Chemistry · Carboxylic Acids and Derivatives

JEE Main 2024 — 5 April, Shift 2 — Question 86

The product (C) in the following sequence of reactions has ______\_\_\_\_\_\_ π\pi bonds.

figure

Answer: 4

Numerical answer — enter this value.

Step-by-step solution

The reaction sequence is:

C6H5CH2CH2CH3→Δalk. KMnO4C6H5COOK→H+C6H5COOH→Br2/FeBr3m ⁣− ⁣BrC6H4COOHPropyl  benzenePotassium   benzoate (A)Benzoic   acid (B)  m-Bromobenzoic   acid (C)\begin{array}{cccccc} \mathrm{C_6H_5CH_2CH_2CH_3} & \xrightarrow[\Delta]{\text{alk. }KMnO_4} & \mathrm{C_6H_5COOK} & \xrightarrow{H^+} & \mathrm{C_6H_5COOH} & \xrightarrow{Br_2/FeBr_3} \mathrm{m\!-\!BrC_6H_4COOH} \\ \text{Propyl\;benzene} & & \text{Potassium\; benzoate (A)} & & \text{Benzoic \;acid (B)} & \;\text{m-Bromobenzoic \;acid (C)} \end{array}

The product (C) is m-bromobenzoic acid.

Number of π\pi bonds in product (C) :

Benzene ring: 33 π\pi bonds

Carboxylic acid group (COOH): 11 π\pi bond (C=O)

So, total number of π\pi bonds =3+1=4= 3 + 1 = 4

Answer key and solution verified before publishing.

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Exam
JEE Main 2024
Subject
Chemistry
Chapter
Carboxylic Acids and Derivatives
Topic
Introduction and Preparation of Carboxylic Acids