Chemistry · p-Block Elements (Group 15-18)

JEE Main 2026 — 8 April, Evening Shift — Question 45

Bromine trifluoride autoionizes to form BrF2+BrF_2^+ and BrF4−BrF_4^-. The shapes of the cation and anion are respectively

------and --------

  1. Option A:

    bent, square planar

    Correct
  2. Option B:

    linear, square planar

  3. Option C:

    bent, see-saw

  4. Option D:

    linear, tetrahedral

Answer: A

Step-by-step solution

BrFX2X+⇒sp3\ce{BrF2^+} \Rightarrow sp^3

[Bond pair=2, lone pair=2][\text{Bond pair} = 2,\ \text{lone pair} = 2]

⇒bent\Rightarrow \text{bent}

BrFX4X−⇒sp3d2\ce{BrF4^-} \Rightarrow sp^3 d^2

[Bond pair=4, lone pair=2][\text{Bond pair} = 4,\ \text{lone pair} = 2]

⇒square planar\Rightarrow \text{square planar}

Answer key and solution verified before publishing.

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Exam
JEE Main 2026
Subject
Chemistry
Chapter
p-Block Elements (Group 15-18)
Topic
Compounds of Halogens
Bromine trifluoride autoionizes to form BrF 2 + and BrF 4 - . The… | JEE Main 2026 PYQ with Solution · DhiX AI