Chemistry · Alkyl and Aryl Halides

JEE Main 2024 — 1 February, Shift 1 — Question 58

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A) : Haloalkanes react with KCN to form alkyl cyanides as a main product while with AgCN form isocyanide as the main product.

Reason (R) : KCN and AgCN both are highly ionic compounds.

In the light of the above statement, choose the most appropriate answer from the options given below:

  1. Option A:

    (A) is correct but (R) is not correct

    Correct
  2. Option B:

    Both (A) and (R) are correct but (R) is not the correct explanation of (A)

  3. Option C:

    (A) is not correct but (R) is correct

  4. Option D:

    Both (A) and (R) are correct and (R) is the correct explanation of (A)

Answer: A

Step-by-step solution

AgCN is mainly covalent in nature and nitrogen is available for attack, so alkyl isocyanide is formed as main product.

Solution figure

Answer key and solution verified before publishing.

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Exam
JEE Main 2024
Subject
Chemistry
Chapter
Alkyl and Aryl Halides
Topic
Introduction to Alkyl Halides and Methods of Preparation
Given below are two statements : one is labelled as Assertion (A) and… | JEE Main 2024 PYQ with Solution · DhiX AI