Chemistry · Structure of Atom

JEE Main 2025 — 28 January, Morning Shift — Question 38

In a multielectron atom, which orbitals described by quantum numbers have same energy in absence of electric and magnetic fields?

(A) n=1, ℓ=0, mℓ=0n=1,\ \ell=0,\ m_\ell=0

(B) n=2, ℓ=0, mℓ=0n=2,\ \ell=0,\ m_\ell=0

(C) n=2, ℓ=1, mℓ=1n=2,\ \ell=1,\ m_\ell=1

(D) n=3, ℓ=2, mℓ=1n=3,\ \ell=2,\ m_\ell=1

(E) n=3, ℓ=2, mℓ=0n=3,\ \ell=2,\ m_\ell=0

Choose the correct answer from the options given below :

  1. Option A:

    A and B only

  2. Option B:

    B and C only

  3. Option C:

    C and D only

  4. Option D:

    D and E only

    Correct

Answer: D

Step-by-step solution

In multielectron atoms, orbital energy depends on nn and ℓ\ell, not on mℓm_\ell.

Orbitals with same nn and ℓ\ell are degenerate.

Only D and E have n=3, ℓ=2n=3,\ \ell=2

Thus, they have same energy.

Answer key and solution verified before publishing.

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Exam
JEE Main 2025
Subject
Chemistry
Chapter
Structure of Atom
Topic
Quantum Numbers and Sommerfeld
In a multielectron atom, which orbitals described by quantum numbers… | JEE Main 2025 PYQ with Solution · DhiX AI