Chemistry · Coordination Compounds

JEE Main 2026 — 23 January, Evening Shift — Question 50

Identify the CORRECT set of details from the following :

A. [Co(NH3)6)3+\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right)^{3+} : Inner orbital complex ; d 2{ }^{2} sp 3^{3} hybridized

B. [MnCl6]3−\left[\mathrm{MnCl}_{6}\right]^{3-} Outer orbital complex; sp 3{ }^{3} hybridized

C. [CoF6]3\left[\mathrm{CoF}_{6}\right]^{3} : Outer orbital complex ; d2sp3\mathrm{d}^{2} \mathrm{sp}^{3} hybridized

D. [FeF6]3\left[\mathrm{FeF}_{6}\right]^{3} : Outer orbital complex: sp3 d2\mathrm{sp}^{3} \mathrm{~d}^{2} hybridized

E. [Ni(CN)4]2−\left[\mathrm{Ni}(\mathrm{CN})_{4}\right]^{2-} : Inner orbital complex ; sp 3{ }^{3} hybridized

Choose the correct answer from the options given below:

  1. Option A:

    C & D only

  2. Option B:

    A, B & D only

    Correct
  3. Option C:

    A, C & E only

  4. Option D:

    A, B, C, D & E

Answer: B

Step-by-step solution

(A) Co3+:−3 d6\mathrm{Co}^{3+}:-3 \mathrm{~d}^{6} NH3⇒\mathrm{NH}_{3} \Rightarrow S.F.L Hybridisation ⇒d2sp3\Rightarrow \mathrm{d}^{2} \mathrm{sp}^{3}, Inner orbital complex (B) Mn3+:−3 d4\mathrm{Mn}^{3+}:-3 \mathrm{~d}^{4} Cl−⇒\mathrm{Cl}^{-} \Rightarrow W.F.L Hybridisation ⇒sp3 d2\Rightarrow \mathrm{sp}^{3} \mathrm{~d}^{2}, Outer orbital complex (C) Co3+:−3 d6\mathrm{Co}^{3+}:-3 \mathrm{~d}^{6} F−⇒\mathrm{F}^{-} \Rightarrow W.F.L Hybridisation ⇒sp3 d2\Rightarrow \mathrm{sp}^{3} \mathrm{~d}^{2}, Outer orbital complex (D) Fe3+:−3 d5\mathrm{Fe}^{3+}:-3 \mathrm{~d}^{5} F−⇒\mathrm{F}^{-} \Rightarrow W.F.L Hybridisation ⇒sp3 d2\Rightarrow \mathrm{sp}^{3} \mathrm{~d}^{2}, Outer orbital complex (E) Ni2+:−3 d8\mathrm{Ni}^{2+}:-3 \mathrm{~d}^{8} CN−⇒\mathrm{CN}^{-} \Rightarrow S.F.L Hybridisation ⇒ dsp 2{ }^{2}, Inner orbital complex

Answer key and solution verified before publishing.

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Exam
JEE Main 2026
Subject
Chemistry
Chapter
Coordination Compounds
Topic
Theories of Bonding in Coordination Compounds
Identify the CORRECT set of details from the following : A. [ Co ( NH… | JEE Main 2026 PYQ with Solution · DhiX AI