of benzene, its vapour pressure decreases from 650 mm Hg to 640 mm Hg . The depression of freezing point of benzene (in K ) upon addition of the solute is (Given data: Molar mass and the molal freezing point depression constant of benzene are 78 g mol−178 \mathrm{~g} \mathrm{~mol}^{-1} and 5.12 K kg mol−15.12 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}, respectively)

  26. Question 26Chemistry· Chemical Equilibrium
    For the following reaction, the equilibrium constant Kc at 298 K is 1.6×1017\text{For the following reaction, the equilibrium constant } K_c \text{ at } 298 \text{ K is } 1.6 \times 10^{17} Fe2+(aq)+S2−(aq)⇌FeS(s)\text{Fe}^{2+}(aq) + \text{S}^{2-}(aq) \rightleftharpoons \text{FeS}(s) When equal volumes of 0.06 M Fe2+(aq) and 0.2 M S2−(aq) solutions are mixed, the \text{When equal volumes of } 0.06 \text{ M Fe}^{2+}(aq) \text{ and } 0.2 \text{ M S}^{2-}(aq) \text{ solutions are mixed, the }  equilibrium concentration of Fe2+(aq) is found to be Y×10−17 M. The value of Y is \text{ equilibrium concentration of Fe}^{2+}(aq) \text{ is found to be } Y \times 10^{-17} \text{ M. The value of } Y \text{ is }

    ……… \ldots \ldots \ldots

  27. Question 27Chemistry· Chemical Kinetics
    Experiment No.[A][\mathrm{A}] (mol  dm−3)\left(\mathrm{mol} \; \mathrm{dm}^{-3}\right)[B][\mathrm{B}] (mol  dm−3)\left(\mathrm{mol} \; \mathrm{dm}^{-3}\right)[C][\mathrm{C}] (mol  dm−3)\left(\mathrm{mol} \; \mathrm{dm}^{-3}\right)Rate of reaction (mol  dm−3 s−1)\left(\mathrm{mol} \; \mathrm{dm}^{-3} \mathrm{~s}^{-1}\right)
    10.20.10.16.0×10−56.0 \times 10^{-5}
    20.20.20.16.0×10−56.0 \times 10^{-5}
    30.20.10.21.2×10−51.2 \times 10^{-5}
    40.30.10.19.0×10−59.0 \times 10^{-5}

    The rate of the reaction for [A]=0.15 moldm−3,[ B]=0.25 moldm−3[\mathrm{A}]=0.15 \mathrm{~mol} \mathrm{dm}^{-3},[\mathrm{~B}]=0.25 \mathrm{~mol} \mathrm{dm}^{-3} and

    [C]=0.15 moldm−3[\mathrm{C}]=0.15 \mathrm{~mol} \mathrm{dm}^{-3} is found to be Y×10−5 moldm−3 s−1\mathrm{Y} \times 10^{-5} \mathrm{~mol} \mathrm{dm}^{-3} \mathrm{~s}^{-1}. The value of Y is

  28. Question 28Chemistry· p-Block Elements (Group 15-18)

    At 143 K , the reaction of XeF4\mathrm{XeF}_{4} with O2 F2\mathrm{O}_{2} \mathrm{~F}_{2} produces xenon compound Y. The total number of lone Pair(s) of electrons present on the whole molecule of Y is ____\_\_\_\_

  29. Question 29Mathematics· Matrices

    Let M=[sin⁡4θ−1−sin⁡2θ1+cos⁡2θcos⁡4θ]=α1+βM−1M=\left[\begin{array}{cc}\sin ^{4} \theta & -1-\sin ^{2}\\ \theta 1+\cos ^{2} \theta & \cos ^{4} \theta\end{array}\right]=\alpha 1+\beta M^{-1}, where α=α(θ)\alpha=\alpha(\theta) and β=β(θ)\beta=\beta(\theta) are

    real numbers, and 1 is the 2×22 \times 2 identity matrix. If α∗\alpha^{*} is the minimum of the set {α(θ):θ∈[0,2π)}\{\alpha(\theta): \theta \in[0,2 \pi)\} and β∗\beta^{*}

    is the minimum of the set {β(θ):θ∈[0,2π)}\{\beta(\theta): \theta \in[0,2 \pi)\}, then the value of α∗+β∗\alpha^{*}+\beta^{*} is

    1. Option A:

      −3716-\frac{37}{16}

    2. Option B:

      −3116-\frac{31}{16}

    3. Option C:

      −1716-\frac{17}{16}

    4. Option D:

      −2916-\frac{29}{16}

  30. Question 30Mathematics· Area under the Curves

    The area of the region {(x,y):xy≤8,1≤y≤x2}\left\{(x, y): x y \leq 8,1 \leq y \leq x^{2}\right\} is

    1. Option A:

      16log⁡e2−616 \log _{\mathrm{e}} 2-6

    2. Option B:

      8log⁡e2−143\quad 8 \log _{\mathrm{e}} 2-\frac{14}{3}

    3. Option C:

      16log⁡e2−14316 \log _{e} 2-\frac{14}{3}

    4. Option D:

      8log⁡e2−738 \log _{\mathrm{e}} 2-\frac{7}{3}

  31. Question 31Mathematics· Complex Numbers

    Let SS be the set of all complex numbers zz satisfying ∣z−2+i∣≥5|z-2+i| \geq \sqrt{5}. If the complex number z0z_{0} is such that 1∣z0−1∣\frac{1}{\left|z_{0}-1\right|} is the maximum of the set {1∣z−1∣:z∈S}\left\{\frac{1}{|z-1|}: z \in S\right\}, then the principal argument of 4−z0−z0‾z0−z0‾+2i\frac{4-z_{0}-\overline{z_{0}}}{z_{0}-\overline{z_{0}}+2 i} is

    1. Option A:

      3π4\frac{3 \pi}{4}

    2. Option B:

      π4\frac{\pi}{4}

    3. Option C:

      −π2-\frac{\pi}{2}

    4. Option D:

      π2\frac{\pi}{2}

  32. Question 32Mathematics· Circles

    A line y=mx+1y=m x+1 intersects the circle (x−3)2+(y+2)2=25(x-3)^{2}+(y+2)^{2}=25 at the points PP and QQ. If the midpoint

    of the line segment PQ has x -coordinate −35-\frac{3}{5}, then which one of the following options is correct?

    1. Option A:

      4≤m<64 \leq \mathrm{m}<6

    2. Option B:

      −3≤m<−1\quad-3 \leq \mathrm{m}<-1

    3. Option C:

      2≤m<42 \leq \mathrm{m}<4

    4. Option D:

      6≤m<86 \leq \mathrm{m}<8

  33. Question 33Mathematics· Sequence and Series

    Let α\alpha and β\beta be the roots of x2−x−1=0x^{2}-x-1=0, with α>β\alpha>\beta. For all positive integers nn, define

    an=an−βnα−β,n≥1,b1=1a_{n}=\frac{a^{n}-\beta^{n}}{\alpha-\beta}, \quad n \geq 1, b_{1}=1 and bn=an−1+an+1,n≥2b_{n}=a_{n-1}+a_{n+1}, n \geq 2. Then which of the following

    options is/are correct?

    1. Option A:

      ∑n=1∞bn10n=889\sum_{\mathrm{n}=1}^{\infty} \frac{\mathrm{b}_{\mathrm{n}}}{10^{\mathrm{n}}}=\frac{8}{89}

    2. Option B:

      bn=αn+βnb_{n}=\alpha^{n}+\beta^{n} for all n≥1n \geq 1

    3. Option C:

      a1+a2+a3+…..+an=an+2−1a_{1}+a_{2}+a_{3}+\ldots . .+a_{n}=a_{n+2}-1 for all n≥1n \geq 1

    4. Option D:

      ∑n=1∞an10n=1089\sum_{\mathrm{n}=1}^{\infty} \frac{\mathrm{a}_{\mathrm{n}}}{10^{\mathrm{n}}}=\frac{10}{89}

  34. Question 34Mathematics· properties of traingles

    In a non-right-angled triangle ΔPQR\Delta \mathrm{PQR}, let p,q,r\mathrm{p}, \mathrm{q}, \mathrm{r} denote the lengths of the sides opposite to the angles at P , Q,R\mathrm{Q}, \mathrm{R} respectively. The median from R meets the side PQ at S , the perpendicular from P meets the side QR at EE, and RS and PE intersect at OO. If p=3,q=1p=\sqrt{3}, q=1, and the radius of the circumcircle of the △PQR\triangle P Q R equals 1 , then which of the following options is/are correct?

    1. Option A:

      length of OE=16\mathrm{OE}=\frac{1}{6}

    2. Option B:

      Radius of incircle of △PQR=32(2−3)\triangle \mathrm{PQR}=\frac{\sqrt{3}}{2}(2-\sqrt{3})

    3. Option C:

      Length of RS=72\mathrm{RS}=\frac{\sqrt{7}}{2}

    4. Option D:

      Are of △SOE=312\triangle \mathrm{SOE}=\frac{\sqrt{3}}{12}

  35. Question 35Mathematics· Differential Equations

    Let Γ\Gamma denote a curve y=y(x)\mathrm{y}=\mathrm{y}(\mathrm{x}) which is in the first quadrant and let the point (1,0)(1,0) lie on it. Let the tangent to Γ\Gamma at a point PP intersect the yy-axis at YPY_{P}. If PYPP Y_{P} has length 1 for each point PP on Γ\Gamma, then which of the following option is/are correct?

    1. Option A:

      y=log⁡e(1+1−x2x)−1−x2\mathrm{y}=\log _{\mathrm{e}}\left(\frac{1+\sqrt{1-\mathrm{x}^{2}}}{\mathrm{x}}\right)-\sqrt{1-\mathrm{x}^{2}}

    2. Option B:

      xy′+1−x2=0x y^{\prime}+\sqrt{1-x^{2}}=0

    3. Option C:

      y=−log⁡e(1+1−x2x)+1−x2y=-\log _{e}\left(\frac{1+\sqrt{1-x^{2}}}{x}\right)+\sqrt{1-x^{2}}

    4. Option D:

      xy′−1−x2=0x y^{\prime}-\sqrt{1-x^{2}}=0

  36. Question 36Mathematics· Matrices

    Let M=[01a1233 b1]\mathrm{M}=\left[\begin{array}{lll}0 & 1 & \mathrm{a}\\ 1 & 2 & 3\\ 3 & \mathrm{~b} & 1\end{array}\right] and adj M=[−11−18−62−53−1]\mathrm{M}=\left[\begin{array}{ccc}-1 & 1 & -1\\ 8 & -6 & 2\\ -5 & 3 & -1\end{array}\right] where aa and bb area real numbers. Which of the following options is/are correct?

    1. Option A:

      (adj⁡M)−1+adj⁡M−1=−M\quad(\operatorname{adj} M)^{-1}+\operatorname{adj} M^{-1}=-M

    2. Option B:

      If M[αβγ]=[123]\mathrm{M}\left[\begin{array}{l}\alpha\\ \beta\\ \gamma\end{array}\right]=\left[\begin{array}{l}1\\ 2\\ 3\end{array}\right], then α−β+γ=3\alpha-\beta+\gamma=3

    3. Option C:

      det⁡(adj⁡M2)=81\quad \operatorname{det}\left(\operatorname{adj} \mathrm{M}^{2}\right)=81

    4. Option D:

      a+b=3a+b=3

  37. Question 37Mathematics· Ellipse

    Define the collections {E1,E2,E3,……}\left\{E_{1}, E_{2}, E_{3}, \ldots \ldots\right\} of ellipses and {R1,R2,R3,…}\left\{R_{1}, R_{2}, R_{3}, \ldots\right\} of rectangles as follows:

    E1:x29+y24=1E_{1}: \frac{x^{2}}{9}+\frac{y^{2}}{4}=1;

    R1R_{1} : rectangle of largest area, with sides parallel to the axes, inscribed in E1E_{1};

    EnE_{n} : ellipse x2an2+y2bn2=1\frac{x^{2}}{a_{n}^{2}}+\frac{y^{2}}{b_{n}^{2}}=1 of largest area inscribed in Rn−1,n>1R_{n-1}, n>1;

    Rn\mathrm{R}_{\mathrm{n}} : rectangle of largest area, with sides parallel to the axes, inscribed in En,n>1\mathrm{E}_{\mathrm{n}}, \mathrm{n}>1.

    Then which of the following options is/are correct?

    1. Option A:

      ∑n=1N(\quad \sum_{n=1}^{N}\left(\right. area of Rn)<24\left.R_{n}\right)<24, for each positive integer NN

    2. Option B:

      The distance of a focus from the centre in E9\mathrm{E}_{9} is 532\frac{\sqrt{5}}{32}

    3. Option C:

      The eccentricities of E18\mathrm{E}_{18} and E19\mathrm{E}_{19} are NOT equal

    4. Option D:

      The length of latus rectum of E9E_{9} is 16\frac{1}{6}

  38. Question 38Mathematics· Application of Derivatives

    Let f:R→Rf: R \rightarrow R by given by f(x)={x5+5x4+10x3+10x2+3x+1,x<0;x2−x+1,0≤x<1;23x3−4x2+7x−83,1≤x<3;(x−2)log⁡e(x−2)−x+103,x≥3.f(x) = \begin{cases} x^5 + 5x^4 + 10x^3 + 10x^2 + 3x + 1, & x < 0; \\ x^2 - x + 1, & 0 \le x < 1; \\ \frac{2}{3}x^3 - 4x^2 + 7x - \frac{8}{3}, & 1 \le x < 3; \\ (x-2)\log_e(x-2) - x + \frac{10}{3}, & x \ge 3. \end{cases}

    Then which of the following options is/are correct?

    1. Option A:

      f′f^{\prime} has a local maximum at x=1\mathrm{x}=1

    2. Option B:

      f′\quad \mathrm{f}^{\prime} is NOT differentiable at x=1\mathrm{x}=1

    3. Option C:

      f is onto

    4. Option D:

      ff is increasing on (−∞,0)(-\infty, 0)

  39. Question 39Mathematics· 3D Geometry

    Let L1L_{1} and L2L_{2} denote the lines r⃗=i^+λ(−i^+2j^+2k^),λ∈R\vec{r}=\hat{i}+\lambda(-\hat{i}+2 \hat{j}+2 \hat{k}), \lambda \in R and r⃗=μ(2i^−j^+2k^),μ∈R\vec{r}=\mu(2 \hat{i}-\hat{j}+2 \hat{k}), \mu \in R

    respectively. If L3L_{3} is a line which is perpendicular to both L1L_{1} and L2L_{2} and cuts both of them, then which of the

    following options describe (s) L3\mathrm{L}_{3} ?

    1. Option A:

      r→=29(4i^+j^+k^)+t(2i^+2j^−k^),t∈R\quad \overrightarrow{\mathrm{r}}=\frac{2}{9}(4 \hat{\mathrm{i}}+\hat{\mathrm{j}}+\hat{\mathrm{k}})+\mathrm{t}(2 \hat{\mathrm{i}}+2 \hat{\mathrm{j}}-\hat{\mathrm{k}}), \mathrm{t} \in \mathrm{R}

    2. Option B:

      r→=13(2i^+k^)+t(2i^+2j^−k^),t∈R\overrightarrow{\mathrm{r}}=\frac{1}{3}(2 \hat{\mathrm{i}}+\hat{\mathrm{k}})+\mathrm{t}(2 \hat{\mathrm{i}}+2 \hat{\mathrm{j}}-\hat{\mathrm{k}}), \mathrm{t} \in \mathrm{R}

    3. Option C:

      r→=29(2i^−j^+2k^)+t(2i^+2j‾−k^),t∈R\overrightarrow{\mathrm{r}}=\frac{2}{9}(2 \hat{\mathrm{i}}-\hat{\mathrm{j}}+2 \hat{\mathrm{k}})+\mathrm{t}(2 \hat{\mathrm{i}}+2 \overline{\mathrm{j}}-\hat{\mathrm{k}}), \mathrm{t} \in \mathrm{R}

    4. Option D:

      r→=t(2i^+2j^−k^),t∈R\overrightarrow{\mathrm{r}}=\mathrm{t}(2 \hat{\mathrm{i}}+2 \hat{\mathrm{j}}-\hat{\mathrm{k}}), \mathrm{t} \in \mathrm{R}

  40. Question 40Mathematics· Probability

    There are three bags B1,B2B_{1}, B_{2} and B3B_{3}. The bag B1B_{1} contains 5 red and 5 green balls, B2B_{2} contains 3 red and 5 green balls and B3B_{3} contains 5 red and 3 green balls. Bags B1,B2B_{1}, B_{2} and B3B_{3} have probabilities 310,310\frac{3}{10}, \frac{3}{10} and 410\frac{4}{10} respectively of being chosen. A bag is selected at random and a ball is chosen at random from the bag. Then which of the following options is/are correct?

    1. Option A:

      Probability that the chosen ball is green equals 3980\frac{39}{80}

    2. Option B:

      Probability that the chosen ball is green, given that the selected bag is B3B_{3}, equals 38\frac{3}{8}

    3. Option C:

      Probability that the selected bag is B3B_{3} and the chosen ball is green equals 310\frac{3}{10}

    4. Option D:

      Probability that the selected bag is B3B_{3}, given that the chosen ball is green, equals 513\frac{5}{13}

  41. Question 41Mathematics· Complex Numbers

    Let ω≠1\omega \neq 1 be a cube root of unity. Then the minimum of the set {∣a+bω+cω2∣2:a,b,c\left\{\left|a+b \omega+c \omega^{2}\right|^{2}: a, b, c\right. distinct non-zero integers }\} equals ____\_\_\_\_

  42. Question 42Mathematics· Definite Integration

    If I=2π∫−π/4π/4dx(1+esin⁡x)(2−cos⁡2x)I=\frac{2}{\pi} \int_{-\pi / 4}^{\pi / 4} \frac{d x}{\left(1+e^{\sin x}\right)(2-\cos 2 x)} then 27I227 I^{2} equals ____\_\_\_\_

  43. Question 43Mathematics· Probability

    Let SS be the sample space of all 3×33 \times 3 matrices with entries from the set {0,1}\{0,1\}. Let the events E1\mathrm{E}_{1} and E2\mathrm{E}_{2} be given by E1={A∈S:det⁡A=0} and E2={A∈S: sum of entries of A is 7}\begin{aligned} & E_{1}=\{A \in S: \operatorname{det} A=0\} \text { and } & E_{2}=\{A \in S: \text { sum of entries of } A \text { is } 7\} \end{aligned} If a matrix is chosen at random from SS, then the conditional probability P(E1/E2)P\left(E_{1} / E_{2}\right) equals ____\_\_\_\_

  44. Question 44Mathematics· Circles

    Let the point BB be the reflection of the point A(2,3)A(2,3) with respect to line 8x−6y−23=08 x-6 y-23=0. Let ΓA\Gamma_{A} and ΓB\Gamma_{B} be circles of radii 2 and 1 with centres A and B respectively. Let TT be a common tangent to the circles ΓA\Gamma_{A} and ΓB\Gamma_{\mathrm{B}} such that both the circles are on the same side of T . If C is the point of intersection of T and the line passing through AA and BB, then the length of the line segment ACA C is ____\_\_\_\_ -

  45. Question 45Mathematics· Sequence and Series

    Let AP(a;d)\mathrm{AP}(\mathrm{a} ; \mathrm{d}) denote the set of all the terms of an infinite arithmetic progression with first term a and common

    difference d>0\mathrm{d}>0. If AP(1;3)∩AP⁡(2;5)∩AP(3;7)=AP(a;d)\mathrm{AP}(1 ; 3) \cap \operatorname{AP}(2 ; 5) \cap \mathrm{AP}(3 ; 7)=\mathrm{AP}(\mathrm{a} ; \mathrm{d}) then a+d\mathrm{a}+\mathrm{d} equals ____\_\_\_\_

  46. Question 46Mathematics· 3D Geometry

    Three lines are given by r⃗=λi^,λ∈R,r⃗=μ(i^+j^),μ∈R\vec{r}=\lambda \hat{i}, \lambda \in R, \vec{r}=\mu(\hat{i}+\hat{j}), \mu \in R and r⃗=v(i^+j^+k^),v∈R\vec{r}=v(\hat{i}+\hat{j}+\hat{k}), v \in R. Let the

    lines cut the plane x+y+z=1x+y+z=1 at the points A,BA, B and CC respectively. If the area of the triangle ABCA B C is

    Δ\Delta then the value of (6Δ)2(6 \Delta)^{2} equals

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