Chemistry · Hydrocarbons

JEE Main 2024 — 29 January, Shift 1 — Question 70

The final product A formed in the following multistep reaction sequence is

Question figure
  1. Option A:
    Option A figure
    Correct
  2. Option B:
    Option B figure
  3. Option C:
    Option C figure
  4. Option D:
    Option D figure

Answer: A

Step-by-step solution

The starting compound is allylbenzene, C6H5−CH2−CH=CH2\mathrm{C_6H_5{-}CH_2{-}CH{=}CH_2}. Step (i):} H2O,H+\mathrm{H_2O, H^+} : Acid-catalysed hydration of the alkene gives a secondary alcohol at the benzylic side chain.

Step (ii): CrO3\mathrm{CrO_3} : Oxidation of the secondary alcohol forms a ketone.

Step (iii): H2N−NH2, KOH, heat\mathrm{H_2N{-}NH_2,\ KOH,\ heat}: Wolff-Kishner reduction converts the ketone into a methylene group.

Thus, the side chain is reduced to an ethyl group, and the final product is C6H5−CH2−CH3\mathrm{C_6H_5{-}CH_2{-}CH_3}.

Hence, the final product AA is ethylbenzene, corresponding to Option A.

Solution figure

Answer key and solution verified before publishing.

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Exam
JEE Main 2024
Subject
Chemistry
Chapter
Hydrocarbons
Topic
Properties & Uses of Alkenes and Dienes
The final product A formed in the following multistep reaction… | JEE Main 2024 PYQ with Solution · DhiX AI