Chemistry · d and f Block Elements

JEE Main 2026 — 22 January, Evening Shift — Question 49

Given below are two statements : one is labelled as Statement I and the other is labelled as Statement II :

Statement-I : The first ionization enthalpy of Cr is lower than that of Mn.

Statement-II : The second and third ionization enthalpies of Cr are higher than those of Mn .

In the light of the above statements, choose the correct answer from the options given below :

  1. Option A:

    Both Statement-I and Statement-II are false.

  2. Option B:

    Statement-I is true but Statement-II is false.

    Correct
  3. Option C:

    Both Statement-I and Statement-II are true.

  4. Option D:

    Statement-I is false but Statement-II is true.

Answer: B

Step-by-step solution

Cr=(Ar)3 d54 s1\mathrm{Cr}=(\mathrm{Ar}) 3 \mathrm{~d}^{5} 4 \mathrm{~s}^{1} Mn=(Ar)3 d54 s2\mathrm{Mn}=(\mathrm{Ar}) 3 \mathrm{~d}^{5} 4 \mathrm{~s}^{2} IE1(Cr)<IE1(Mn)\mathrm{IE}_{1}(\mathrm{Cr})<\mathrm{IE}_{1}(\mathrm{Mn}) IE2(Cr)>IE2(Mn)\mathrm{IE}_{2}(\mathrm{Cr})>\mathrm{IE}_{2}(\mathrm{Mn}) IE3(Cr)<IE3(Mn)\mathrm{IE}_{3}(\mathrm{Cr})<\mathrm{IE}_{3}(\mathrm{Mn})

Answer key and solution verified before publishing.

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Exam
JEE Main 2026
Subject
Chemistry
Chapter
d and f Block Elements
Topic
Introduction and Properties of Transition Elements
Given below are two statements : one is labelled as Statement I and… | JEE Main 2026 PYQ with Solution · DhiX AI