Chemistry · Some Basic Concepts of Chemistry (Mole Concept) + Stoichiometry

JEE Main 2024 — 1 February, Shift 1 — Question 72

Given below are two statements, one is labelled as Statement I and the other is labelled as Statement II.

Statement (I) : Potassium hydrogen phthalate is a primary standard for standardisation of sodium hydroxide solution.

Statement (II) : In this titration phenolphthalein can be used as indicator.

In the light of the above statements, choose the most appropriate answer from the options given below:

  1. Option A:

    Both Statement I and Statement II are correct

    Correct
  2. Option B:

    Statement I is correct but Statement II is incorrect

  3. Option C:

    Statement I is incorrect but Statement II is correct

  4. Option D:

    Both Statement I and Statement II are incorrect

Answer: A

Step-by-step solution

Statement I is Correct: Potassium hydrogen phthalate (KHP) is a primary standard because it is pure, stable, non-hygroscopic, and has a high molar mass. Hence, it is commonly used for the standardisation of sodium hydroxide solution.

Statement II is Correct: In the titration of KHP (weak acid) with NaOH (strong base), the equivalence point lies in the basic range, so phenolphthalein is a suitable indicator.

Thus, both Statement I and Statement II are correct (Option A).

Answer key and solution verified before publishing.

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Exam
JEE Main 2024
Subject
Chemistry
Chapter
Some Basic Concepts of Chemistry (Mole Concept) + Stoichiometry
Topic
Acid-Base Titrations and Related Problems
Given below are two statements, one is labelled as Statement I and… | JEE Main 2024 PYQ with Solution · DhiX AI