Chemistry · p-Block Elements (Group 15-18)

JEE Main 2026 — 24 January, Evening Shift — Question 55

One mole of Cl2( g)\mathrm{Cl}_{2}(\mathrm{~g}) was passed into 2 L of cold 2 M KOH solution. After the reaction, the concentrations of Cl−,ClO−\mathrm{Cl}^{-}, \mathrm{ClO}^{-}and OH−\mathrm{OH}^{-}are respectively (assume volume remains constant)

  1. Option A:

    0.75M,0.75M,1M0.75 \mathrm{M}, 0.75 \mathrm{M}, 1 \mathrm{M}

  2. Option B:

    0.5M,0.5M,0.5M0.5 \mathrm{M}, 0.5 \mathrm{M}, 0.5 \mathrm{M}

  3. Option C:

    0.5M,0.5M,1M0.5 \mathrm{M}, 0.5 \mathrm{M}, 1 \mathrm{M}

    Correct
  4. Option D:

    1M,1M,1M1 \mathrm{M}, 1 \mathrm{M}, 1 \mathrm{M}

Answer: C

Step-by-step solution

Cl2+2KOH→KCl+KClO+H2O \mathrm{Cl}_{2}+2 \mathrm{KOH} \rightarrow \mathrm{KCl}+\mathrm{KClO}+\mathrm{H}_{2} \mathrm{O} t=01\mathrm{t}=01 mole 4 mole tf02\mathrm{t}_{\mathrm{f}} 02 mole 1 mole 1 mole [OH−]=1M\left[\mathrm{OH}^{-}\right]=1 \mathrm{M} [Cl−]=12M\left[\mathrm{Cl}^{-}\right]=\frac{1}{2} \mathrm{M} [ClO−]=12M\left[\mathrm{ClO}^{-}\right]=\frac{1}{2} \mathrm{M}

Answer key and solution verified before publishing.

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Exam
JEE Main 2026
Subject
Chemistry
Chapter
p-Block Elements (Group 15-18)
Topic
Compounds of Halogens
One mole of Cl 2 ( g ) was passed into 2 L of cold 2 M KOH solution.… | JEE Main 2026 PYQ with Solution · DhiX AI