Chemistry · Solutions and Colligative Properties

JEE Advanced 2018 — Paper 1 — Question 24

Liquids A\mathbf{A} and B\mathbf{B} form ideal solution over the entire range of composition. At temperature T\mathbf{T}, equimolar binary solution of liquids A\mathbf{A} and B\mathbf{B} has vapour pressure 45 Torr. At the same temperature, a new solution of A\mathbf{A} and B\mathbf{B} having mole fractions xAx_{\mathrm{A}} and xBx_{\mathrm{B}}, respectively, has vapour pressure of 22.5 Torr. The value of xA/xBx_{\mathrm{A}} / x_{\mathrm{B}} in the new solution is ____\_\_\_\_ -. (given that the vapour pressure of pure liquid A\mathbf{A} is 20 Torr at temperature T )

Answer: 19

Numerical answer — enter this value.

Step-by-step solution

xA=12,xB=12\mathrm{x}_{\mathrm{A}}=\frac{1}{2}, \mathrm{x}_{\mathrm{B}}=\frac{1}{2}

PT=PA012+PB0×12\mathrm{P}_{\mathrm{T}}=\mathrm{P}_{\mathrm{A}}^{0} \frac{1}{2}+\mathrm{P}_{\mathrm{B}}^{0} \times \frac{1}{2}

(Given PA0=20\mathrm{P}_{\mathrm{A}}^{0}=20 )

90=45×2=PA0+PB0…(1)90=45 \times 2=P_{A}^{0}+P_{B}^{0} …(1)

PB0=90−20=70\mathrm{P}_{\mathrm{B}}^{0}=90-20=70

22.5=PA0xA+PB0(1−xA)22.5=\mathrm{P}_{\mathrm{A}}^{0} \mathrm{x}_{\mathrm{A}}+\mathrm{P}_{\mathrm{B}}^{0}\left(1-\mathrm{x}_{\mathrm{A}}\right)

=20xA+70(1−xA)=20 \mathrm{x}_{\mathrm{A}}+70\left(1-\mathrm{x}_{\mathrm{A}}\right)

22.5=20xA+70−70xA=70−50xA22.5=20 \mathrm{x}_{\mathrm{A}}+70-70 \mathrm{x}_{\mathrm{A}}=70-50 \mathrm{x}_{\mathrm{A}}

xA=47.550=1920\mathrm{x}_{\mathrm{A}}=\frac{47.5}{50}=\frac{19}{20} XB=120\mathrm{X}_{\mathrm{B}}=\frac{1}{20}

xAxB=1920120=19\frac{\mathrm{x}_{\mathrm{A}}}{\mathrm{x}_{\mathrm{B}}}=\frac{\frac{19}{20}}{\frac{1}{20}}=19

Answer key and solution verified before publishing.

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Exam
JEE Advanced 2018
Paper
Paper 1
Subject
Chemistry
Chapter
Solutions and Colligative Properties
Topic
Liquid in Liquid Solutions (Raoult's Law)