Chemistry · d and f Block Elements

JEE Main 2025 — 22 January, Morning Shift — Question 30

Lanthanoid ions with 4f74 f^{7} configuration are :

(A) Eu2+\mathrm{Eu}^{2+} (B) Gd3+\mathrm{Gd}^{3+} (C) Eu3+\mathrm{Eu}^{3+}

(D) Tb3+\mathrm{Tb}^{3+} (E) Sm2+\mathrm{Sm}^{2+}

Choose the correct answer from the options given below:

  1. Option A:

    (A) and (B) only

    Correct
  2. Option B:

    (A) and (D) only

  3. Option C:

    (B) and (E) only

  4. Option D:

    (B) and (E) only

Answer: A

Step-by-step solution

63Eu2+−[Xe]4f76 s0{ }_{63} \mathrm{Eu}^{2+}-[\mathrm{Xe}] 4 \mathrm{f}^{7} 6 \mathrm{~s}^{0}

64Gd3+−[Xe]4f75 d06 s0{ }_{64} \mathrm{Gd}^{3+}-[\mathrm{Xe}] 4 \mathrm{f}^{7} 5 \mathrm{~d}^{0} 6 \mathrm{~s}^{0}

63Eu3+−[Xe]4f66 s0{ }_{63} \mathrm{Eu}^{3+}-[\mathrm{Xe}] 4 \mathrm{f}^{6} 6 \mathrm{~s}^{0}

65 Tb3+−[Xe]4f86 s0{ }_{65} \mathrm{~Tb}^{3+}-[\mathrm{Xe}] 4 \mathrm{f}^{8} 6 \mathrm{~s}^{0}

62Sm2+−[Xe]4f66 s0{ }_{62} \mathrm{Sm}^{2+}-[\mathrm{Xe}] 4 \mathrm{f}^{6} 6 \mathrm{~s}^{0}

Eu2+&Gd3+\mathrm{Eu}^{2+} \& \mathrm{Gd}^{3+}

Answer key and solution verified before publishing.

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Exam
JEE Main 2025
Subject
Chemistry
Chapter
d and f Block Elements
Topic
Inner transition elements (f-Block elements)