Chemistry · Alcohols, Ethers and Phenols

JEE Main 2025 — 7 April, Morning Shift — Question 14

Given below are two statements : one is labelled as Statement I and the other is labelled as Statement II:

Statement I: Dimethyl ether is completely soluble in water. However, diethyl ether is soluble in water to a very small extent.

Statement II: Sodium metal can be used to dry diethyl ether and not ethyl alcohol.

In the light of the above statements, choose the correct answer from the options given below :

  1. Option A:

    Statement I is true but Statement II is false

  2. Option B:

    Both Statement I and Statement II are true

    Correct
  3. Option C:

    Statement I is false but Statement II is true

  4. Option D:

    Both Statement I and Statement II are False

Answer: B

Step-by-step solution

Diethyl ether is less soluble then dimethyl ether- as hydrophobic portion grows

C2H5OH+Na⟶C2H5ONa+12H2\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}+\mathrm{Na} \longrightarrow \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{ONa}+\frac{1}{2} \mathrm{H}_{2}

Na metal reacts with alcohol.

Answer key and solution verified before publishing.

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Exam
JEE Main 2025
Subject
Chemistry
Chapter
Alcohols, Ethers and Phenols
Topic
Ethers
Given below are two statements : one is labelled as Statement I and… | JEE Main 2025 PYQ with Solution · DhiX AI