Chemistry · p-Block Elements (Group 15-18)

JEE Main 2024 — 8 April, Shift 2 — Question 66

Identify the incorrect statements about group 15 elements :

(A) Dinitrogen is a diatomic gas which acts like an inert gas at room temperature.

(B) The common oxidation states of these elements are −3,+3-3,+3 and +5 .

(C) Nitrogen has unique ability to form pπ−pπ\mathrm{p} \pi-\mathrm{p} \pi multiple bonds.

(D) The stability of +5 oxidation states increases down the group.

(E) Nitrogen shows a maximum covalency of 6 .

Choose the correct answer from the options given below.

  1. Option A:

    (A), (B), (D) only

  2. Option B:

    (A), (C), (E) only

  3. Option C:

    (B), (D), (E) only

  4. Option D:

    (D) and (E) only

    Correct

Answer: D

Step-by-step solution

(A) Correct: Dinitrogen (N2\mathrm{N_2}) is a diatomic gas with a very strong N≡N\mathrm{N \equiv N} triple bond, which makes it relatively inert at room temperature.

(B) Correct: Group 15 elements commonly exhibit oxidation states of −3-3, +3+3, and +5+5.

(C) Correct: Nitrogen has a unique ability to form pπ-pπp\pi\text{-}p\pi multiple bonds due to its small size and effective orbital overlap.

(D) Incorrect: The stability of the +5+5 oxidation state decreases down the group because of the increasing inert pair effect.

(E) Incorrect: Nitrogen does not show a maximum covalency of 6; due to the absence of dd-orbitals, its maximum covalency is 4. Therefore, incorrect statements are (D) and (E).

Answer key and solution verified before publishing.

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Exam
JEE Main 2024
Subject
Chemistry
Chapter
p-Block Elements (Group 15-18)
Topic
Introduction & Properties of Group 15: Nitrogen Family
Identify the incorrect statements about group 15 elements : (A)… | JEE Main 2024 PYQ with Solution · DhiX AI