Chemistry · Thermodynamics & Thermochemistry

JEE Advanced 2023 — Paper 1 — Question 41

One mole of an ideal monoatomic gas undergoes two reversible processes ( A→BA \rightarrow B and B→CB \rightarrow C ) as shown in the given figure: A→BA \rightarrow B is an adiabatic process. If the total heat absorbed in the entire process ( A→BA \rightarrow B and B→CB \rightarrow C ) is RT2ln⁡10\mathrm{RT}_{2} \ln 10, the value of 2log⁡ V32 \log \mathrm{~V}_{3} is _____\_\_\_\_\_ —. [Use, molar heat capacity of the gas at constant pressure, Cp,m=52R\mathrm{C}_{\mathrm{p}, \mathrm{m}}=\frac{5}{2} \mathrm{R} ]

Question figure

Answer: 7

Numerical answer — enter this value.

Step-by-step solution

A→B\mathrm{A} \rightarrow \mathrm{B} (reversible adiabatic), γ=53\gamma=\frac{5}{3} qtotal =EAB+qBC=0+qBC=qBC\mathrm{q}_{\text {total }}=\mathrm{E}_{\mathrm{AB}}+\mathrm{q}_{\mathrm{BC}}=0+\mathrm{q}_{\mathrm{BC}}=\mathrm{q}_{\mathrm{BC}} qBC=RT2ℓn10\mathrm{q}_{\mathrm{BC}}=\mathrm{RT}_{2} \ell \mathrm{n} 10 For the process A to B T1×V1γ−1=T2×V2γ−1\mathrm{T}_{1} \times \mathrm{V}_{1}^{\gamma-1}=\mathrm{T}_{2} \times \mathrm{V}_{2}^{\gamma-1} (V2 V1)γ−1=T1 T2=60060=10\left(\frac{\mathrm{V}_{2}}{\mathrm{~V}_{1}}\right)^{\gamma-1}=\frac{\mathrm{T}_{1}}{\mathrm{~T}_{2}}=\frac{600}{60}=10 (V2 V1)53−1=10\left(\frac{\mathrm{V}_{2}}{\mathrm{~V}_{1}}\right)^{\frac{5}{3}-1}=10 V2 V1=(10)32\frac{\mathrm{V}_{2}}{\mathrm{~V}_{1}}=(10)^{\frac{3}{2}} V2=10×(10)32=(10)52\mathrm{V}_{2}=10 \times(10)^{\frac{3}{2}}=(10)^{\frac{5}{2}} V2=(10)52\mathrm{V}_{2}=(10)^{\frac{5}{2}} −RT2ln⁡10=−RT2ln⁡ V3 V2-\mathrm{RT}_{2} \ln 10=-\mathrm{RT}_{2} \ln \frac{\mathrm{~V}_{3}}{\mathrm{~V}_{2}} 10=V3 V210=\frac{\mathrm{V}_{3}}{\mathrm{~V}_{2}} V3=10 V2=10×(10)52=(10)72\mathrm{V}_{3}=10 \mathrm{~V}_{2}=10 \times(10)^{\frac{5}{2}}=(10)^{\frac{7}{2}} 2ln⁡ V3=2×ln⁡10722 \ln \mathrm{~V}_{3}=2 \times \ln 10^{\frac{7}{2}} 2log⁡ V3=2×72×1=72 \log \mathrm{~V}_{3}=2 \times \frac{7}{2} \times 1=7

Answer key and solution verified before publishing.

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Exam
JEE Advanced 2023
Paper
Paper 1
Subject
Chemistry
Chapter
Thermodynamics & Thermochemistry
Topic
Internal Energy and the First Law
One mole of an ideal monoatomic gas undergoes two reversible… | JEE Advanced 2023 PYQ with Solution · DhiX AI