Chemistry · p-Block (I) (Grp. 13, 14)

JEE Main 2024 — 5 April, Shift 1 — Question 64

Given below are two statements, one is labelled as Statement I and the other is labelled as Statement II.

Statement I : In group 13, the stability of +1 oxidation state increases down the group.

Statement II : The atomic size of gallium is greater than that of aluminium.

In the light of the above statements, choose the most appropriate answer from the options given below:

  1. Option A:

    Statement I is incorrect but Statement II is correct

  2. Option B:

    Both Statement I and Statement II are correct

  3. Option C:

    Both Statement I and Statement II are incorrect

  4. Option D:

    Statement I is correct but Statement II is incorrect

    Correct

Answer: D

Step-by-step solution

Statement I is Correct: In Group 13, the stability of the +1+1 oxidation state increases down the group due to the inert pair effect.

Statement II is Incorrect: Because of poor shielding by dd-electrons, gallium has a smaller atomic size than aluminium, not larger.

Thus, Statement I is correct but Statement II is incorrect (Option D).

Answer key and solution verified before publishing.

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Exam
JEE Main 2024
Subject
Chemistry
Chapter
p-Block (I) (Grp. 13, 14)
Topic
Introduction & Properties of Group 13: Boron Family
Given below are two statements, one is labelled as Statement I and… | JEE Main 2024 PYQ with Solution · DhiX AI