Chemistry · Practical Organic Chemistry

JEE Main 2026 — 21 January, Morning Shift — Question 54

In Carius method, 0.75 g of an organic compound gave 1.2 g of barium sulphate, find percentage of sulphur (molar mass 32 g mol−132 \mathrm{~g} \mathrm{~mol}^{-1} ). Molar mass of barium sulphate is 233 g mol−1233 \mathrm{~g} \mathrm{~mol}^{-1}.

  1. Option A:

    4.55%4.55 \%

  2. Option B:

    10.30%10.30 \%

  3. Option C:

    21.97%21.97 \%

    Correct
  4. Option D:

    16.48%16.48 \%

Answer: C

Step-by-step solution

nBaSO4×32 W(unknown comp.) ×100\frac{\mathrm{n}_{\mathrm{BaSO}_{4}} \times 32}{\mathrm{~W}_{\text {(unknown comp.) }}} \times 100 =1.2×32233×1000.75=21.97%=\frac{1.2 \times 32}{233} \times \frac{100}{0.75}=21.97 \%

Answer key and solution verified before publishing.

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Exam
JEE Main 2026
Subject
Chemistry
Chapter
Practical Organic Chemistry
Topic
Quantitative organic analysis
In Carius method, 0.75 g of an organic compound gave 1.2 g of barium… | JEE Main 2026 PYQ with Solution · DhiX AI