Chemistry · Thermodynamics & Thermochemistry

NEET (UG) 2024 — Question 81

In which of the following processes entropy increases?

A. A liquid evaporates to vapour.

B. Temperature of a crystalline solid lowered from 130 K to 0 K .

C. 2NaHCO3( s)→Na2CO3( s)+CO2( g)+H2O(g)2 \mathrm{NaHCO}_{3(\mathrm{~s})} \rightarrow \mathrm{Na}_{2} \mathrm{CO}_{3(\mathrm{~s})}+\mathrm{CO}_{2(\mathrm{~g})}+\mathrm{H}_{2} \mathrm{O}_{(\mathrm{g})}

D. Cl2( g)→2Cl(g)\mathrm{Cl}_{2(\mathrm{~g})} \rightarrow 2 \mathrm{Cl}_{(\mathrm{g})}

Choose the correct answer from the options given below:

  1. Option A:

    A and C

  2. Option B:

    A, B and D

  3. Option C:

    A, C and D

    Correct
  4. Option D:

    C and D

Answer: C

Step-by-step solution

When a liquid evaporates to vapour entropy increases.

2NaHCO3( s)→Na2CO3( s)+CO2( g)+H2O(g)2 \mathrm{NaHCO}_{3(\mathrm{~s})} \rightarrow \mathrm{Na}_{2} \mathrm{CO}_{3(\mathrm{~s})}+\mathrm{CO}_{2(\mathrm{~g})}+\mathrm{H}_{2} \mathrm{O}_{(\mathrm{g})}

Number of gaseous product molecules increases so entropy increases.

Cl2( g)→2Cl(g)\mathrm{Cl}_{2(\mathrm{~g})} \rightarrow 2 \mathrm{Cl}_{(\mathrm{g})}

1 mole Cl2( g)\mathrm{Cl}_{2(\mathrm{~g})} form 2 molCl(g)2 \mathrm{~mol} \mathrm{Cl}_{(\mathrm{g})}. So entropy increases.

Answer key and solution verified before publishing.

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Exam
NEET (UG) 2024
Subject
Chemistry
Chapter
Thermodynamics & Thermochemistry
Topic
Entropy Change in Different Processes
In which of the following processes entropy increases? A. A liquid… | NEET (UG) 2024 PYQ with Solution · DhiX AI