Start free

Chemistry · Coordination Compounds

JEE Advanced 2018 — Paper 2 — Question 26

Match each set of hybrid orbitals from LIST-I with complex(es) given in LIST-II. The correct option is

LIST-ILIST-II
P. dsp2\mathrm{dsp}^{2}1. [FeF6]4−\left[\mathrm{FeF}_{6}\right]^{4-}
Q. sp3\mathrm{sp}^{3}2. [Ti(H2O)3Cl3]\left[\mathrm{Ti}\left(\mathrm{H}_{2} \mathrm{O}\right)_{3} \mathrm{Cl}_{3}\right]
R. sp3 d2\mathrm{sp}^{3} \mathrm{~d}^{2}3. [Cr(NH3)6]3+\left[\mathrm{Cr}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}
S. d2sp3\mathrm{d}^{2} \mathrm{sp}^{3}4. [FeCl[\mathrm{FeCl} ]2−]^{2-}
5. Ni(CO)4\mathrm{Ni}(\mathrm{CO})_{4}
6. [Ni(CN)4]2−\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]^{2-}
  1. Option A:

    P→5;Q→4,6;R→2,3;S→1\mathbf{P} \rightarrow 5 ; \mathbf{Q} \rightarrow 4,6 ; \mathbf{R} \rightarrow 2,3 ; \mathbf{S} \rightarrow 1

  2. Option B:

    P→5,6;Q→4;R→3;S→1,2\mathbf{P} \rightarrow 5,6 ; \mathbf{Q} \rightarrow 4 ; \mathbf{R} \rightarrow 3 ; \mathbf{S} \rightarrow 1,2

  3. Option C:

    P→6;Q→4,5;R→1;S→2,3\mathbf{P} \rightarrow 6 ; \mathbf{Q} \rightarrow 4,5 ; \mathbf{R} \rightarrow 1 ; \mathbf{S} \rightarrow 2,3

    Correct
  4. Option D:

    P→4,6;Q→5,6;R→1,2;S→3\mathbf{P} \rightarrow 4,6 ; \mathbf{Q} \rightarrow 5,6 ; \mathbf{R} \rightarrow 1,2 ; \mathbf{S} \rightarrow 3

Answer: C

Step-by-step solution

dsp2:[Ni(CN)4]2−\mathrm{dsp}^{2}:\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]^{2-}

sp3:[FeCl4]2−;[Ni(CO)4]\mathrm{sp}^{3}:\left[\mathrm{FeCl}_{4}\right]^{2-} ;\left[\mathrm{Ni}(\mathrm{CO})_{4}\right]

sp3 d2:[FeF6]4−\mathrm{sp}^{3} \mathrm{~d}^{2}:\left[\mathrm{FeF}_{6}\right]^{4-}

d2sp3:[Ti(H2O)3Cl3],[Cr(NH3)6]3+d^{2} \mathrm{sp}^{3}:\left[\mathrm{Ti}\left(\mathrm{H}_{2} \mathrm{O}\right)_{3} \mathrm{Cl}_{3}\right],\left[\mathrm{Cr}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}

Answer key and solution verified before publishing.

Practise Coordination Compounds

Start with this question, then two more from the same chapter — with a tutor that explains every step. Free.

Solve a similar one free
Exam
JEE Advanced 2018
Paper
Paper 2
Subject
Chemistry
Chapter
Coordination Compounds
Topic
Theories of Bonding in Coordination Compounds

More Coordination Compounds questions from this paper

Match each set of hybrid orbitals from LIST-I with complex(es) given… | JEE Advanced 2018 PYQ with Solution · DhiX AI