Chemistry · Structure of Atom

JEE Main 2026 — 23 January, Evening Shift — Question 60

The work functions of two metals (MA\mathrm{M}_{\mathrm{A}} and MB\mathrm{M}_{\mathrm{B}}) are in the 1:21: 2 ratio. When these metals are exposed to photons of energy 6 eV , the kinetic energy of liberated electrons of MA:MBM_{A}: M_{B} is in the ratio of 2.642 : 1. The work functions (in eV ) of MA\mathrm{M}_{\mathrm{A}} and MB\mathrm{M}_{\mathrm{B}} are respectively.

  1. Option A:

    3.1,6.23.1,6.2

  2. Option B:

    2.3,4.62.3,4.6

    Correct
  3. Option C:

    1.4,2.81.4,2.8

  4. Option D:

    1.5,3.01.5,3.0

Answer: B

Step-by-step solution

Einstein equation, KEmax⁡=E−ϕ\mathrm{KE}_{\max} = E - \phi

For metal A: (KEmax⁡)1=6−ϕ1\left(\mathrm{KE}_{\max}\right)_1 = 6 - \phi_1 …..(1)

For metal B: (KEmax⁡)2=6−ϕ2\left(\mathrm{KE}_{\max}\right)_2 = 6 - \phi_2 …..(2)

Given: ϕ2=2ϕ1\phi_2 = 2\phi_1

Dividing (1) by (2), we have

(KEmax⁡)1(KEmax⁡)2=6−ϕ16−ϕ2=2.6421\frac{\left(\mathrm{KE}_{\max}\right)_1} {\left(\mathrm{KE}_{\max}\right)_2} = \frac{6-\phi_1}{6-\phi_2} = \frac{2.642}{1}

Substitute ϕ2=2ϕ1\phi_2 = 2\phi_1, we have

2.6421=6−ϕ16−2ϕ1\frac{2.642}{1} = \frac{6-\phi_1}{6-2\phi_1}

Cross multiplying, we have

2.642(6−2ϕ1)=6−ϕ12.642(6-2\phi_1)=6-\phi_1 15.852−5.284ϕ1=6−ϕ115.852-5.284\phi_1=6-\phi_1 4.284ϕ1=9.8524.284\phi_1=9.852 ϕ1=2.3 eV\phi_1=2.3\,\mathrm{eV} ϕ2=4.6 eV\phi_2=4.6\,\mathrm{eV}

Answer key and solution verified before publishing.

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Exam
JEE Main 2026
Subject
Chemistry
Chapter
Structure of Atom
Topic
Photoelectric Effect and Planck's Quantum Theory
The work functions of two metals ( M A and M B ) are in the 1: 2… | JEE Main 2026 PYQ with Solution · DhiX AI