Chemistry · p-Block (I) (Grp. 13, 14)

JEE Main 2024 — 5 April, Shift 2 — Question 77

The correct statements from the following are :

(A) The decreasing order of atomic radii of group 13 elements is Tl>In>Ga>Al>B\mathrm{Tl}>\mathrm{In}>\mathrm{Ga}>\mathrm{Al}>\mathrm{B}.

(B) Down the group 13 electronegativity decreases from top to bottom.

(C) Al dissolves in dil. HCl and liberate H2\mathrm{H}_{2} but conc. HNO3\mathrm{HNO}_{3} renders Al passive by forming a protective oxide layer on the

surface.

(D) All elements of group 13 exhibits highly stable +1 oxidation state.

(E) Hybridisation of Al in [Al(H2O)6]3+\left[\mathrm{Al}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{3+} ion is sp3 d2\mathrm{sp}^{3} \mathrm{~d}^{2}

Choose the correct answer from the options given below :

  1. Option A:

    (C) and (E) only

    Correct
  2. Option B:

    (A), (C) and (E) only

  3. Option C:

    (A), (B), (C) and (E) only

  4. Option D:

    (A) and (C) only

Answer: A

Step-by-step solution

A. size order Tℓ>In>Al>Ga>B\mathrm{T} \ell>\mathrm{In}>\mathrm{Al}>\mathrm{Ga}>\mathrm{B}

B. Electronegativity order B>Al<Ga<In<Tℓ\mathrm{B}>\mathrm{Al}<\mathrm{Ga}<\mathrm{In}<\mathrm{T} \ell

D. B,Al\mathrm{B}, \mathrm{Al} are more stable in +3 oxidation state So, only C, E statements are correct.

Answer key and solution verified before publishing.

Practise p-Block (I) (Grp. 13, 14)

Start with this question, then two more from the same chapter — with a tutor that explains every step. Free.

Exam
JEE Main 2024
Subject
Chemistry
Chapter
p-Block (I) (Grp. 13, 14)
Topic
Introduction & Properties of Group 13: Boron Family
The correct statements from the following are : (A) The decreasing… | JEE Main 2024 PYQ with Solution · DhiX AI