Chemistry · Aldehydes and Ketones

JEE Advanced 2024 — Paper 1 — Question 40

Complete reaction of acetaldehyde with excess formaldehyde, upon heating with conc. NaOH solution, gives P\mathbf{P} and Q\mathbf{Q}. Compound P\mathbf{P} does not give Tollen's test, whereas Q\mathbf{Q} on acidification gives positive Tollen's test. Treatment of P\mathbf{P} with excess cyclohexanone in the presence of catalytic amount of p-tolunesulfonic acid (PTSA) gives product R\mathbf{R}. Sum of the number of methylene groups (−CH2−)\left(-\mathrm{CH}_{2}-\right) and oxygen atoms in R\mathbf{R} is \qquad .

Answer: 18

Numerical answer — enter this value.

Step-by-step solution

The number of CH2\mathrm{CH}_{2} group in R=14\mathbf{R}=14 The number of O atom in R=4\mathbf{R}=4 Total =18=18

Solution figure

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Exam
JEE Advanced 2024
Paper
Paper 1
Subject
Chemistry
Chapter
Aldehydes and Ketones
Topic
Chemical properties of Aldehydes & Ketones
Complete reaction of acetaldehyde with excess formaldehyde, upon… | JEE Advanced 2024 PYQ with Solution · DhiX AI