Physics · Atomic Physics

JEE Advanced 2019 — Paper 2 — Question 7

A free hydrogen atom after absorbing a photon of wavelength λa\lambda_{a} gets excited from the state n=1n=1 to the state

n=4n=4. Immediately after that the electron jumps to n=mn=m state by emitting a photon of wavelength λe\lambda_{e}. Let

the change in momentum of atom due to the absorption and the emission are Δpa\Delta \mathrm{p}_{\mathrm{a}} and Δpe\Delta \mathrm{p}_{\mathrm{e}}. respectively. If

λaλe=15\frac{\lambda_{a}}{\lambda_{e}}=\frac{1}{5}, which of the option(s) is /are correct ? [Use hc =1242eVnm;1 nm=10−9 m=1242 \mathrm{eV} \mathrm{nm} ; 1 \mathrm{~nm}=10^{-9} \mathrm{~m}, h and c are

Planck's constant and speed of light, respectively]

  1. Option A:

    ΔpaΔpe=12\frac{\Delta \mathrm{p}_{\mathrm{a}}}{\Delta \mathrm{p}_{\mathrm{e}}}=\frac{1}{2}

  2. Option B:

    The ratio of kinetic energy of the electron in the state n=mn=m to the state n=1n=1 is 14\frac{1}{4}

    Correct
  3. Option C:

    λe=418 nm\lambda_{e}=418 \mathrm{~nm}

  4. Option D:

    m=2\mathrm{m}=2

    Correct

Answer: B, D

Step-by-step solution

The energy level diagram is shown in the figure

It is given : λaλe=15\frac{\lambda_{\mathrm{a}}}{\lambda_{\mathrm{e}}}=\frac{1}{5}

or, 1−m2−142−1−1−142−=1λe1λa=15\frac{\frac{1}{-\mathrm{m}^{2}}-\frac{1}{4^{2}}-}{\frac{1}{-1}-\frac{1}{4^{2}}-}=\frac{\frac{1}{\lambda_{\mathrm{e}}}}{\frac{1}{\lambda_{\mathrm{a}}}}=\frac{1}{5}

⇒m=2\Rightarrow \mathrm{m}=2

clearly ΔpaΔpe≠12\frac{\Delta \mathrm{p}_{\mathrm{a}}}{\Delta \mathrm{p}_{\mathrm{e}}} \neq \frac{1}{2}

The ratio of the kinetic energies is also the ratio of the corresponding total energies =14=\frac{1}{4}

∴\therefore correct options are B, D

Solution figure

Answer key and solution verified before publishing.

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Exam
JEE Advanced 2019
Paper
Paper 2
Subject
Physics
Chapter
Atomic Physics
Topic
Hydrogen Spectrum