Chemistry · Hydrocarbons

JEE Main 2024 — 30 January, Shift 1 — Question 66

Compound A formed in the following reaction reacts with B gives the product C. Find out A and B.

CH3−C≡CH+Na→A→BCH3−C≡C−CH2−CH2−CH(CH3)−CH2+NaBr\text{CH}_3 - \text{C}\equiv\text{CH} + \text{Na} \rightarrow \text{A} \xrightarrow{\text{B}} \text{CH}_3 - \text{C}\equiv\text{C} - \text{CH}_2 - \text{CH}_2 - \text{CH}(\text{CH}_3) - \text{CH}_2 + \text{NaBr}
  1. Option A:

    A=CH3−C≡C‾Na,B=CH3−CH2−CH2−Br\mathrm{A}=\mathrm{CH}_{3}-\mathrm{C} \equiv \overline{\mathrm{C}} \mathrm{Na}, \mathrm{B}=\mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{CH}_{2}-\mathrm{Br}

    Correct
  2. Option B:

    A=CH3−CH=CH2, B=CH3−CH2−CH2−Br\mathrm{A}=\mathrm{CH}_{3}-\mathrm{CH}=\mathrm{CH}_{2}, \mathrm{~B}=\mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{CH}_{2}-\mathrm{Br}

  3. Option C:

    A=CH3−CH2−CH3, B=CH3−C≡CH\mathrm{A}=\mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{CH}_{3}, \mathrm{~B}=\mathrm{CH}_{3}-\mathrm{C} \equiv \mathrm{CH}

  4. Option D:

    A=CH3−C≡CˉNa+ ,B=CH3−CH2−CH3A=C{{H}_{3}}-C\equiv \bar{C}N\overset{+}{\mathop{a}}\,,B=C{{H}_{3}}-C{{H}_{2}}-C{{H}_{3}}

Answer: A

Step-by-step solution

CH3−C≡CH→NaCH3−C≡C−Na+→CH3CH2CH2−BrNaBr+CH3−C≡C−CH2CH2CH3\text{CH}_3 - \text{C}\equiv\text{CH} \xrightarrow{\text{Na}} \text{CH}_3 - \text{C}\equiv\text{C}^-\text{Na}^+ \xrightarrow{\text{CH}_3\text{CH}_2\text{CH}_2 - \text{Br}} \text{NaBr} + \text{CH}_3 - \text{C}\equiv\text{C} - \text{CH}_2\text{CH}_2\text{CH}_3

Answer key and solution verified before publishing.

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Exam
JEE Main 2024
Subject
Chemistry
Chapter
Hydrocarbons
Topic
Properties & Uses of Alkynes
Compound A formed in the following reaction reacts with B gives the… | JEE Main 2024 PYQ with Solution · DhiX AI