Chemistry · Solutions and Colligative Properties

NEET (UG) 2025 — Question 73

Which of the following aqueous solution will exhibit highest boiling point?

  1. Option A:

    0.01 M Urea

  2. Option B:

    0.01MKNO30.01 \mathrm{M} \mathrm{KNO}_{3}

  3. Option C:

    0.01MNa2SO40.01 \mathrm{M} \mathrm{Na}_{2} \mathrm{SO}_{4}

    Correct
  4. Option D:

    0.015MC6H12O60.015 \mathrm{M} \mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}

Answer: C

Step-by-step solution

ΔTb=iKKbm\Delta \mathrm{T}_{\mathrm{b}}=\mathrm{iK} \mathrm{K}_{\mathrm{b}} \mathrm{m}

Consider m≈M\mathrm{m} \approx \mathrm{M}

Kb\mathrm{K}_{\mathrm{b}} same for all i×M\mathrm{i} \times \mathrm{M}

(1) 1×0.01=0.011 \times 0.01=0.01

(2) 2×0.01=0.022 \times 0.01=0.02

(3) 3×0.01=0.033 \times 0.01=0.03

(4) 1×0.015=0.0151 \times 0.015=0.015

iM↑⇒ΔTb↑⇒Tb↑\mathrm{iM} \uparrow \Rightarrow \Delta \mathrm{T}_{\mathrm{b}} \uparrow \Rightarrow \mathrm{T}_{\mathrm{b}} \uparrow

Answer key and solution verified before publishing.

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Exam
NEET (UG) 2025
Subject
Chemistry
Chapter
Solutions and Colligative Properties
Topic
Abnormal Colligative Properties - van't Hoff Factor
Which of the following aqueous solution will exhibit highest boiling… | NEET (UG) 2025 PYQ with Solution · DhiX AI