Physics · Kinetic Theory of Gases

JEE Main 2026 — 22 January, Evening Shift — Question 28

Consider two boxes containing ideal gases A and B such that their temperatures, pressures and number densities are same. The molecular size of A is half of that of B and mass of molecule A is four times that of B . If the collision frequency in gas B is 32×1018 s32 \times 10 \frac{18}{\mathrm{~s}} then collision frequency in gas A is ____\_\_\_\_ /s.

  1. Option A:

    32×10832 \times 10^{8}

  2. Option B:

    4×1084 \times 10^{8}

    Correct
  3. Option C:

    2×1082 \times 10^{8}

  4. Option D:

    8×1088 \times 10^{8}

Answer: B

Step-by-step solution

Collision frequency (z)=2πd2N8RTπM(z)=\sqrt{2} \pi d^{2} N \sqrt{\frac{8 R T}{\pi M}} Temp, N are same Z∝d2M\mathrm{Z} \propto \frac{\mathrm{d}^{2}}{\sqrt{\mathrm{M}}} dA=dB2\mathrm{d}_{\mathrm{A}}=\frac{\mathrm{d}_{\mathrm{B}}}{2} MA=4MB\mathrm{M}_{\mathrm{A}}=4 \mathrm{M}_{\mathrm{B}} ZAZB=dA2MA×MBdB2=(MBMA)(dAdB)2\frac{\mathrm{Z}_{\mathrm{A}}}{\mathrm{Z}_{\mathrm{B}}}=\frac{\mathrm{d}_{\mathrm{A}}^{2}}{\sqrt{\mathrm{M}_{\mathrm{A}}}} \times \frac{\sqrt{\mathrm{M}_{\mathrm{B}}}}{\mathrm{d}_{\mathrm{B}}^{2}}=\left(\sqrt{\frac{\mathrm{M}_{\mathrm{B}}}{\mathrm{M}_{\mathrm{A}}}}\right)\left(\frac{\mathrm{d}_{\mathrm{A}}}{\mathrm{d}_{\mathrm{B}}}\right)^{2} =(14)(12)2=\left(\sqrt{\frac{1}{4}}\right)\left(\frac{1}{2}\right)^{2} ZAZB=12×14=18\frac{\mathrm{Z}_{\mathrm{A}}}{\mathrm{Z}_{\mathrm{B}}}=\frac{1}{2} \times \frac{1}{4}=\frac{1}{8} ⇒ZA=32×1088=4×108/s\Rightarrow \mathrm{Z}_{\mathrm{A}}=\frac{32 \times 10^{8}}{8}=4 \times 10^{8} / \mathrm{s}

Answer key and solution verified before publishing.

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Exam
JEE Main 2026
Subject
Physics
Chapter
Kinetic Theory of Gases
Topic
Energy of Gas and Gas Laws and Miscellaneous Problems