Chemistry · d and f Block Elements

NEET (UG) 2023 — Question 72

Which of the following statements are INCORRECT?

A. All the transition metals except scandium form MOMO oxides which are ionic.

B. The highest oxidation number corresponding to the group number in transition metal oxides is attained in Sc2O3\mathrm{Sc}_{2} \mathrm{O}_{3} to Mn2O7\mathrm{Mn}_{2} \mathrm{O}_{7}.

C. Basic character increases from V2O3\mathrm{V}_{2} \mathrm{O}_{3} to V2O4\mathrm{V}_{2} \mathrm{O}_{4} to V2O5\mathrm{V}_{2} \mathrm{O}_{5}.

D. V2O4\mathrm{V}_{2} \mathrm{O}_{4} dissolves in acids to give VO43−\mathrm{VO}_{4}^{3-} salts.

E. CrO\mathrm{CrO} is basic but Cr2O3\mathrm{Cr}_{2} \mathrm{O}_{3} is amphoteric.

In the light of the above statements, choose the most appropriate answer from the options given below:

  1. Option A:

    B and D only

  2. Option B:

    C and D only

    Correct
  3. Option C:

    B and C only

  4. Option D:

    A and E only

Answer: B

Step-by-step solution

A is Correct: Most transition metals (except Sc) form MOMO-type ionic oxides in lower oxidation states.

B is Correct: The highest oxidation state equal to the group number is attained from Sc2O3\mathrm{Sc_2O_3} (+3)(+3) to Mn2O7\mathrm{Mn_2O_7} (+7)(+7).

C is Incorrect: In vanadium oxides, basic character decreases and acidic character increases in the order V2O3→V2O4→V2O5\mathrm{V_2O_3 \rightarrow V_2O_4 \rightarrow V_2O_5}.

D is Incorrect: V2O4\mathrm{V_2O_4} dissolves in acids to form VO2+\mathrm{VO^{2+}} (vanadyl) salts, not VO43−\mathrm{VO_4^{3-}} salts.

E is Correct: CrO\mathrm{CrO} is basic, whereas Cr2O3\mathrm{Cr_2O_3} is amphoteric.

Thus, the incorrect statements are C and D only.

Answer key and solution verified before publishing.

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Exam
NEET (UG) 2023
Subject
Chemistry
Chapter
d and f Block Elements
Topic
Properties of general compounds of transition elements
Which of the following statements are INCORRECT? A. All the… | NEET (UG) 2023 PYQ with Solution · DhiX AI