Chemistry · Redox Reactions

JEE Main 2024 — 1 February, Shift 1 — Question 60

Which of the following reactions are disproportionation reactions?

(A) Cu+→Cu2++Cu\mathrm{Cu}^{+} \rightarrow \mathrm{Cu}^{2+}+\mathrm{Cu}

(B) 3MnO42−+4H+→2MnO4−+MnO2+2H2O3 \mathrm{MnO}_{4}^{2-}+4 \mathrm{H}^{+} \rightarrow 2 \mathrm{MnO}_{4}^{-}+\mathrm{MnO}_{2}+2 \mathrm{H}_{2} \mathrm{O}

(C) 2KMnO4→ K2MnO4+MnO2+O22 \mathrm{KMnO}_{4} \rightarrow \mathrm{~K}_{2} \mathrm{MnO}_{4}+\mathrm{MnO}_{2}+\mathrm{O}_{2}

(D) 2MnO4−+3Mn2++2H2O→5MnO2+4H+2 \mathrm{MnO}_{4}^{-}+3 \mathrm{Mn}^{2+}+2 \mathrm{H}_{2} \mathrm{O} \rightarrow 5 \mathrm{MnO}_{2}+4 \mathrm{H}^{+}

Choose the correct answer from the options given below:

  1. Option A:

    (A), (B)

    Correct
  2. Option B:

    (B), (C), (D)

  3. Option C:

    (A), (B), ©

  4. Option D:

    (A), (D)

Answer: A

Step-by-step solution

When a particular oxidation state becomes less stable relative to other oxidation state, one lower, one higher, it is said to

undergo disproportionation.

Cu+→Cu2++Cu\mathrm{Cu}^{+} \rightarrow \mathrm{Cu}^{2+}+\mathrm{Cu}

3MnO42−+4H+→2MnO4−+MnO2+2H2O3 \mathrm{MnO}_{4}^{2-}+4 \mathrm{H}^{+} \rightarrow 2 \mathrm{MnO}_{4}^{-}+\mathrm{MnO}_{2}+2 \mathrm{H}_{2} \mathrm{O}

Answer key and solution verified before publishing.

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Exam
JEE Main 2024
Subject
Chemistry
Chapter
Redox Reactions
Topic
Types of Redox Reactions & Balancing of Redox Reactions
Which of the following reactions are disproportionation reactions?… | JEE Main 2024 PYQ with Solution · DhiX AI